kopsine

kopsine Struktur
559-48-8
CAS-Nr.
559-48-8
Englisch Name:
kopsine
Synonyma:
kopsine;3-Hydroxy-22-oxokopsan-1-carboxylic acid methyl ester;6H,13aH-3a,5a-Ethano-5,11-methano-1H-indolizino[8,1-cd]carbazole-6-carboxylic acid, 2,3,4,5,11,12-hexahydro-5-hydroxy-14-oxo-, methyl ester, (3aR,5S,5aS,10bR,11R,13aS)- (9CI)
CBNumber:
CB21480539
Summenformel:
C22H24N2O4
Molgewicht:
380.44
MOL-Datei:
559-48-8.mol

kopsine Eigenschaften

Schmelzpunkt:
220°C (dec.).
alpha 
D27 -14.3 ± 1° (c = 2 in chloroform)

Sicherheit

kopsine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

The major constituent of Kopsia !ruticosa, this base has [α]D - 17.5° (c 2.15, CHC13). It forms a series of crystalline salts and derivatives, e.g. the aurichloride, m.p. 203-5°C (dec.); perchlorate, m.p. 284°C (dec.); picrate, m.p. 230°C (dec.) and methiodide, m.p. 200°C (dec.). It may be reduced to the dihydro derivative which has m.p. 218°C. When fused with NaOH the alkaloid furnishes 2- methylindole and 2-indole-2-carboxylic acid.

Einzelnachweise

Bhattacharya et al., 1. Amer. Chem. Soc., 71,3370 (1949)
Spiteller et al., Naturwiss., 49, 279 (1962)
Govindachari et al., Helv. Chim. Acta, 45, 1146 (1962)
Govindachari et al., ibid, 46, 433, 572 (1963)
Battersby, Gregory.,J. Chern. Soc., 22 (1963)

kopsine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


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  • kopsine
  • 3-Hydroxy-22-oxokopsan-1-carboxylic acid methyl ester
  • 6H,13aH-3a,5a-Ethano-5,11-methano-1H-indolizino[8,1-cd]carbazole-6-carboxylic acid, 2,3,4,5,11,12-hexahydro-5-hydroxy-14-oxo-, methyl ester, (3aR,5S,5aS,10bR,11R,13aS)- (9CI)
  • 559-48-8
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