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HYDROGEN SULFIDE

HYDROGEN SULFIDE
HYDROGEN SULFIDE
CAS No.
7783-06-4
Chemical Name:
HYDROGEN SULFIDE
Synonyms
H2S;sourgas;sewergas;Sour gas;Sewer gas;stinkdamp;Stink damp;Hepatic gas;Siarkowodor;Hepatic acid
CBNumber:
CB0122872
Molecular Formula:
H2S
Formula Weight:
34.08
MOL File:
7783-06-4.mol

HYDROGEN SULFIDE Properties

Melting point:
−85 °C(lit.)
Boiling point:
−60 °C(lit.)
vapor density 
1.19 (15 °C, vs air)
vapor pressure 
252 psi ( 21 °C)
FEMA 
3779 | HYDROGEN SULFIDE
Flash point:
-17℃
storage temp. 
2-8°C
pka
7(at 25℃)
explosive limit
6%
Merck 
13,4823
Stability:
Stable. Highly flammable. May form explosive mixture with air. Note wide explosive limits. Incompatible with strong oxidizing agents, many metals. May react violently with metal oxides, copper, fluorine, sodium, ethanal.
CAS DataBase Reference
7783-06-4(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F+,T+,N,F
Risk Statements  12-26-50-40-36/37-19-11
Safety Statements  9-16-36-38-45-61-28-26
RIDADR  UN 1053 2.3
WGK Germany  2
RTECS  MX1225000
HazardClass  2.3
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H220 Extremely flammable gas Flammable gases Category 1 Danger P210, P377, P381, P403
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H280 Contains gas under pressure; may explode if heated Gases under pressure Compressed gas
Liquefied gas
Dissolved gas
Warning P410+P403
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P410+P403 Protect from sunlight. Store in a well-ventilated place.

HYDROGEN SULFIDE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 742546 Hydrogen sulfide solution 0.8 M in THF 7783-06-4 25ml $122 2017-11-08 Buy
Sigma-Aldrich 295442 Hydrogen sulfide ≥99.5% 7783-06-4 227g $463 2017-11-08 Buy
Sigma-Aldrich 742546 Hydrogen sulfide solution 0.8 M in THF 7783-06-4 100ml $277 2017-11-08 Buy

HYDROGEN SULFIDE Chemical Properties,Uses,Production

Chemical Properties

colourless gas with strong odour of rotten eggs (odour threshold ca 0.2 ppt)

Definition

ChEBI: A sulfur hydride consisting of s single sulfur atom bonded to two hydrogen atoms. A highly poisonous, flammable gas with a characteristic odour of rotten eggs, it is often produced by bacterial decomposition of organic matter in the absence of oxygen.

Air & Water Reactions

Highly flammable; a flame can very easily flash back to the source of leak. Soluble in water to a maximum of 0.4% by mass at room temperature .

Reactivity Profile

HYDROGEN SULFIDE reacts as an acid and as a reducing agent. Explodes on contact with oxygen difluoride, bromine pentafluoride, chlorine trifluoride, dichlorine oxide, silver fulminate. May ignite and explode when exposed to powdered copper in oxygen [Mertz, V. et al., Ber., 1880, 13, p. 722]. May react similarly with other powdered metals. Ignites on contact with metal oxides and peroxides (barium peroxide, chromium trioxide, copper oxide, lead dioxide, manganese dioxide, nickel oxide, silver oxide, silver dioxide, thallium trioxide, sodium peroxide, mercury oxide, calcium oxide) [Mellor, 1947, vol. 10, p. 129, 141]. Ignites with silver bromate, lead(II) hypochlorite, copper chromate, nitric acid, lead(IV) oxide and rust. May ignite if passed through rusty iron pipes [Mee, A. J., School Sci. Rev., 1940, 22(85), p. 95]. Reacts exothermically with bases. The heat of the reaction with soda lime, sodium hydroxide, potassium hydroxide, barium hydroxide may lead to ignition or explosion of the unreacted portion in the presence of air / oxygen [Mellor, 1947, vol. 10, p. 140].

Health Hazard

Exposure to very high concentrations causes immediate death. Also death or permanent injury may occur after very short exposure to small quantities. It acts directly upon the nervous system resulting in paralysis of respiratory centers.

Fire Hazard

Compound is heavier than air and may travel a considerable distance to source of ignition and flash back. HYDROGEN SULFIDE forms explosive mixtures with air over a wide range. Also reacts explosively with bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, oxygen difluoride, and phenyl diazonium chloride. When heated to decomposition, HYDROGEN SULFIDE emits highly toxic fumes of oxides of sulfur. Incompatible with many materials including strong oxidizers, metals, strong nitric acid, bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, oxygen difluoride and phenyl diazonium chloride. Avoid physical damage to containers; sources of ignition; storage near nitric acid, strong oxidizing materials, and corrosive liquids or gases.

HYDROGEN SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products


HYDROGEN SULFIDE Suppliers

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