| Identification | More | 【Name】
4-Nitrophenol | 【CAS】
100-02-7 | 【Synonyms】
4-HYDROXYNITROBENZENE 4-NITROHYDROXYBENZENE ACETAMINOPHENE IMP F ACETAMINOPHEN IMPURITY F AKOS BBS-00004351 HONP PARA-NITROPHENOL P-NITROPHENOL 1-Hydroxy-4-nitrobenzene 4-hydroxy-1-nitrobenzene 4-Nitrofenol 4-nitro-pheno Mononitrophenol NCI-C55992 Niphen Paranitrofenol Paranitrofenolo Phenol, p-nitro- Phenol,4-nitro- p-Hydroxynitrobenzene | 【EINECS(EC#)】
202-811-7 | 【Molecular Formula】
C6H5NO3 | 【MDL Number】
MFCD00007331 | 【Molecular Weight】
139.11 | 【MOL File】
100-02-7.mol |
| Chemical Properties | Back Directory | 【Appearance】
Yellow to tan crystals or powder | 【mp 】
112 °C | 【bp 】
279 °C(lit.)
| 【density 】
1,27 g/cm3 | 【vapor pressure 】
0.6 mm Hg ( 120 °C)
| 【Fp 】
169 °C
| 【storage temp. 】
Store in dark! | 【Stability:】
Stable. Incompatible with strong oxidizing agents, strong bases, organics, combustible material, reducing agents. Combustible. | 【Water Solubility 】
1.6 g/100 mL (25 ºC) | 【Sensitive 】
Light Sensitive | 【Merck 】
14,6621 | 【BRN 】
1281877 | 【CAS DataBase Reference】
100-02-7(CAS DataBase Reference) | 【NIST Chemistry Reference】
Phenol, 4-nitro-(100-02-7) | 【EPA Substance Registry System】
100-02-7(EPA Substance) |
| Safety Data | Back Directory | 【Hazard Codes 】
Xn,T,F | 【Risk Statements 】
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R33:Danger of cumulative effects. R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed . R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R11:Highly Flammable. | 【Safety Statements 】
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37:Wear suitable protective clothing and gloves . S16:Keep away from sources of ignition - No smoking . S7:Keep container tightly closed . | 【RIDADR 】
UN 1663 6.1/PG 3
| 【WGK Germany 】
2
| 【RTECS 】
SM2275000
| 【F 】
8 | 【HazardClass 】
6.1 | 【PackingGroup 】
III | 【HS Code 】
29089000 | 【Hazardous Substances Data】
100-02-7(Hazardous Substances Data) |
| Hazard Information | Back Directory | 【General Description】
A white to light yellow crystalline solid. Contact may severely irritate skin and eyes. Poisonous by ingestion and moderately toxic by skin contact. | 【Reactivity Profile】
4-NITROPHENOL(100-02-7) is a slightly yellow, crystalline material, moderately toxic. Mixtures with diethyl phosphite may explode when heated. Decomposes exothermally, emits toxic fumes of oxides of nitrogen [Lewis, 3rd ed., 1993, p. 941]. Decomposes violently at 279°C and will burn even in absence of air [USCG, 1999]. Solid mixtures of the nitrophenol and potassium hydroxide (1:1.5 mol) readily deflagrate [Bretherick, 5th Ed., 1995]. | 【Air & Water Reactions】
Soluble in hot water and more dense than water. | 【Health Hazard】
Inhalation or ingestion causes headache, drowsiness, nausea, and blue color in lips, ears, and fingernails (cyanosis). Contact with eyes or skin causes irritation; can be absorbed through skin to give same symptoms as for inhalation. |
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