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Methyl 4-formylbenzoate

CAS No.
1571-08-0
Chemical Name:
Methyl 4-formylbenzoate
Synonyms
METHYL P-FORMYLBENZOATE;METHYL TEREPHTHALALDEHYDATE;METHYL BENZALDEHYDE-4-CARBOXYLATE;NSC 28459;AKOS BBS-00003165;TIMTEC-BB SBB008362;Methyl 4-formylbenzo;OTAVA-BB BB7018801965;Mehyl4-Formylbenzoate;Methyl-4-formylbenzoat
CBNumber:
CB0333234
Molecular Formula:
C9H8O3
Molecular Weight:
164.16
MDL Number:
MFCD00006950
MOL File:
1571-08-0.mol
MSDS File:
SDS
Last updated:2023-08-30 13:35:17

Methyl 4-formylbenzoate Properties

Melting point 59-63 °C (lit.)
Boiling point 265 °C (lit.)
Density 1,2 g/cm3
refractive index 1.5260 (estimate)
Flash point 144 °C
storage temp. Store below +30°C.
solubility methanol: 0.1 g/mL, clear
form Crystalline Powder or Chunks
color White to cream or slightly green
Water Solubility insoluble
Sensitive Air Sensitive
BRN 775895
Stability Stable, though possibly air-sensitive. Combustible. Incompatible with strong oxidizing agents.
InChIKey FEIOASZZURHTHB-UHFFFAOYSA-N
LogP 2.050 (est)
CAS DataBase Reference 1571-08-0(CAS DataBase Reference)
FDA UNII NH766742VV
NIST Chemistry Reference 4-HC(O)-C6H4-COOCH3(1571-08-0)
EPA Substance Registry System Benzoic acid, 4-formyl-, methyl ester (1571-08-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xn,Xi
Risk Statements  36/37/38-20/21/22
Safety Statements  22-24/25
WGK Germany  2
Hazard Note  Irritant
TSCA  Yes
HS Code  29183000
NFPA 704
1
2 0

Methyl 4-formylbenzoate price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 244740 Methyl 4-formylbenzoate 99% 1571-08-0 5g $131 2024-03-01 Buy
Sigma-Aldrich 244740 Methyl 4-formylbenzoate 99% 1571-08-0 25g $182 2024-03-01 Buy
TCI Chemical T0012 Methyl Terephthalaldehydate >98.0%(GC) 1571-08-0 25g $44 2024-03-01 Buy
TCI Chemical T0012 Methyl Terephthalaldehydate >98.0%(GC) 1571-08-0 100g $132 2024-03-01 Buy
Alfa Aesar B24091 Methyl 4-formylbenzoate, 98+% 1571-08-0 5g $40.65 2024-03-01 Buy
Product number Packaging Price Buy
244740 5g $131 Buy
244740 25g $182 Buy
T0012 25g $44 Buy
T0012 100g $132 Buy
B24091 5g $40.65 Buy

Methyl 4-formylbenzoate Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Uses

4-Formylbenzoic Acid Methyl Ester is a benzoic acid derivative with antioxidant activity.

Uses

Methyl 4-formylbenzoate is used in the preparation of dimethyl terephthalate. It is also used as an active pharmaceutical ingredient intermediate and fluorescent brightener intermediate.

Synthesis Reference(s)

Tetrahedron, 64, p. 688, 2008 DOI: 10.1016/j.tet.2007.11.030

General Description

Needles (in water) or white powder.

Air & Water Reactions

Methyl 4-formylbenzoate may be sensitive to prolonged exposure to air. . Insoluble in water.

Reactivity Profile

Methyl 4-formylbenzoate is an aldehyde/ester. Aldehydes are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

Flash point data for Methyl 4-formylbenzoate are not available. Methyl 4-formylbenzoate is probably combustible.

619-66-9
119-36-8
69-72-7
1571-08-0
Synthesis of Methyl 4-formylbenzoate from 4-Formylbenzoic acid and Methyl salicylate
Global( 396)Suppliers
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Nanjing Qiangshan New Material Co.,Ltd.
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View Lastest Price from Methyl 4-formylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 4-formylbenzoate pictures 2023-08-30 Methyl 4-formylbenzoate
1571-08-0
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Methyl 4-Formylbenzoate  pictures 2023-05-24 Methyl 4-Formylbenzoate
1571-08-0
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
Methyl 4-formylbenzoate pictures 2023-04-18 Methyl 4-formylbenzoate
1571-08-0
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
Methyl 4-formylbenzoate,99% Methyl 4-formylbenzoate,95% Methyl 4-formylbenzoate,Methyl benzaldehyde-4-carboxylate, Methyl terephthalaldehydate Methyl 4-formylbenzo Methyl 4-forMylbenzoate, 99% 10GR NSC 28459 Para(Methoxycarbonyl)benzaldehyde 4-Formylbenzoic Acid Methyl Ester Methyl 4-Formylbenzoate Terephthalaldehydic Acid Methyl Ester METHYL 4-FORMYLBENZOATE FOR SYNTHESIS Methyl 4-forMylbenzoate, 98+% 4-forMylbenzoate Methyl P-CarbonMethoxybenzaldehyde The acyl Methyl benzoic acid methyl 4-methanoylbenzoate 2-Methoxycarbonylbenzaldehyde 4-formyl-benzoicacimethylester Terephthalaldehydic acid methyl TIMTEC-BB SBB008362 TEREPHTHALALDEHYDIC ACID METHYL ESTER TEREPHTHALALDEHYDIO ACID METHYL ESTER OTAVA-BB BB7018801965 P-CARBOMETHOXYBENZALDEHYDE P-METHOXYCARBONYLBENZALDEHYDE Terephthalaldehyde acid methylester Mehyl4-Formylbenzoate METHYL-PARA-FORMYLBENZOATE Methyl-4-formylbenzoat 4-Formylbenzoic acid methyl Benzoic acid, 4-formyl-, methyl ester Methyl terephthaldehydate methylterephthaldehydate p-Formylbenzoic acid methyl ester p-formylbenzoicacidmethylester METHYL TEREPHTHALADEHYDATE METHYL 4-FORMYLBENZOATE LABOTEST-BB LT00941130 4-(methoxycarbonyl)benzaldehyde 4-FORMYLBENZOIC ACID METHYL ESTER 4-CARBOMETHOXYBENZALDEHYDE 4-carboxybenzaldehyde methyl ester AKOS BBS-00003165 Methyl benzaldehyde-4-carboxylate, Methyl terephthalaldehydate Methyl Terephthalaldehydate > METHYL P-FORMYLBENZOATE METHYL BENZALDEHYDE-4-CARBOXYLATE METHYL TEREPHTHALALDEHYDATE 2H4]-Methyl Terephthalaldehydate Bifeprunox Impurity 29 1571-08-0 HCOC6H4CO2CH3 ALDEHYDE Building Blocks Aldehydes Carbonyl Compounds C9 Organic Building Blocks Aromatic Aldehydes & Derivatives (substituted) Intermediates of Dyes and Pigments