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14644-61-2

14644-61-2 Structure

14644-61-2 Structure
IdentificationMore
[Name]

Zirconium sulphate
[CAS]

14644-61-2
[Synonyms]

ZIRCONIUM(IV) SULFATE
ZIRCONIUM SULFATE
disulfatozirconicacid
Sulfuricacid,zirconium(4+)salt(2:1)
sulfuricacid,zirconium(4++)salt(2:1)
zirconium(iv)sulfate(1:2)
zirconiumdisulfate
zirconiumorthosulfate
Zirconium sulfatete trahydrate PURATREM white xtl
ZIRCONIUM(IV) SULFATE, 35 WT. % SOLUTIO&
ZirconiumSulphate(33.0%)
ZIRCONIUM SULFATE, TETRAHYDRATE 99.99% (Low Hf)
zirconium(iv) sulfate solution
ZIRCONYLSULPHATE
ZIRCONIUM(IV)SULPHATE
Sulfuric acid, zirconium salt
ZIRCONIUM(IV) SULFATE TETRAHYDRATE: 99.99% PURATREM
Zirconium sulphate
zirconium tanning agent
Bis(sulfonylbisoxy)zirconium(IV)
[EINECS(EC#)]

238-694-4
[Molecular Formula]

O8S2Zr
[MDL Number]

MFCD00085312
[Molecular Weight]

283.35
[MOL File]

14644-61-2.mol
Chemical PropertiesBack Directory
[Melting point ]

410°C
[density ]

3.22
[solubility ]

H2O: slightly soluble(lit.)
[color ]

white hygroscopic crystals, crystalline
[Water Solubility ]

52.5g/100g solution H2O (18°C); deposits solid with elementary composition 4ZrO2 · 3SO3 · 15H2O, on standing at ambient temp [MER06]
[Merck ]

13,10235
[InChIKey]

ZXAUZSQITFJWPS-UHFFFAOYSA-J
[CAS DataBase Reference]

14644-61-2(CAS DataBase Reference)
[EPA Substance Registry System]

14644-61-2(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

white crystal(s) [STR93]
[General Description]

Anhydrous ZIRCONIUM SULFATE(14644-61-2) is a colorless microcrystalline solid. ZIRCONIUM SULFATE(14644-61-2) is also obtained as a white crystalline tetrahydrate, ZrSO4.4H2O. Both forms are soluble in water and noncombustible. ZIRCONIUM SULFATE(14644-61-2) is corrosive to aluminum. ZIRCONIUM SULFATE(14644-61-2) is used in chemical analysis, as an additive for lubricants, and for many other uses.
[Reactivity Profile]

ZIRCONIUM SULFATE is a weak oxidizing agent. Water solutions are acidic and corrosive to aluminum and other metals
[Air & Water Reactions]

Water soluble.
[Health Hazard]

Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.
[Fire Hazard]

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
[Physical properties]

Anhydrous sulfate is a microcrystalline hygroscopic solid; density 3.22 g/cm3; decomposes at 410°C; soluble in water.
The tetrahydrate, Zr(SO4)2?4H2O, is a white crystalline solid; orthorhombic crystals; loses three molecules of water between 100 and 150°C; becomes anhydrous at 380°C; soluble in water, 52.5 g/100g solution; the solution deposits a solid on standing; the aqueous solution is strongly acidic, decomposed by bases or on heating.
[Uses]

Zirconium sulfate [Zr(SO4)2] is an ingredient in lubricants that do not disintegrate at hightemperatures. It is also used for tanning leather to make it white and as a chemical reagent and catalyst in chemical laboratories.
[Preparation]

Zirconium sulfate is prepared by the action of sulfuric acid on zirconium hydroxide: Zr(OH)4 + 2H2SO4 → Zr(SO4)2 + 4H2O
Also, it is prepared by treating zirconyl chloride with hot concentrated sulfuric acid: ZrOCl2 + 2H2SO4 → Zr(SO4)2 + H2O + 2HCl.
[Flammability and Explosibility]

Nonflammable
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3264 8/PG 3
[RTECS ]

ZH9100000
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[Safety Profile]

Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. A corrosive. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also SULFATES and ZIRCONIUM COMPOUNDS.
[Hazardous Substances Data]

14644-61-2(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium silicate-->ZIRCONIUM SILICATE-->SODIUM ZIRCONATE-->Zircon tanning agent
[Preparation Products]

Zirconium dioxide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Zirconium sulphate(14644-61-2).msds
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

14644-61-2(sigmaaldrich)
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