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L(-)-10-Camphorsulfonyl chloride

CAS No.
39262-22-1
Chemical Name:
L(-)-10-Camphorsulfonyl chloride
Synonyms
((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride;(1R)-(-)-10-CamphorsuL;R)-()-10-CaMphorsulfony;L(-)Camphor sulfonyl chloride;(-)-10-CAMPHORSULFONYL CHLORIDE;(-)-10-Camphorsulfonyl Chloride;(-)-CAMPHOR-10-SULFONYL CHLORIDE;L(-)-10-CAMPHORSULFONYL CHLORIDE;(+)-camphor-10-sulfonyl chloride;L-(-)-1-Camphorsulfonyl chloride
CBNumber:
CB0356635
Molecular Formula:
C10H15ClO3S
Molecular Weight:
250.74
MDL Number:
MFCD00064155
MOL File:
39262-22-1.mol
MSDS File:
SDS
Last updated:2023-08-31 16:33:09

L(-)-10-Camphorsulfonyl chloride Properties

Melting point 66-68 °C(lit.)
alpha -33 º (c=3, chloroform)
Boiling point 349.4±15.0 °C(Predicted)
Density 1.331±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Acetone, Dichloromethane, Ethyl Acetate, Methanol
form Solid
color White
optical activity [α]18/D 33°, c = 3 in chloroform
Water Solubility Decomposes
Sensitive Moisture Sensitive
BRN 3205975
InChIKey BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference 39262-22-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
HazardClass  8
PackingGroup  II
HS Code  29147090
NFPA 704
1
3 0

L(-)-10-Camphorsulfonyl chloride price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 301949 (1R)-(?)-10-Camphorsulfonyl chloride 97% 39262-22-1 5g $65.6 2023-01-07 Buy
TCI Chemical C1308 (-)-10-Camphorsulfonyl Chloride >98.0%(T) 39262-22-1 5g $42 2024-03-01 Buy
TCI Chemical C1308 (-)-10-Camphorsulfonyl Chloride >98.0%(T) 39262-22-1 25g $168 2024-03-01 Buy
TRC C175070 (1R)-(?)-10-Camphorsulfonyl chloride 39262-22-1 10g $415 2021-12-16 Buy
American Custom Chemicals Corporation HCH0415093 (1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE 95.00% 39262-22-1 2G $825 2021-12-16 Buy
Product number Packaging Price Buy
301949 5g $65.6 Buy
C1308 5g $42 Buy
C1308 25g $168 Buy
C175070 10g $415 Buy
HCH0415093 2G $825 Buy

L(-)-10-Camphorsulfonyl chloride Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.

Uses

A chiral derivative of Camphor.

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 173)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 29220 58
Baoji Guokang Bio-Technology Co., Ltd.
0917-3909592 13892490616 gksales1@gk-bio.com China 9339 58

View Lastest Price from L(-)-10-Camphorsulfonyl chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
L(-)-10-Camphorsulfonyl chloride pictures 2023-08-31 L(-)-10-Camphorsulfonyl chloride
39262-22-1
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
L(-)-10-Camphorsulfonyl chloride pictures 2021-09-02 L(-)-10-Camphorsulfonyl chloride
39262-22-1
US $10.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
L(-)-10-Camphorsulfonyl chloride pictures 2021-08-12 L(-)-10-Camphorsulfonyl chloride
39262-22-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
L(-)-10-CAMPHORSULFONYL CHLORIDE (-)-CAMPHOR-10-SULFONYL CHLORIDE (1R)-(-)-10-CAMPHORSULFONYL CHLORIDE (1R)-(-)-CAMPHOR-10-SULPHONYL CHLORIDE (1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORIDE (1R)-CAMPHOR-10-SULFONIC ACID CHLORIDE (1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE (-)-10-CAMPHORSULFONYL CHLORIDE (1R)-(-)-10-CAMPHORSULFONYL CHLORIDE, 97 % (1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORIDE 98+% 6,(1R)-(-)-10-Camphorsulfonylchloride Bicyclo2.2.1heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1R,4S)- (-)-Camphor-10-sulphonyl chloride L(-)Camphor sulfonyl chloride (1R)-CaMphor-1-sulfonic acid chloride (-)-Camphor-10-sulfonyl chloride, (1R)-Camphor-10-sulfonic acid chloride (7,7-Dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonyl chloride (1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfochloride [1R,4R,(-)]-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid chloride L(-)-10-Camphorsulfonyl chloride,97% (1R,4S)-7,7-DiMethyl-2-oxo-bicyclo[2.2.1]heptane-1-Methanesulfonyl Chloride (1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORI R)-()-10-CaMphorsulfony L-10- of caMphorsulfonyl chloride L(-)-10-Camphorsulfonyl chloride (1R)-Camphor-10-sulfonic acid chloride (1R)-()-10-Camphorsulfonyl chloride (1R)-(-)-10-Camphorsulfonyl chloride 97% (1R)-(-)-Camphor-10-sulfonic acid chloride for synthesis [(1S,4R)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride (-)-10-Camphorsulfonyl Chloride > (1R)-(-)-10-CamphorsuL L(-)-10-Camphorsulfonyl chloride USP/EP/BP (+)-camphor-10-sulfonyl chloride L-(-)-1-Camphorsulfonyl chloride (-)-10-Camphorsulfonyl Chloride [3-(chlorosulfonylmethyl)-2,2,3-trimethylcyclopentyl]methanesulfonyl chloride ((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride 39262-22-1 C10H15O3Cl Bicyclic Monoterpenes Terpenes for Resolution of Bases for Resolution of Alcohols & Thiols Optical Resolution SULFONYL CHLORIDE Peptide Intermediates & Fine Chemicals Pharmaceuticals Sulfonyl Chlorides chiral Chiral Reagents Bicyclic Monoterpenes Biochemistry for Resolution of Alcohols & Thiols for Resolution of Bases Optical Resolution Synthetic Organic Chemistry Terpenes