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(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester

CAS No.
14019-66-0
Chemical Name:
(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester
Synonyms
Uncarine F;(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester;(1'S,3R,4'aS,5'aR,10'aS)-1,2,5',5'a,7',8',10',10'a-Octahydro-1'-methyl-2-oxospiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid methyl ester;Spiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid, 1,2,5',5'a,7',8',10',10'a-octahydro-1'-methyl-2-oxo-, methyl ester, (1'S,3R,4'aS,5'aR,10'aS)-
CBNumber:
CB02362913
Molecular Formula:
C21H24N2O4
Molecular Weight:
368.43
MDL Number:
MOL File:
14019-66-0.mol
Last updated:2023-05-04 17:34:33

(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Properties

Boiling point 555.2±50.0 °C(Predicted)
Density 1.33
pka 13.56±0.60(Predicted)
FDA UNII 9968028I8W

(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Chemical Properties,Uses,Production

Description

An Uncaria alkaloid, this base forms a colourless, non-crystallizable glass. The specific rotation is [α]D + 84° (CHCI3 ). It is stereoisomeric with the other alkaloids of this species just described.

Definition

ChEBI: Uncarine F is a member of indolizines.

References

Hart, Johns, Lamberton., Chem. Commun., 87 (1967)
Hemingway, Phillipson., J. Pharm. Pharmacol., 24, 169P (1972)
Circular dichroism: Beecham et al., Tetrahedron Lett., 991 (1967)

(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Suppliers

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Chengdu Push Bio-Technology Co., Ltd. 18080489829 3004654993@qq.com China 9209 58
(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester (1'S,3R,4'aS,5'aR,10'aS)-1,2,5',5'a,7',8',10',10'a-Octahydro-1'-methyl-2-oxospiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid methyl ester Uncarine F Spiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid, 1,2,5',5'a,7',8',10',10'a-octahydro-1'-methyl-2-oxo-, methyl ester, (1'S,3R,4'aS,5'aR,10'aS)- 14019-66-0