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(R)-SpiroPAP-Me-Ir

CAS No.
1396201-63-0
Chemical Name:
(R)-SpiroPAP-Me-Ir
Synonyms
97% (>(R)-SpiroPAP-Me-Ir;Ir-(R)-DTB-SpiroPAP-3-Me;99% ee) Ir-(R)-DTB-SpiroPAP-3-Me;Chlorodihydrido{(R)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III);Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III), >[N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO-ΚP]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE-ΚN1,ΚN2]CHLORODIHYDRO-IRIDIUM;CHLORODIHYDRIDO{(R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(3-METHYLPYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE}IRIDIUM(III),>97%(>99%EE)IR-(R)-DTB-SPIROPAP-3-ME;Ir-(R)-DTB-SpiroPAP-3-Me,[N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO-ΚP]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE-ΚN1,ΚN2]CHLORODIHYDRO-IRIDIUM;Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(3-methylpyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane}iridium(III), >97% (>99% ee) Ir-(R)-DTB-SpiroPAP-3-Me
CBNumber:
CB13154488
Molecular Formula:
C52H67ClIrN2P
Molecular Weight:
978.76
MDL Number:
MOL File:
1396201-63-0.mol
Last updated:2023-04-23 13:52:06

(R)-SpiroPAP-Me-Ir Properties

form solid
color yellow-green
CAS DataBase Reference 1396201-63-0

(R)-SpiroPAP-Me-Ir price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 77-4035 Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III), >97% (>99% ee) Ir-(R)-DTB-SpiroPAP-3-Me 1396201-63-0 25mg $85 2024-03-01 Buy
Strem Chemicals 77-4035 Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III), >97% (>99% ee) Ir-(R)-DTB-SpiroPAP-3-Me 1396201-63-0 100mg $250 2024-03-01 Buy
Chemenu CM103008 Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(3-methylpyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane}iridium(III) 97% 1396201-63-0 100mg $408 2021-12-16 Buy
Chemenu CM103008 Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(3-methylpyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane}iridium(III) 97% 1396201-63-0 250mg $816 2021-12-16 Buy
Product number Packaging Price Buy
77-4035 25mg $85 Buy
77-4035 100mg $250 Buy
CM103008 100mg $408 Buy
CM103008 250mg $816 Buy

(R)-SpiroPAP-Me-Ir Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the enantioselective synthesis of chiral disubstituted oxa-cyclic ethers
  2. Catalyst for the enantioselective hydrogenation for the asymmetric synthesis of Rivastigmine
  3. Catalyst for the asymmetric hydrogenation for the synthesis of Crizotinib
  4. Catalyst for the asymmetric hydrogenation of α-keto acids
  5. Catalyst for the kinetic resolution of racemic aliphatic alcohols via selective asymmetric hydrogenation
Reactions of 1396201-63-0_1
Reactions of 1396201-63-0_2

(R)-SpiroPAP-Me-Ir Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 20)Suppliers
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Shanghai Arbor Chemical Co., Ltd.
021-60451682 act@arborchemical.com CHINA 906 58
Zhuoer Chemical Co., Ltd
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Aladdin Scientific
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Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6854 65
Shanghai Topbiochem Technology Co., Ltd 021-58170097 info@topbiochem.com China 9449 58
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4049 58
Jiangsu aikang biomedical research and development co., LTD 025-66110311 13155353615 qzhang@aikonchem.com China 15527 58
Shanghai Kaiwei Chemical Technology Co., Ltd. 021-58461859 15821823057 service@aiviche.com China 49323 58
(R)-SpiroPAP-Me-Ir [N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO-ΚP]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE-ΚN1,ΚN2]CHLORODIHYDRO-IRIDIUM Ir-(R)-DTB-SpiroPAP-3-Me CHLORODIHYDRIDO{(R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(3-METHYLPYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE}IRIDIUM(III),>97%(>99%EE)IR-(R)-DTB-SPIROPAP-3-ME 99% ee) Ir-(R)-DTB-SpiroPAP-3-Me Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III), > 97% (> Ir-(R)-DTB-SpiroPAP-3-Me,[N-[(1R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO-ΚP]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-3-METHYL-2-PYRIDINEMETHANAMINE-ΚN1,ΚN2]CHLORODIHYDRO-IRIDIUM Chlorodihydrido{(R)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane}iridium(III) Chlorodihydrido{(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(3-methylpyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane}iridium(III), >97% (>99% ee) Ir-(R)-DTB-SpiroPAP-3-Me 1396201-63-0 C52H67ClIrN2P Chiral Phosphine Chiral Spiro Ligand Ir