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Diallyl phthalate

CAS No.
131-17-9
Chemical Name:
Diallyl phthalate
Synonyms
DAP;Dially Phthalate;DAP(Diallyl Phthalate);Dappu;daponr;Dapon R;dapon35;Dapon 35;RX 1-501N;NCI-C50657
CBNumber:
CB0246486
Molecular Formula:
C14H14O4
Molecular Weight:
246.26
MDL Number:
MFCD00008646
MOL File:
131-17-9.mol
MSDS File:
SDS
Last updated:2023-10-21 14:53:33

Diallyl phthalate Properties

Melting point -70 °C
Boiling point 165-167 °C/5 mmHg (lit.)
Density 1.121 g/mL at 25 °C (lit.)
vapor density 8.3 (vs air)
vapor pressure 2.3 mm Hg ( 150 °C)
refractive index n20/D 1.519(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,2-8°C
solubility 0.18g/l
form Liquid
color Clear colorless to light yellow
Odor mild odor
Water Solubility 6 g/L (20 ºC)
BRN 1880877
InChIKey QUDWYFHPNIMBFC-UHFFFAOYSA-N
LogP 3.23 at 20℃
CAS DataBase Reference 131-17-9(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances DIALLYL PHTHALATE
FDA 21 CFR 175.105; 176.180
EWG's Food Scores 1
FDA UNII F79L0UL6ST
NIST Chemistry Reference 1,2-Benzenedicarboxylic acid, di-2-propenyl ester(131-17-9)
EPA Substance Registry System Diallyl phthalate (131-17-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H302+H332-H317-H410
Precautionary statements  P261-P273-P280-P301+P312-P302+P352-P304+P340+P312
Hazard Codes  Xn,N
Risk Statements  22-50/53
Safety Statements  24/25-60-61
RIDADR  UN 3082 9/PG 3
WGK Germany  2
RTECS  CZ4200000
19
Autoignition Temperature 725 °F
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29173400
NFPA 704
1
1 1

Diallyl phthalate price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 269379 Diallyl phthalate 97% 131-17-9 250ml $32.4 2024-03-01 Buy
Sigma-Aldrich 269379 Diallyl phthalate 97% 131-17-9 1l $64.2 2024-03-01 Buy
TCI Chemical P0290 Diallyl Phthalate >98.0%(GC) 131-17-9 25mL $22 2024-03-01 Buy
TCI Chemical P0290 Diallyl Phthalate >98.0%(GC) 131-17-9 500mL $42 2024-03-01 Buy
Alfa Aesar B24648 Diallyl phthalate, 97% 131-17-9 100g $15.65 2024-03-01 Buy
Product number Packaging Price Buy
269379 250ml $32.4 Buy
269379 1l $64.2 Buy
P0290 25mL $22 Buy
P0290 500mL $42 Buy
B24648 100g $15.65 Buy

Diallyl phthalate Chemical Properties,Uses,Production

Chemical Properties

clear colourless to light yellow liquid

Uses

Diallyl Phthalate is used as a reagent in ring-closing ruthenium based reactions.

Application

Diallyl phthalate is an important monomer for the production of thermosetting molding compounds, which must have good dimensional stability and electrical properties, and be resistant to heat and solvents. Diallyl phthalate can be polymerized or copolymerized. This usually is done by dissolving the diallyl phthalate monomer in 2- propanol, adding 50% hydrogen peroxide at about 105 ℃, and precipitating the prepolymer from the cooled, viscous solution with excess 2- propanol. Copolymers containing diallyl phthalate are suitable for specialty coating and for embedding, especially in the production of electronic devices. For example, the moisture-sensitive epoxy compounds now used in light-emitting diode (LED) displays can be replaced by stable diallyl phthalate epoxy encapsulating resins. By adding inorganic materials to diallyl phthalate prepolymer compositions, reinforced thermosetting molding compounds can be obtained. Glass cloth or paper can be impregnated with a solution of prepolymer, monomer, and peroxide initiator. After removal of the solvent, the glass cloth or paper is cured to give the desired film-protected material, which is used for decoration, stain-resistant overlays for household articles, and furniture.

Preparation

Diallyl phthalate (DAP) is prepared by reaction of phthalic anhydride and allyl alcohol:

131-17-9 synthesis

General Description

Clear pale-yellow liquid. Odorless.

Air & Water Reactions

Incompatible with water and oxygen. Should be stored air tight, with inhibitor, to prevent polymerization reaction .

Reactivity Profile

Diallyl phthalate can react with oxidizers. Diallyl phthalate can also react with acids and alkalis. Diallyl phthalate is incompatible with water and oxygen.

