1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97
- CAS No.
- 18163-47-8
- Chemical Name:
- 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97
- Synonyms
- DK621;(iodoethynyl)triMethylsilane;2-Iodoethynyl(Trimethyl)Silane;Silane, (2-iodoethynyl)trimethyl-;1-Iodo-2-(trimethylsilyl)acetylene;1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97;1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97 ISO 9001：2015 REACH
- CBNumber:
- CB0499253
- Molecular Formula:
- C5H9ISi
- Molecular Weight:
- 224.11
- MDL Number:
- MFCD00274201
- MOL File:
- 18163-47-8.mol
- MSDS File:
- SDS
| Boiling point | 130 °C (lit.) |
|---|---|
| Density | 1.46 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 119 °F |
| storage temp. | 2-8°C |
| solubility | sol organics (THF, Et2O, pyridine, DCM, CHCl3, DMF). |
| form | clear liquid |
| color | Colorless to Red to Green |
| Specific Gravity | 1.46 |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Sensitive | Light Sensitive |
| CAS DataBase Reference | 18163-47-8 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H302+H312+H332-H317-H334-H361 | |||||||||
| Precautionary statements | P202-P210-P280-P301+P312-P303+P361+P353-P308+P313 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 10-20/21/22-42/43-63 | |||||||||
| Safety Statements | 16-23-36/37/39-45 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2931.90.9010 | |||||||||
| HazardClass | 3 | |||||||||
| NFPA 704 |
|
1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97 price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 414670 | 1-Iodo-2-(trimethylsilyl)acetylene 97% | 18163-47-8 | 1G | $48.7 | 2024-03-01 | Buy |
| TCI Chemical | I1081 | (Iodoethynyl)trimethylsilane | 18163-47-8 | 1G | $52 | 2024-03-01 | Buy |
| Alfa Aesar | H53375 | 1-Iodo-2-(trimethylsilyl)acetylene, 97% | 18163-47-8 | 1g | $32.65 | 2024-03-01 | Buy |
| Alfa Aesar | H53375 | 1-Iodo-2-(trimethylsilyl)acetylene, 97% | 18163-47-8 | 5g | $135 | 2024-03-01 | Buy |
| Alfa Aesar | H53375 | 1-Iodo-2-(trimethylsilyl)acetylene, 97% | 18163-47-8 | 25g | $424.65 | 2024-03-01 | Buy |
1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97 Chemical Properties,Uses,Production
Physical properties
bp 96 °C, 55 °C/20 mmHg; n20 D 1.5110; d 1.46 g cm?3, fp 48°C.
Uses
1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.
Uses
(Iodoethynyl)trimethylsilane is widely used as alkyne coupling reagent predominantly used in conjunction with organocopper species or palladium catalysis.(Iodoethynyl)trimethylsilane has been largely confined to aryl- and vinylcopper coupling, where it serves well since the reverse procedure, i.e. coupling with alkynylcopper reagents, is not straightforward due to the lack of reactivity of alkynyl moieties bound to copper.
Preparation
All involve iodination of trimethylsilylacetylenes. Direct iodination of metalated (lithium or magnesium) trimethylsilylacetylene has been largely supplanted due to the modest yields obtained. Utilizing trimethylsilylacetylene and bis(trimethylsilyl) peroxide in the presence of copper(I) iodide gives good yields. Substituting zinc iodide requires using the lithium acetylide. Copper(I) iodide (0.05 equiv.) in the presence of iodine, sodium carbonate, and a phase-transfer catalyst gives good yields without having to use n-butyllithium or a Grignard reagent to first deprotonate the trimethylsilylacetylene. The most popular procedure uses bis(trimethylsilyl)acetylene, treating it with iodine monochloride in dichloromethane at 25°Cto obtain excellent yields of (iodoethynyl)trimethylsilane.
1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97 Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 8174 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Win-Win Chemical CO., Limited | 0086-577-64498589 | sales@win-winchemical.com | CHINA | 998 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8823 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Hubei Co-Formula Material Tech Co., Ltd. | +86-27-84459282 | sales@cfmats.com | CHINA | 882 | 58 |
View Lastest Price from 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97 manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2023-12-29 | 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97
18163-47-8
|
US $101.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-08-14 | 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE
18163-47-8
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2022-12-13 | 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE
18163-47-8
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Guanlang Biotechnology Co., Ltd. |
-
- 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE 97
18163-47-8
- US $101.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE
18163-47-8
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- 1-IODO-2-(TRIMETHYLSILYL)ACETYLENE
18163-47-8
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.