[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside

CAS No.
23544-46-9
Chemical Name:
[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside
Synonyms
Ipalbine;4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside;[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside;β-D-Glucopyranoside, 4-[(8aS)-1,2,3,5,8,8a-hexahydro-7-methyl-6-indolizinyl]phenyl
CBNumber:
CB02345493
Molecular Formula:
C21H29NO6
Molecular Weight:
391.46
MDL Number:
MOL File:
23544-46-9.mol

[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Properties

Melting point 118 °C
Boiling point 615.6±55.0 °C(Predicted)
Density 1.38±0.1 g/cm3(Predicted)
pka 12.83±0.70(Predicted)

[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Chemical Properties,Uses,Production

Description

This alkaloid, which is the O-~-D-glucoside of ipalbidine, also occurs in Ipomoea alba L. It is dextrorotatory with [α]23D + 32.5° (c 0.03, EtOH). The structure has been confirmed by the total synthesis from 2-methoxypyrroline and the methyl ester of acetylacetic acid.

References

Gourley et al., Chem. Commun., 709 (1969) Total synthesis: Wick, Bartlett, Dolphin., Helv. Chim. Acta., 54, 513 (1971)

[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Preparation Products And Raw materials

Raw materials

Preparation Products

[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Suppliers

Global( 4)Suppliers
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[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Ipalbine β-D-Glucopyranoside, 4-[(8aS)-1,2,3,5,8,8a-hexahydro-7-methyl-6-indolizinyl]phenyl 4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside 23544-46-9