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ChemicalBook >> CAS DataBase List >>(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Structure
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide structure
CAS No.
864943-22-6
Chemical Name:
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
Synonyms
SF110065;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e.;(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate;4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide;(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin
CBNumber:
CB02614267
Molecular Formula:
C48H29O4P
Molecular Weight:
700.72
MDL Number:
MFCD12546016
MOL File:
864943-22-6.mol
Last updated:2022-12-30 16:20:48
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(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Properties

Melting point 390-400°C
Density 1.46±0.1 g/cm3(Predicted)
storage temp. -20°C
pka 1.11±0.20(Predicted)
optical activity [α]22/D 44.0°, c = 1 in DMSO
CAS DataBase Reference 864943-22-6

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315
Precautionary statements  P264-P280-P302+P352-P332+P313-P362+P364
WGK Germany  3
HS Code  2919900090

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 700665 (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide 864943-22-6 100mg $158.4 2024-03-01 Buy
Strem Chemicals 15-0552 (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98% 98% 864943-22-6 50mg $271 2024-03-01 Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 864943-22-6 1g $625 2021-12-16 Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 864943-22-6 5g $2165 2021-12-16 Buy
Ambeed A996076 (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diylHydrogenPhosphate 98% 864943-22-6 250mg $215 2021-12-16 Buy
Product number Packaging Price Buy
700665 100mg $158.4 Buy
15-0552 50mg $271 Buy
A996076 1g $625 Buy
A996076 5g $2165 Buy
A996076 250mg $215 Buy

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Chemical Properties,Uses,Production

Uses

Catalyst for:

  • Asymmetric hydrogenation cascade
  • Enantioselective Friedel-Crafts reaction
  • Asymmetric hydrogenation of 2-substituted quinolines
  • Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
  • Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
  • Asymmetric transfer hydrogenation of substituted quinoxalines

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Suppliers

Global( 40)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Career Henan Chemica Co 		+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
CR Corporation Lomited 		fred.wen@crcorporation.cn CHINA 12069 58
Labnetwork lnc. 		+86-27-50766799 +8618062016861 contact@labnetwork.com China 19994 58
LEAPCHEM CO., LTD. 		+86-852-30606658 market18@leapchem.com China 43348 58
Shanghai Acmec Biochemical Technology Co., Ltd. 		+undefined18621343501 product@acmec-e.com China 33349 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
Shanghai Suifu Chemical Technology CO.,LTD. +86-021-33738187 +86-17736114707 suifuchemical@163.com China 585 58
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6818 65
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 2918 50
Supplier Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		58
Career Henan Chemica Co 		58
CR Corporation Lomited 		58
Labnetwork lnc. 		58
LEAPCHEM CO., LTD. 		58
Shanghai Acmec Biochemical Technology Co., Ltd. 		58
Aladdin Scientific 		58
Shanghai Suifu Chemical Technology CO.,LTD. 58
Daicel Chiral Technologies (China)CO.,LTD 65
Tianjin Derchemist Science & Technology Co., Ltd. 50

864943-22-6((11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide)Related Search:

R-4-oxide-4-hydroxy-2,6-bis(4-Methoxyphenyl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate Ir(I)/(S)-t-Bu-PHOX S-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
R-4-oxide-4-hydroxy-2,6-di-2-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-Dibromo-2,2'-bis(meth (R)-3,3'-DIBROMO-2,2'-DIMETHOXY-1,1'-BINAPHTHYL R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol R-3,3'-di-9-phenanthrenyl-1,1'-Binaphthalene]-2,2'-diol
R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol R-2,2'-bis(methoxymethoxy)-3,3'-diphenyl-1,1'-Binaphthalene R-3,3'-diiodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene (R)-NOBIN R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
R-3,3'-bis[4-(trifluoroMethyl)phenyl]-[1,1'-Binaphthalene]-2,2'-diol R-4-oxide-2,6-di-9-anthracenyl-8,9,10,11,12,13,14,15-octahydro-4-hydroxy--Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

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(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide (11bS)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide,99%e.e. (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate SF110065 (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-di-9-phenanthrenyl-, 4-oxide, (11bR)- 4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-Bis(9-phenanthrenyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate 864943-22-6