ChemicalBook >> CAS DataBase List >>(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE structure

CAS No.: 147253-67-6

Chemical Name:: (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE

Synonyms: an-1-yL;(R,R)-ME-DUPHOS;(R,R)-METHYL-DUPHOS;()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene;1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene;(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE;1,2-bis((2R,5R)-2,5-dimethylphospholan-1-yl)benzene;(-)-1,2-bis-((2R,5R)-2,5-Dimethylphospholano)benzene;(-) -1,2-bis ((2R, 5R) -2,5-dimethylphosphorus) benzene;1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]benzene, 97+%

CBNumber:: CB0456508

Molecular Formula:: C18H28P2

Molecular Weight:: 306.36

MDL Number:: MFCD00142336

MOL File:: 147253-67-6.mol

Last updated:2023-04-23 13:52:06

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(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Properties

Melting point	66-76 °C
Boiling point	415.0±15.0 °C(Predicted)
alpha	-476° (c 1, hexane)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	crystal
color	white
optical activity	[α]20/D -420±15°, c = 0.5 in methylene chloride
Water Solubility	Insoluble in water.
Sensitive	Air Sensitive
BRN	4810602
CAS DataBase Reference	147253-67-6
FDA UNII	H5W03D1HAQ

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P280-P302+P352-P362+P364

Safety Statements

22-24/25

WGK Germany

10-23

HS Code

2934999090

NFPA 704

	1
0		0

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE price More Price(22)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	665258	(?)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene kanata purity	147253-67-6	100mg	$78.5	2023-06-20	Buy
TCI Chemical	B2436	1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene	147253-67-6	100MG	$65	2024-03-01	Buy
TCI Chemical	B2436	1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene	147253-67-6	500MG	$269	2024-03-01	Buy
Alfa Aesar	H60592	1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene, 97+%	147253-67-6	250mg	$125.65	2024-03-01	Buy
Alfa Aesar	H60592	1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene, 97+%	147253-67-6	1g	$424.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
665258	100mg	$78.5	Buy
B2436	100MG	$65	Buy
B2436	500MG	$269	Buy
H60592	250mg	$125.65	Buy
H60592	1g	$424.65	Buy

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Chemical Properties,Uses,Production

Reactions

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses.
Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides.
Asymmetric hydrogenation of vinyl alcohols.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
Asymmetric hydrogenation of allylic alcohols.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.

Uses

1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff. It is used as highly efficient privileged ligands.

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE synthesis

Synthesis of (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE from 1,2-BIS(PHOSPHINO)BENZENE and (2S,5S)-Hexane-2,5-diol cyclic sulfate

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Preparation Products And Raw materials

Raw materials

(2S,5S)-Hexane-2,5-diol cyclic sulfate 1,2-BIS(PHOSPHINO)BENZENE

Preparation Products

1,1′-(1,2-Phenylene)bis(phospholane)

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Suppliers

Global( 76)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
NINGBO INNO PHARMCHEM CO., LTD.	13867897135	sales@nbinno.com	CHINA	925	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
Alfa Chemistry	+1-5166625404	Info@alfa-chemistry.com	United States	21317	58
PT CHEM GROUP LIMITED	+86-85511178 +86-85511178	peter68@ptchemgroup.com	China	35453	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	49999	58
Henan Allgreen Chemical Co.,LTD	+86-37155567971 +86-13633837469	info@allgreenchem.com	China	5986	58
Suzhou Origin Specialty Chemicals Co., Ltd.	+86-512-68662322 +86-17312436797	hanqun@origsc.com	China	733	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+undefined18621343501	product@acmec-e.com	China	33349	58
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	57511	58

Supplier	Advantage
ATK CHEMICAL COMPANY LIMITED	60
NINGBO INNO PHARMCHEM CO., LTD.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Alfa Chemistry	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Henan Allgreen Chemical Co.,LTD	58
Suzhou Origin Specialty Chemicals Co., Ltd.	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
Aladdin Scientific	58

View Lastest Price from (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene 147253-67-6	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene
147253-67-6
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

147253-67-6((-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE)Related Search:

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene,98+%(S,S)-Me-DUPHOS,(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE (3R,6R)-3,6-OCTANEDIOL (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE (R)-5-fluoro-3-methylisobenzofuran-1(3H)-one

(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE (S)-5-fluoro-3-methylisobenzofuran-1(3H)-one (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate (S,S)-I-PR-DUPHOS

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene monooxide (-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

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(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(r,r)-me-duphos (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene,98+%(R,R)-Me-DUPHOS (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene, (R,R)-Me-DUPHOS,98+% ()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene,(2R,2’R,5R,5′R)-2,2′,5,5′-Tetramethyl-1,1′-(o-phenylene)diphospholane, (R,R)-Me-DUPHOS, (R,R)-Methyl-DUPHOS 1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]benzene, 97+% (2R,5R,2'R,5'R)-1,1'-(1,2-Phenylene)bis(2,5-dimethylphospholane) 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene (R,R)-ME-DUPHOS (R,R)-METHYL-DUPHOS ()-1,2-Bis[(2R,5R)-2,5-diMethylphospholano]benzene,>=95.0% (2R,2'R,5R,5'R)-2,2',5,5'-TETRAMETHYL-1,1'-(1,2-PHENYLENE)DIPHOSPHOLANE (2R,2'R,5R,5'R)-2,2',5,5'-TETRAMETHYL-1,1'-(O-PHENYLENE)DIPHOSPHOLANE (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE, KANATA PURITY 1,2-bis((2R,5R)-2,5-dimethylphospholan-1-yl)benzene [2R-[1(2'R*,5'R*),2a,5b]]-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane] (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene, min.97% (R,R)-Me-DUPHOS Phospholane, 1,1'-(1,2-phenylene)bis[2,5-dimethyl-, (2R,2'R,5R,5'R)- an-1-yL ()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene (-)-1,2-bis-((2R,5R)-2,5-Dimethylphospholano)benzene (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene (R,R)-Me-Duphos (-) -1,2-bis ((2R, 5R) -2,5-dimethylphosphorus) benzene 147253-67-6 C18H28P2 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Privileged Ligands DuPhos/BPE organophosphine ligand