[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer

Copper(II) phthalocyanine Struktur
147-14-8
CAS-Nr.
147-14-8
Bezeichnung:
[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer
Englisch Name:
Copper(II) phthalocyanine
Synonyma:
CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue
CBNumber:
CB6255035
Summenformel:
C32H16CuN8
Molgewicht:
576.07
MOL-Datei:
147-14-8.mol

[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer Eigenschaften

Schmelzpunkt:
600°C (dec.)
Dichte
1.62[at 20℃]
storage temp. 
Inert atmosphere,Room Temperature
Löslichkeit
insoluble in H2O, ethanol; soluble in concHSO 4
Colour Index 
74160
Aggregatzustand
Fine Crystalline Powder
Farbe
Dark blue
Geruch (Odor)
odorless
Wasserlöslichkeit
<0.1 g/100 mL at 20 ºC
maximale Wellenlänge (λmax)
602nm(CHCl3)(lit.)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck 
14,2520
BRN 
4121848
Expositionsgrenzwerte
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey
XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP
-1 at 23℃
NIST chemische Informationen
Copper phthalocyanine(147-14-8)
EPA chemische Informationen
C.I. Pigment Blue 15 (147-14-8)
Absorption
λmax 678 nm (DMF)

Sicherheit

S-Sätze: 22-24/25
WGK Germany  -
RTECS-Nr. GL8510000
TSCA  Yes
HS Code  32041300
Giftige Stoffe Daten 147-14-8(Hazardous Substances Data)
Toxizität LD50 intraperitoneal in rat: > 3gm/kg

[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

ERSCHEINUNGSBILD

HELLBLAUE KRISTALLE.

CHEMISCHE GEFAHREN

Zersetzung beim Erhitzen unter Bildung giftiger Rauche.

ARBEITSPLATZGRENZWERTE

TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2006).

INHALATIONSGEFAHREN

Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitsschädliche Konzentration in der Luft erreicht wird.

LECKAGE

Persönliche Schutzausrüstung: Atemschutzgerät, P1-Filter für inerte Partikel. Verschüttetes Material in Behältern sammeln. Reste sorgfältig sammeln. An sicheren Ort bringen.

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

dark blue fine crystalline powder

Verwenden

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

Application

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

Allgemeine Beschreibung

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

läuterung methode

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 435)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282
alice@crovellbio.com China 8823 58
Hebei Dongdu Import and Export Co. LTD
+86-15333296769 +86-15333296769
manager@cndongdu.com China 71 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21700 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763
info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873
sales@chemdad.com China 39916 58
Winchem industrial co limited
+86-0086-574-83851061 +86-13003762012
lucyhu@win-chemical.com China 300 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 47465 58

147-14-8([29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfer)Verwandte Suche:


  • Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)- Copper, [phthalocyaninato(2-)]-
  • phthalocyanine blueB15:0
  • Pigment Blue 15 (purified by sublimation)
  • calcotonebluegp
  • ceresbluebhr
  • chromatexbluebn
  • ciingrainblue2
  • cipigmentblue15
  • congoblueb-4
  • Copper phthalocyanine,CI 74160
  • Copper, [29H,31H-phthalocyaninato(2-)-N(29)-,N(30)-,N(31)-,N(32)-]-, (SP-4-1)-
  • copper,(29h,31h-phthalocyaninato(2-)-n(sup29),n(sup30),n(sup31),n(sup32)
  • Copper,[29H,31H-phthalocyaninato(2(-))-N29,N30,N31,N32]-(SP-4-1)-
  • copperphthalocyanin
  • copperphthalocyanineblue
  • cromophtalblue4g
  • cyanbluebnc55-3745
  • cyanbluebnf55-3753
  • cyanbluegt55-3295
  • cyaninebluebb
  • CyanineBlueBB,BF,GC,HB,LB
  • cyaninebluec
  • cyanpeacockblueg
  • dainichicyanineblueb
  • dainichicyaninebluefpg
  • daltolitefastblueb
  • duratintblue1001
  • fastogenblue5110
  • fastogenblueb
  • fastoluxblue
  • fenalacbluebdisp
  • franconiabluea-4431
  • graphtolblue2gls
  • graphtolbluebl
  • helioblueb
  • HelioFastBlueB,BB,BF,BRN,BT,GO,GOT,HB,HG
  • heliofastbluebrn
  • HeliogenBlue6480
  • heliogenblueb
  • heliogenbluelbg
  • HostapermBlueAFN,A3R
  • indolenblue3g
  • irgalitefastbrilliantbluebl
  • isolfastblueb
  • lbx5
  • Monastral blue B
  • phthaloblue
  • phthalocyanineblue15
  • pigmentblue15:4
  • PigmentphthalocyanineblueB
  • PigmentphthalocyanineblueBN
  • PigmentphthalocyanineblueBS
  • PigmentphthalocyanineblueBX
  • PigmentphthalocyanineblueFGX
  • Copper(II) Phthalocyanine (alpha-form)
  • Copper(II) Phthalocyanine (beta-form)
  • Copper(II) phthalocyanine,CuPc, Phthalocyanine blue, Pigment Blue 15
  • Phthalocyanine Copper(II)
Copyright 2019 © ChemicalBook. All rights reserved