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70124-77-5

70124-77-5 Structure

70124-77-5 Structure
IdentificationMore
[Name]

FLUCYTHRINATE
[CAS]

70124-77-5
[Synonyms]

ALPHA-CYANO-3-PHENOXYBENZYL 4-DIFLUOROMETHOXY-ALPHA-ISOPROPYLPHENYLACETATE
CYBOLT
CYTHRIN
FLUCYTHRINATE
FLUCYTRINAT
FLUENT
PAY-OFF
(+-)-cyano(3-phenoxyphenyl)methyl(+)-4-(difluoromethoxy)-alpha-(1-methylethy
(+-)-cyano-(3-phenoxyphenyl)methyl(+)-4-(difluoromethoxy)-alpha-(methylethyl)
(rs)-alpha-cyano-3-phenoxybenzyl(s)-2-(4-difluoromethoxyphenyl)-3-methylbutyr
(rs)-alpha-cyano-3-phenoxybenzyl(s)-2-(4-difluoromethoxyphenyl)-3-methylbutyra
(rs)-cyano-(3-phenoxyphenyl)methyl(s)-4-(difluoromethoxy)-alpha-(1-methylethy
(rs)-cyano-(3-phenoxyphenyl)methyl(s)-4-(difluoromethoxy)-alpha-(1-methylethyl
)-benzeneacetate
4-(difluoromethoxy)-alpha-(1-methylethyl)-benzeneaceticacicyano(3-phenoxy
4-(difluoromethoxy)-alpha-(1-methylethyl)benzeneaceticacid,cyano(3-phenoxyphe
4-(difluoromethoxy)-alpha-(1-methylethyl)benzeneaceticacidcyano(3-phenoxy-ph
ac222705
ac-222705
benzeneacetate
[EINECS(EC#)]

274-322-7
[Molecular Formula]

C26H23F2NO4
[MDL Number]

MFCD00137383
[Molecular Weight]

451.46
[MOL File]

70124-77-5.mol
Chemical PropertiesBack Directory
[Melting point ]

<25℃
[Boiling point ]

108℃ (0.35mmHg)
[density ]

1.189 g/cm3 (22℃)
[vapor pressure ]

1.2×10-6 Pa (25 °C)
[refractive index ]

1.541 (589.3 nm 25℃)
[Fp ]

-18 °C
[storage temp. ]

APPROX 4°C
[form ]

neat
[Water Solubility ]

0.5 mg l-1 (22 °C)
[Specific Gravity]

1.189 (22℃)
[BRN ]

2195795
[CAS DataBase Reference]

70124-77-5(CAS DataBase Reference)
[EPA Substance Registry System]

Flucythrinate (70124-77-5)
Safety DataBack Directory
[Hazard Codes ]

T,N,Xn,F
[Risk Statements ]

R20/21:Harmful by inhalation and in contact with skin .
R25:Toxic if swallowed.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R38:Irritating to the skin.
R11:Highly Flammable.
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
[RIDADR ]

UN 2810 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

CY1578620
[HS Code ]

29269090
[Hazardous Substances Data]

70124-77-5(Hazardous Substances Data)
[Toxicity]

LC50 (96-hour) for rainbow trout 0.32 μg/L, bluegill sun?sh 0.71 μg/L, channel cat?sh 0.51 μg/L, sheepshead minnow 1.6 μg/L (Hartley and Kidd, 1987), estuarine mysid 0.008 μg/L, pink shrimp 0.22 μg/L and sheepshead minnow 1.1 μg/L (Schimmel et al., 1983); acute oral LD50 for male and female rats is 81 and 67 mg/kg, respectively (Hartley and Kidd, 1987).
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dichloromethane-->Hexane-->1,4-Dioxane-->Fenvalerate-->p-Anisaldehyde-->Dimethyl ether-->Isovaleric acid-->2-PhenylethylaMine-->Pyrethrins-->3-PHENOXYBENZALDEHYDE CYANOHYDRIN, 70 WT% SOLUTION IN ETHER
Hazard InformationBack Directory
[Uses]

Flucythrinate controls a wide range of insects on cotton, fruit trees, vines, citrus, bananas, pineapples, olives, coffee, cocoa, hops, vegetables, soyabeans, cereals, alfalfa, sugar beet, sunflowers and tobacco.
[Uses]

Insecticide.
[Uses]

Nonsystemic insecticide.
[General Description]

Flucythrinate belongs to the class of synthetic pyrethroids, primarily used to control Heliothis spp. in cotton and other insect pests in agricultural crops.
[Agricultural Uses]

Insecticide, Acaricide: Not approved for use in EU countries. Not currently registered in the U.S. Flucythrinate is a synthetic pyrethroid used to control pests in apples, cabbage, head lettuce, pears, corn and cotton, but it was used primarily on cotton.
[Trade name]

AASTAR®[C]; CYBOLT®; CYTHRIN®; FUCHING JUJR®; GUARDIAN®[C]; PAYOFF®[C]; STOCK GUARD®; TOMAHAWK®
[Pharmacology]

Flucythrinate is the (S)-2-(4-difluoromethoxyphenyl)-3-methylbutyrate analog of fenvalerate, partially resolved. Its insecticide action is approximately two times higher compared with fenvalerate (138,142).
[Environmental Fate]

Surface Water. The half-life of ?ucythrinate in an estuarine environment is 34 days (Schimmel et al., 1983).
Chemical/Physical. Hydrolyzes in aqueous solutions forming acetic acid and other compounds.
[Metabolic pathway]

Flucythrinate is an analogue of fenvalerate and would be expected to have a similar fate.
[Degradation]

Flucythrinate is a stable compound but it is readily hydrolysed at alkaline pH to afford 2-(4-difluoromethoxyphenyl)-3-methylbutyric acid (2), 3PBAl(3) and cyanide ion. Its DT50 values at 27 °C are 52 days (pH 5) and 6.3 days (pH 9). It undergoes aqueous and soil surface photolysis with DT50 values of 1-4 days and <2 days, respectively. The products formed under aqueous conditions were 2 and 3. Compound 3 was oxidised to 3PBA (4) and reduced to 3PBAlc (5). The α-carbamoyl (amide) derivative (6) of 3PBAlc was also detected. On soil surfaces, products were similar with the exceptions that 3PBA was not formed and the α-amide (7) and a-carboxy derivative (8) were formed. These are usually considered to be products of thermal degradation (Dureja and Chattopadhyay, 1995).
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

70124-77-5(sigmaaldrich)
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