| Identification | More | [Name]
(S)-(-)-2-Methyl-2-propanesulfinamide | [CAS]
343338-28-3 | [Synonyms]
(S)-(-)-2-METHYL-2-PROPANESULFINAMIDE
(S)-2-METHYL-2-PROPANESULFINAMIDE
(S)-(-)-2-METHYL-2-PROPANESULPHINAMIDE
(S)-2-METHYLPROPANE-2-SULFINAMIDE
(S)-(-)-2-METHYL-PROPANE-2-SULFINIC ACID AMIDE
(S)-(-)-T-BUTYLMETHYLSULFINAMIDE
(S)-(-)-T-BUTYLSULFINAMIDE
(S)-(-)-TERT-BUTANESULFINAMIDE
(S)-TERT-BUTANESULFINAMIDE
(S)-(-)-TERT-BUTYLSULFINAMIDE
(S)-(-)-TERT-BUTYL SULPHINAMIDE
TERT-BUTYL SULFINAMIDE
(S)-(-)-t-Butylmethylsulfinamide,min.97%
(S)-(-)-tert-Butyl sulphinamide 98%
(S)-(-)-t-Butyl sulfinamide, 98% ee
(S)-TERT-BUTANESULFINAMIDE/(S)-(-)-2-METHYL-2-PROPANESULFINAMIDE
(S)-(-)-2-METHYL-2-PROPANESULFINAMIDE,98.5+%
(S)-(-)-2-Methyl-2-propanesulfinamide
(S)-TERT-BUTYLSULFINAMIDE,97+% (>98.0% EE)
(S)-(-)-t-Butylmethylsulfinamide, min. 97% | [EINECS(EC#)]
640-158-3 | [Molecular Formula]
C4H11NOS | [MDL Number]
MFCD05861480 | [Molecular Weight]
121.2 | [MOL File]
343338-28-3.mol |
| Questions And Answer | Back Directory | [Description]
Acid labile protecting groups are important in organic synthesis. The
tert‐butyl group is commonly used for protection of a large variety of
functional groups, e.g., acids, alcohols, phenols, and sulfonamides.
Among them, s-tert-butyl sulfonamide is a chiral ligand used in
pharmaceutical compositions. P, n-sulfoxide imine ligands were
synthesized by condensation of s-tert-butylsulfonamide with aldehydes
and ketones, and they can be used for asymmetric hydrogenation of
olefins under iridium catalysis. |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
97-101 °C(lit.)
| [alpha ]
-4.5 º (c=1, CHCl3) | [Boiling point ]
220.0±23.0 °C(Predicted) | [density ]
1.124 | [storage temp. ]
Keep Cold | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder | [pka]
10.11±0.50(Predicted) | [color ]
White | [optical activity]
[α]20/D 4.5°, c = 1 in chloroform | [Stability:]
store cold | [InChI]
InChI=1/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3/t7-/s3 | [InChIKey]
CESUXLKAADQNTB-SSDOTTSWSA-N | [SMILES]
CC(C)([S@@](N)=O)C |&1:3,r| | [CAS DataBase Reference]
343338-28-3(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Physical properties]
white to light yellow crystal powde | [Uses]
It is also employed as a reagent for synthesizing chiral amines. | [Uses]
suzuki reaction |
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