Fire Hazard

Diallyl phthalate is combustible.

Flammability and Explosibility

Not classified

Safety Profile

Suspected carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, intraperitoneal, and subcutaneous routes. An eye irritant. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use CO2 or dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.

Carcinogenicity

In the 103-week study referred to previously, a slight increase in MNCL was seen in female rats treated with 50 or 100 mg/kg/day of DAP. MNCL occurs in F344 control rats at a high incidence; however, the incidence of 51% in female rats at the high dose level was above historical control data for the laboratory (29%). No significant increases in tumor incidences were seen in male rats. Based on this study, DAP was considered to have demonstrated equivocal evidence for carcinogenicity in female F344 rats according to the NTP.
In male and female B6C3F1 mice receiving 300 mg/kg of DAP by gavage for 103 weeks (5 days/week), the incidence of forestomach papillomas was significantly greater than that of controls. Because of the rarity of forestomach papillomas in control B6C3F1 mice and the concomitant observation of dose-related forestomach hyperplasia, the development of these tumors was considered to be test substance related. Compared to controls, a slight increase in the incidence of lymphomas was observed in males receiving 300 mg/kg/day of DAP. Because the increase was not statistically significant compared to historical control data, this effect was not considered to be test substance related.

85-44-9
107-18-6
131-17-9
Synthesis of Diallyl phthalate from Phthalic anhydride and Allyl alcohol

Diallyl phthalate Preparation Products And Raw materials

Global( 411)Suppliers
Supplier Tel Email Country ProdList Advantage
Shouguang Nuomeng Chemical Co Ltd.
536-5119508 18363669993; export@nuomengchem.com China 44 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7377 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9352 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58

View Lastest Price from Diallyl phthalate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diallyl phthalate pictures 2024-01-11 Diallyl phthalate
131-17-9
US $122.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Diallyl phthalate, DAP monomer pictures 2023-12-26 Diallyl phthalate, DAP monomer
131-17-9
US $3500.00 / T 1KG 99.5% 120 tons per month Shouguang Nuomeng Chemical Co Ltd.
Diallyl phthalate pictures 2023-03-27 Diallyl phthalate
131-17-9
US $5.00 / KG 1KG 99.9% 500MT/month XINGTAI XINGJIU NEW MATERIAL TECHNOLOGY CO., LTD
  • Diallyl phthalate pictures
  • Diallyl phthalate
    131-17-9
  • US $5.00 / KG
  • 99.9%
  • XINGTAI XINGJIU NEW MATERIAL TECHNOLOGY CO., LTD
DIALLYL PHTHALATE OEKANAL, 250 MG di-2-propenyl1,2-benzenedicarboxylate Diallyl ester of phthalic acid Diallyl ester o-phthalic acid Diallylester kyseliny ftalove Diallylester phthalic acid diallylesterkyselinyftalove diallylesterkyselinyftalove(czech) diallylphthalate-1,2-benzenedicarboxylicacid,di-2-propenylester NCI-C50657 Nonflammable decobest DA RX 1-501N RX 3-1-530 Diallyl-o-phthalate DIALLYL ORTHO-PHTHALATE DIALLYL PHTHALATE DI-(2-PROPENY)PHTHALATE Dapon 35 Dapon R dapon35 Daponite sheet daponr Dipropen-2-yl Phthalate Diallyl phthalate(DAP) Dappu Phthalic acid diallyl Diallyl phthalate,98% DIALLYL PHTHALATE FOR SYNTHESIS Phthalsurediallylester Diallyl phthalate 10g [131-17-9] DAP MonoMer Diallyl phthalate, 98% 1LT The phthalateesters of acrylicacidtwotwo Diallyl phthalate 97% o-Phthalic acid,diallyl ester PHTHALIC ACID DIALLYL ESTER PHTHALIC ACID, BIS-ALLYL ESTER Diallyl phthalate Solution, 100ppm ALLYL PHTHALATE 1,2-BENZENEDICARBOXYLIC ACID DI-2-PROPENYL ESTER Diallyl phthalate Solution DiallylPhthalate> DIALLYL PHTHALTE MONOMER bis(prop-2-enyl) benzene-1,2-dicarboxylate 7-Dihydroxy-4-Phenylchromen-2-One 7-dihydroxy-4-phenylcoumarin DAP(Diallyl Phthalate) DAP Dially Phthalate O-benzenedicarboxylic acid diallyl ester 131-17-9 C6H4COOCH2CHCH22 C6H412CO2CH2CHCH22 C14H14O4 Carbonyl Compounds C12 to C63 Building Blocks Organic Building Blocks