ChemicalBook--->CAS DataBase List--->86-58-8

86-58-8

86-58-8 Structure

86-58-8 Structure
IdentificationMore
[Name]

8-Quinolineboronic acid
[CAS]

86-58-8
[Synonyms]

8-QUINOLINEBORONIC ACID
8-QUINOLINEBORONIC ACID, DIMER
8-QUINOLINYLBORONIC ACID
QUINOLIN-8-YLBORONIC ACID
QUINOLINE-8-BORONIC ACID
RARECHEM AH PB 0127
TIMTEC-BB SBB003824
8-QUINOLINEBORONIC ACID 95%
Quinoline-8-boronicacid,99%
8-Quinolineboronic
8-quindineboronic acid
8-QUINOLINBORONIC ACID
Quinolin-8-yl-8-boronic acid
[EINECS(EC#)]

626-756-7
[Molecular Formula]

C9H8BNO2
[MDL Number]

MFCD01114698
[Molecular Weight]

172.98
[MOL File]

86-58-8.mol
Chemical PropertiesBack Directory
[Appearance]

yellow crystal powder
[Melting point ]

>300 °C(lit.)
[Boiling point ]

160-165°C
[density ]

1.28±0.1 g/cm3(Predicted)
[storage temp. ]

0-6°C
[solubility ]

soluble in Methanol
[form ]

Powder
[pka]

4.61±0.30(Predicted)
[color ]

Yellow to beige
[Detection Methods]

HPLC
[Merck ]

14,8069
[BRN ]

147522
[InChIKey]

KXJJSKYICDAICD-UHFFFAOYSA-N
[CAS DataBase Reference]

86-58-8(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[HazardClass ]

IRRITANT
[HS Code ]

29334900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Tetrahydrofuran-->n-Butyllithium-->Acetonitrile-->Trimethyl borate-->Cupric bromide-->tert-Butyl nitrite-->8-Bromoquinoline-->8-Aminoquinoline
Hazard InformationBack Directory
[Chemical Properties]

yellow crystal powder
[Uses]

Reactant involved in:
  • C-H and C-S bond activations
  • Synthesis of pyridazine via sequential amination / Suzuki coupling / alkylation reactions
  • Suzuki-Miyaura coupling reactions for synthesis of biaryl monophosphorus ligands, fused tricyclic oxa-quinolones, or substituted β-amino acids
  • Copper-catalyzed azidation with sodium azide
  • Studies of the affect of fluoride on the stability of boronic acids during click reactions
[Uses]

suzuki reaction
Spectrum DetailBack Directory
[Spectrum Detail]

8-Quinolineboronic acid(86-58-8)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

8-Quinoline boronic acid, 96%(86-58-8)
[Alfa Aesar]

Quinoline-8-boronic acid, 99%(86-58-8)
[Sigma Aldrich]

86-58-8(sigmaaldrich)
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