ChemicalBook >> CAS DataBase List >>1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE structure

CAS No.: 173035-10-4

Chemical Name:: 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE

Synonyms: SIMes.HCl;1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride;1,3-diMesityl-4,5-dihydro-1H-iMidazol-3-iuM chloride;1,3-Bis(2;inium ChL;1,3-Bis-(2,4,6-;1,3-Dimesitylimidazolidinium chloride;1,3-DiMesityliMidazolidin-1-iuM chloride;1,3-Bis-(2,4,6-trimethylphenyl)imidazolidinium;4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride

CBNumber:: CB0197636

Molecular Formula:: C21H29ClN2

Molecular Weight:: 344.92

MDL Number:: MFCD09039279

MOL File:: 173035-10-4.mol

MSDS File:: SDS

Last updated:2023-06-08 17:06:37

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1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Properties

Melting point	280-286 °C
storage temp.	Inert atmosphere,Room Temperature
form	Powder
color	Beige to pink-brown
Sensitive	air sensitive
InChIKey	COGMCBFILULEOS-UHFFFAOYSA-M
CAS DataBase Reference	173035-10-4

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

37/39-26-36

WGK Germany

TSCA

HS Code

29332990

NFPA 704

	0
2		0

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	656631	1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride 95%	173035-10-4	1g	$55.56	2024-03-01	Buy
Sigma-Aldrich	656631	1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride 95%	173035-10-4	5g	$155	2024-03-01	Buy
TCI Chemical	B3158	1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride >98.0%(HPLC)(T)	173035-10-4	1g	$71	2024-03-01	Buy
TCI Chemical	B3158	1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride >98.0%(HPLC)(T)	173035-10-4	5g	$247	2024-03-01	Buy
Strem Chemicals	07-4011	1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride, min. 97%	173035-10-4	500mg	$53	2024-03-01	Buy

Product number	Packaging	Price	Buy
656631	1g	$55.56	Buy
656631	5g	$155	Buy
B3158	1g	$71	Buy
B3158	5g	$247	Buy
07-4011	500mg	$53	Buy

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

beige to pink-brown powder

Uses

N-Heterocyclic Carbene Ligands

Precursor to an N-heterocyclic carbene catalysts used for:

A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.
Markovnikov-type hydration of terminal alkynes
Hydrosilylation of ketones and cycloaddition of azides and alkynes
Suzuki-Miyaura reactions
Luminescence experiments

Uses

N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts

General Description

1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride is an NHC (N-heterocyclic carbene) ligand which can bind with metal pre-catalysts to form complexes that show high catalytic activity.

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE synthesis

Synthesis of 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE from Formic acid and N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diamine,dihydrochloride

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Preparation Products And Raw materials

Raw materials

Methanimidamide, N,N'-bis(2,4,6-trimethylphenyl)- N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine N,N'-Bis(2,4,6-trimethylphenyl)ethylenediamine N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diamine,dihydrochloride Dichloromethane

Formic acid Triethyl orthoformate 2,4,6-Trimethybromombenzene 2,4,6-Trimethylaniline

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Preparation Products

1,3-Dimesitylimidazolidin-2-ylidene

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Suppliers

Global( 202)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Xi'an Kono chem co., Ltd.,	029-86107037 13289246953	info@konochemical.com	China	2995	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10828	58

Supplier	Advantage
Springchem New Material Technology Co.,Limited	57
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58
Xi'an Kono chem co., Ltd.,	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58

View Lastest Price from 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-03-18	1,3-Dimesitylimidazolidin-1-ium chloride 173035-10-4	US $1.00 / g	10g	99.8%	3000000	Hebei Endun Biological Technology Co. LTD
2021-07-02	1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride 173035-10-4	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2020-11-16	1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 173035-10-4	US $9.00 / Kg/Bag	25Kg/Bag	99%	20 Tons	Longyan Tianhua Biological Technology Co., Ltd

1,3-Dimesitylimidazolidin-1-ium chloride
173035-10-4
US $1.00 / g
99.8%
Hebei Endun Biological Technology Co. LTD

1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride
173035-10-4
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
173035-10-4
US $9.00 / Kg/Bag
99%
Longyan Tianhua Biological Technology Co., Ltd

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Spectrum

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE(173035-10-4)¹HNMR 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE(173035-10-4)¹³CNMR

173035-10-4(1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE)Related Search:

1,3-Bis (2,6-diisopropylphenyl) imidazolium chloride 1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 1,3-Bis(2,6-di-isopropylphenyl)imidazol-2-ylidenegold(I)chloride,95% Ruthenium(III) chloride hydrate (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM GRUBBS CATALYST 2ND GENERATION 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride

Umicore M42 Tricyclohexylphosphine[3-phenyl-1H-inden-1-ylidene][1,3-bis(2,4,6-triMethylphenyl)-4,5-dihydroiMidazol-2-ylidene]rutheniuM(II) Umicore M41 (1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDA& Isopentenylidene(1,3-dimesitylimidazolidin-2-ylidene) (tricyclohexylphosphine)ruthenium(II) dichloride

RUTHENIUM, [1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-[[2-ISOPROPOXY-5-(N-RESIN-LINKED AMINOSULFONYL)PHENYL]METHYLENE] TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE][(PHENYLTHIO)METHYLENE]RUTHENIUM (II) DICHLORIDE [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II)

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N,Nμ-(2,4,6-Trimethylphenyl)dihydroimidazolium chloride 1,3-Bis(2,4,6-trimethylphenyl)-imidazolidinium-chlorid 1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDRO-1H-IMIDAZOLIUM CHLORIDE 1,3-Bis-(2,4,6-trimethyl-phenyl)-imidazolidin-1-ium chloride 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE 1,3-Bis-(2,4,6-trimethylphenyl)imidazolidinium 1,3-Bis(2,4,6-trimethylphenyl)imidazolidiniumchloride,97% 1,3-Bis-(2,4,6- 1,3-Bis(2,4,6-trimethylphenyl)imidazolidinium-chloride,98+%,TLC 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride, min. 97% 1,3-Bis-(2,4,6-triMethylphenyl)-4,5-dihydro-3H-iMidazol-1-iuM chloride 1,3-Bis(2,4,6-triMethlyphenyl)iMidazoliniuM Chloride 1,3-DiMesityliMidazolidin-1-iuM chloride 1,3-Bis(2,4,6-triMethylphenyl)iMidazoliniuM chloride 95% 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride,97% 1,3-Dimesitylimidazolidinium chloride 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium chloride 4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-1-ium chloride 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride, SIMes.HCl 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride > 1,3-Bis(2 inium ChL 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chlori SIMes.HCl 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride 1,3-diMesityl-4,5-dihydro-1H-iMidazol-3-iuM chloride 173035-10-4 C21H29ClN2 C21H28N C21H27ClN2 C23H33N Achiral Nitrogen NHC Ligands N-Heterocyclic Carbene Ligands Synthetic Organic Chemistry