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(1R,1'R,2S,2'S)-DUANPHOS

(1R,1'R,2S,2'S)-DUANPHOS Structure
(1R,1'R,2S,2'S)-DUANPHOS structure
CAS No.
528814-26-8
Chemical Name:
(1R,1'R,2S,2'S)-DUANPHOS
Synonyms
RcSp-DuanPhos;(1R,1'R,2S,2'S)-2,2'-di-tert-butyl-2,2',3,3'-tetrahydro-1H,1'H-1,1'-biisophosphindole;(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole;(1R,1'R,2S,2'S)- 2,2'-bis(1,1-diMethylethyl)-2,2',3,3'-tetrahydro-1,1'-Bi-1H-isophosphindole;1,1'-Bi-1H-isophosphindole, 2,2'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (1R,1'R,2S,2'S)-;(1R,1'R,2S,2'S)-2,2'-Bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-1,1'-bi-1H-isophosphindole,99%e.e.;(1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole (R,R,S,S)-DUANPHOS
CBNumber:
CB0973023
Molecular Formula:
C24H32P2
Molecular Weight:
382.46
MDL Number:
MFCD32671733
MOL File:
528814-26-8.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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(1R,1'R,2S,2'S)-DUANPHOS Properties

Melting point 214-246 °C
Boiling point 474.5±45.0 °C(Predicted)
alpha +19.5
form crystal
color white
optical activity [α]20/D +18°, c = 1 in chloroform
Sensitive air sensitive
CAS DataBase Reference 528814-26-8

SAFETY

Risk and Safety Statements

WGK Germany  3

(1R,1'R,2S,2'S)-DUANPHOS price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 657697 (1R,1′R,2S,2′S)-DuanPhos 528814-26-8 100mg $183 2024-03-01 Buy
Sigma-Aldrich 657697 (1R,1′R,2S,2′S)-DuanPhos 528814-26-8 500mg $594 2024-03-01 Buy
Strem Chemicals 15-1060 (1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole, min. 98% (R,R,S,S)-DUANPHOS 528814-26-8 100mg $149 2024-03-01 Buy
Strem Chemicals 15-1060 (1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole, min. 98% (R,R,S,S)-DUANPHOS 528814-26-8 500mg $590 2024-03-01 Buy
American Custom Chemicals Corporation CCH0004150 (1R,1'R,2S,2'S)-DUANPHOS 95.00% 528814-26-8 5MG $495.32 2021-12-16 Buy
Product number Packaging Price Buy
657697 100mg $183 Buy
657697 500mg $594 Buy
15-1060 100mg $149 Buy
15-1060 500mg $590 Buy
CCH0004150 5MG $495.32 Buy

(1R,1'R,2S,2'S)-DUANPHOS Chemical Properties,Uses,Production

Reactions

  1. As a highly electron-donating and conformationally rigid ligand, the rhodium complex of DuanPhos has exhibited remarkably high enantioselectivities and reactivities for the hydrogenation of a variety of functionalized olefins.
  2. Rhodium/DUANPHOS catalyst used in the synthesis of 2-trifluoromethyl lactic acid by asymmetric hydroformylation.
Reactions of 528814-26-8

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Catalytic ligand used for:

  • Stereoselective synthesis of cyano-substituted dihydropyrroles by annulation of cyanoallenes
  • Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
  • Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles
  • Stereoselective preparation of anti-1,3-amino alcohols via rhodium-catalyzed asymmetric hydrogenation of β-ketoenamide intermediates
  • Stereoselective preparation of acetylaminoindane via rhodium-catalyzed asymmetric hydrogenation of acetylaminoindene

General Description

(1R,1′R,2S,2′S)-DuanPhos is an electron-rich chiral phosphine ligand mainly for transition metal catalyzed asymmetric hydrogenation.

(1R,1'R,2S,2'S)-DUANPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,1'R,2S,2'S)-DUANPHOS Suppliers

Global( 22)Suppliers
Supplier Tel Email Country ProdList Advantage
Jinan Carbotang Biotech Co.,Ltd. 		+8615866703830 figo.gao@foxmail.com China 6992 58
Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2815987 13927875076 3007432263@qq.com China 10001 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 18521732826; market@aladdin-e.com China 25004 65
ChemStrong Scientific Co.,Ltd 0755-66853366 13670046396 sales@chem-strong.com China 17982 56
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 025-66113011 18112977050 cb6@aikonchem.com China 16687 50
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Jinan Shangbo Biological Co., Ltd. 0531-61320525 15866703830 495745175@qq.com China 6888 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. +86-400-002-6226 13028896684 sales@rrkchem.com China 55672 58
Supplier Advantage
Jinan Carbotang Biotech Co.,Ltd. 		58
Guangdong wengjiang Chemical Reagent Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
ChemStrong Scientific Co.,Ltd 56
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 50
Sigma-Aldrich 80
Jinan Shangbo Biological Co., Ltd. 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. 58

View Lastest Price from (1R,1'R,2S,2'S)-DUANPHOS manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1R,1 2021-07-02 (1R,1"R,2S,2"S)-DuanPhos
528814-26-8
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

528814-26-8((1R,1'R,2S,2'S)-DUANPHOS)Related Search:

(S,S)-1,2-BIS(TERT-BUTYLMETHYLPHOSPHINO)ETHANE (1R,1'R,2S,2'S)-DUANPHOS ((1R,1'R,2S,2'S)-DUANPHOS (CYCLOOCTADIENE)RHODIUM(I)) TETRAFLUOROBORATE
(1R,1'R,2S,2'S)-2,2'-Bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-1,1'-bi-1H-isophosphindole,99%e.e. (1R,1'R,2S,2'S)- 2,2'-bis(1,1-diMethylethyl)-2,2',3,3'-tetrahydro-1,1'-Bi-1H-isophosphindole (1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole (R,R,S,S)-DUANPHOS 1,1'-Bi-1H-isophosphindole, 2,2'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (1R,1'R,2S,2'S)- RcSp-DuanPhos (1R,1'R,2S,2'S)-2,2'-di-tert-butyl-2,2',3,3'-tetrahydro-1H,1'H-1,1'-biisophosphindole (1R,1'R,2S,2'S)-(+)-2,2'-Di-t-butyl-2,3,2',3'-tetrahydro-1,1'-bi-1H-isophosphindole 528814-26-8