ChemicalBook--->CAS DataBase List--->72287-26-4

72287-26-4

72287-26-4 Structure

72287-26-4 Structure
IdentificationBack Directory
[Name]

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
[CAS]

72287-26-4
[Synonyms]

PDCL2(DPPF)
(dppf)2PdCl2
dichloropalladiuM
[1,1′-Bis(diphenylph
(II)dichloromethane adduct
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropall
[1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI
-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
[1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium
[bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane
1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II)
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ)
1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride
[1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II)
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)
Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE
1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride
1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98%
1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99%
[1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9%
1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9%
1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd
(1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2
[1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf)
1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2]
(1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL
Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)-
Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2
Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add
-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex
DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT
1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE
1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane
[1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II), coMplex with dichloroMethane
[1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1)
dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1)
[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1)
1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane
[EINECS(EC#)]

460-040-3
[Molecular Formula]

C34H28Cl2FeP2Pd 10*
[MDL Number]

MFCD00015757
[MOL File]

72287-26-4.mol
[Molecular Weight]

731.7
Chemical PropertiesBack Directory
[Melting point ]

275-280 °C(lit.)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

Soluble in dichloromethane.
[form ]

powder
[color ]

red to very dark red
Questions And AnswerBack Directory
[Uses]

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.
Hazard InformationBack Directory
[Chemical Properties]

Red solid
[Usage]

suzuki reaction
[Application]

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
[Mechanism of action]

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.

R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

20/21/22-36/37/38-40
[Safety Statements ]

23-24/25-26-36/37
[WGK Germany ]

3
[Hazard Note ]

Irritant
[TSCA ]

No
[HazardClass ]

IRRITANT
[HS Code ]

28439090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Methanol-->Dichloromethane-->Toluene-->Acetonitrile-->Palladium chloride-->Lithium chloride-->1,1'-Bis(diphenylphosphino)ferrocene
[Preparation Products]

3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER-->Vanadyl acetylacetonate-->4-Nitrophenylboronic acid-->4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER-->2-Ethoxycarbonylphenylboronic acid pinacol ester
Spectrum DetailBack Directory
[Spectrum Detail]

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)1HNMR
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)31PNMR
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)FT-IR
72287-26-4 suppliers list
Company Name: Wuhan Huahan Dingcheng New Material Technology Co., Ltd
Tel: +undefined-027-81388558 +undefined086-1878077615 , +undefined086-1878077615
Website: www.huahandingcheng.com
Company Name: Hebei Yanxi Chemical Co., Ltd.
Tel: +8617531190177 , +8617531190177
Website: www.chemicalbook.com/manufacturer/hebei-yanxi-chemical-283/
Company Name: Henan Bao Enluo International TradeCo.,LTD
Tel: +86-17331933971 +86-17331933971 , +86-17331933971
Website: baoenluo.guidechem.com/
Company Name: Henan Fengda Chemical Co., Ltd
Tel: +86-371-86557731 +86-13613820652 , +86-13613820652
Website: www.fdachem.com
Company Name: Capot Chemical Co.,Ltd.
Tel: 571-85586718 +8613336195806 , +8613336195806
Website: http://www.capotchem.com
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
Website: www.dakenam.com/
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512 , +86-19937530512
Website: https://www.tianfuchem.com/
Company Name: Hangzhou FandaChem Co.,Ltd.
Tel: 008657128800458; +8615858145714 , +8615858145714
Website: http://www.fandachem.com
Company Name: Nanjing ChemLin Chemical Industry Co., Ltd.
Tel: 025-83697070
Website: www.echemlin.cn
Company Name: ATK CHEMICAL COMPANY LIMITED
Tel: +undefined-21-51877795
Website: www.atkchemical.com
Company Name: AB PharmaTech,LLC
Tel: 323-480-4688
Website: www.abpharmatechusa.com
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: +86-0551-65418679 +86-18949832763 , +86-18949832763
Website: http://www.tnjchem.com
Company Name: Zjartschem
Tel: +86-571-8723 8903 jocelynpan@zjarts.com
Website: www.zjartschem.com/eacpzs.asp?dlb_id=12
Company Name: Shanghai Zheyan Biotech Co., Ltd.
Tel: 18017610038
Website: www.chemicalbook.com/ShowSupplierProductsList30845/0.htm
Company Name: career henan chemical co
Tel: +86-0371-86658258
Website: https://www.coreychem.com/
Company Name: Nanjing Dolon Biotechnology Co.,Ltd.
Tel: 18905173768
Website: www.chemicalbook.com/ShowSupplierProductsList31215/0.htm
Company Name: Hebei Jimi Trading Co., Ltd.
Tel: +86 319 5273535
Website: www.hebeijimi.com
Company Name: Yunbio Tech Co.,Ltd.
Tel: +86-010-60605551 +86-18046518538 , +86-18046518538
Website: https://yunbiopharm.com/
Tags:72287-26-4 Related Product Information
59831-02-6 95408-45-0 50982-13-3 19978-61-1 14221-02-4 4559-70-0 16523-54-9 1079-66-9 2622-14-2 1271-55-2 102-54-5 7647-10-1 12150-46-8 6372-40-3 7440-05-3 75-09-2 638-21-1 95464-05-4