ChemicalBook--->CAS DataBase List--->453-17-8

453-17-8

453-17-8 Structure

453-17-8 Structure
IdentificationMore
[Name]

D-Glyceraldehyde
[CAS]

453-17-8
[Synonyms]

D-(+)-GLYCERALDEHYDE
D-GLYCERALDEHYDE
(r)-2,3-dihydroxy-propanal
Glyceraldehyde, D-
Triose
D-GLYCERALDEHYDE, 80-90 WT. % SOLUTION I N WATER
D-GLYCERALDEHYDE MINIMUM 70%
D(+)GLYCERALDEHYDE extrapure
(R)-(+)-Glyceraldehyde, D-Glyceraldehyde solution
D(+)-Glyceraldehyde solution
(2R)-2,3-Dihydroxypropanal
D-2,3-Dihydroxypropanal
D-2,3-Dihydroxypropionaldehyde
D-Aldotriose
D-Glycerose
(2R)-2,3-Dihydroxypropionaldehyde
[EINECS(EC#)]

207-217-1
[Molecular Formula]

C3H6O3
[MDL Number]

MFCD00064378
[Molecular Weight]

90.08
[MOL File]

453-17-8.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR ORANGE SYRUP
[Melting point ]

127-129 C
[alpha ]

D25 +8.7° (c = 2 in H2O); D15 +21.2° (c = 18)
[Boiling point ]

bp17 127-129°; bp10 123-126°
[density ]

1.272±0.06 g/cm3(Predicted)
[refractive index ]

n20/D 1.494
[Fp ]

112 °C
[storage temp. ]

2-8°C
[form ]

liquid (viscous)
[pka]

12.60±0.20(Predicted)
[Merck ]

13,4494
[BRN ]

1720474
[CAS DataBase Reference]

453-17-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Propanal, 2,3-dihydroxy-, (r)-(453-17-8)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

3
[F ]

10-23
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(R)-2,3-Dihydroxy-propanal(453-17-8).msds
Hazard InformationBack Directory
[Description]

D-(+)-Glyceraldehyde is an intermediate in carbohydrate metabolism. It is phosphorylated by triose kinase to produce D-glyceraldehyde 3-phosphate, an intermediate in glycolysis, gluconeogenesis, photosynthesis, and other metabolic pathways.
[Chemical Properties]

CLEAR ORANGE SYRUP
[Uses]

D-(+)-Glyceraldehyde can be utilized as a reactant in the synthesis of:
  • (S)-homophenylalanine by ruthenium oxidation of a 3-amino-1,2-diol generated via coupling of an amine, and α-hydroxyaldehyde.
  • β- and γ-allenols via metal-catalyzed cyclization. Allenols are used as a key precursor for the preparation of enantiopure dihydropyrans and tetrahydrooxepines.
  • Isopropylidene D-glyceraldehyde intermediate, which controls the chirality in the total synthesis of prostaglandins (PGE1).

[Uses]

D-Glyceraldehyde is the simplest of all aldoses and have been shown to be the one of the carbonyl metabolite of dietary fructose.
[Definition]

ChEBI: The D-enantiomer of glyceraldehyde.
[Purification Methods]

enantiomer [453-17-8] is a syrup (70 + % H2O) with [] D +14o (c 2, H2O) and the dimethyl acetal has b 124-127 o/14mm and []15 +21o (c 18, H2O). [Beilstein 1 H 845, 1 IV 4114.]
Spectrum DetailBack Directory
[Spectrum Detail]

D-Glyceraldehyde(453-17-8)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

453-17-8(sigmaaldrich)
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