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FEMA 3377

CAS No.
557-48-2
Chemical Name:
FEMA 3377
Synonyms
FEMA 3377;NONADIENAL-2,6;T2 C6 NONADIENAL;CUCUMBER ALDEHYDE;(e,z)-6-nonadienal;(2E,6Z)-Nonadienal;violetleafaldehyde;TIMTEC-BB SBB006611;FEMA 3377 USP/EP/BP;(E,Z)-2,6-nonadienal
CBNumber:
CB1388620
Molecular Formula:
C9H14O
Molecular Weight:
138.21
MDL Number:
MFCD00007009
MOL File:
557-48-2.mol
MSDS File:
SDS
Last updated:2024-04-19 15:36:20

FEMA 3377 Properties

Boiling point 94-95 °C18 mm Hg(lit.)
Density 0.86 g/mL at 25 °C(lit.)
refractive index n20/D 1.474(lit.)
FEMA 3377 | NONA-2-TRANS-6-CIS-DIENAL
Flash point 181 °F
storage temp. Refrigerator
solubility Soluble in ethanol and most non volatile oils, insoluble in water.
form Oil
color Sltly yellow liquid
Odor powerful, violet-cucumber odor
Odor Type green
Sensitive Air Sensitive
JECFA Number 1186
InChIKey HZYHMHHBBBSGHB-ODYTWBPASA-N
LogP 2.60
CAS DataBase Reference 557-48-2(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) 2-TRANS-6-CIS-NONADIENAL
FDA UNII 93E895X03C
EPA Substance Registry System 2,6-Nonadienal, (2E,6Z)- (557-48-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H227-H315-H319-H335
Precautionary statements  P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a
Risk Statements  36/37/38
Safety Statements  24/25
RIDADR  NA 1993 / PGIII
WGK Germany  2
RTECS  RA5391800
TSCA  Yes
HS Code  2912.19.5000
Toxicity LD50 orl-rat: >5 g/kg FCTOD7 20,769,82
NFPA 704
1
0 0

FEMA 3377 price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W337706 trans-2,cis-6-Nonadienal mixture of isomers, ≥96%, stabilized, FCC, FG 557-48-2 25g $257 2024-03-01 Buy
Sigma-Aldrich W337706 trans-2,cis-6-Nonadienal mixture of isomers, ≥96%, stabilized, FCC, FG 557-48-2 100g $610 2024-03-01 Buy
Sigma-Aldrich W337706 trans-2,cis-6-Nonadienal mixture of isomers, ≥96%, stabilized, FCC, FG 557-48-2 1kg $4030 2024-03-01 Buy
Sigma-Aldrich 294675 trans-2,cis-6-Nonadienal 95% 557-48-2 1g $19.38 2024-03-01 Buy
Sigma-Aldrich 05549 trans-2,cis-6-Nonadienal analytical standard 557-48-2 100mg $90.8 2024-03-01 Buy
Product number Packaging Price Buy
W337706 25g $257 Buy
W337706 100g $610 Buy
W337706 1kg $4030 Buy
294675 1g $19.38 Buy
05549 100mg $90.8 Buy

FEMA 3377 Chemical Properties,Uses,Production

Chemical Properties

Nona-2-trans-6-cis-dienal is a clear colorless to pale yellow liquid that has an odor reminiscent of green cucumber. The organoleptic character of this compound is attributed almost entirely to olfactory sensations. May be obtained from the steam distillation of fresh cucumber.

Occurrence

Reported as naturally occurring in violet leaves and flowers, in cucumber, sweet and sour cherry, guava, peas, tomato, potato, bell pepper, wheat bread, rye bread, milk, milk powder, fish and fish oil, roast chicken, guinea hen, beef, beer, coffee, tea, oats, mango, kelp, prickly pear, malt, dried bonito, endive, oysters, clam and mate.

Uses

trans-2,cis-6-Nonadienal is an unsaturated aldehyde that is responsible for the cucumber smell of Synura petersenii, a freshwater colonial flagellate. trans-2,cis-6-Nonadienal is also a common natural and drinking water contaminant.

Preparation

From natural hexenol

Definition

ChEBI: (2E,6Z)-nona-2,6-dienal is an enal that is (2E,6Z)-nona-2,6-diene substituted by an oxo group at position 1. It has a role as a plant metabolite. It is an enal and a trans-2,3-unsaturated fatty aldehyde.

Aroma threshold values

Detection: 0.01 ppb

Taste threshold values

Taste characteristics at 10 ppm: green, melon, cucumber-like with an aldehydic nuance

Synthesis Reference(s)

The Journal of Organic Chemistry, 38, p. 36, 1973 DOI: 10.1021/jo00941a008

General Description

trans-2,cis-6-Nonadienal is the key contributor to the cucumber flavor. It is also found in mango ripened anchovy and kelp. Unialgal cultures of various Synurophycean species for the occurrence of trans-2,cis-6-nonadienal have been investigated.

Safety Profile

Low toxicity by ingestion and skin contact. A moderate skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

67674-37-7
557-48-2
Synthesis of FEMA 3377 from (2Z,6Z)-1,1-diethoxynona-2,6-diene

FEMA 3377 Preparation Products And Raw materials

Raw materials

Preparation Products

FEMA 3377 Suppliers

Global( 162)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Neostar United (Changzhou) Industrial Co., Ltd.
+86-519-519-85557386 marketing1@neostarunited.com China 8349 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12431 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9553 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 29474 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58
LEAP CHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 24738 58

View Lastest Price from FEMA 3377 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
FEMA 3377 pictures 2024-04-19 FEMA 3377
557-48-2
US $35.00-1.10 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Trans,Cis-2,6-Nonadienal pictures 2022-09-15 Trans,Cis-2,6-Nonadienal
557-48-2
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
Trans, cis-2, 6-nonadienal aldehyde  pictures 2020-02-26 Trans, cis-2, 6-nonadienal aldehyde
557-48-2
US $0.00-0.00 / Kg 100G 99.0%+ 100 tons Shaanxi Dideu Medichem Co. Ltd
  • FEMA 3377 pictures
  • FEMA 3377
    557-48-2
  • US $35.00-1.10 / kg
  • 99%
  • Henan Fengda Chemical Co., Ltd
TIMTEC-BB SBB006611 T2 C6 NONADIENAL TRANS-2,CIS-6-NONADIENAL TRANS-2,CIS-6-NONADIEN-1-AL (2E,6Z)-2,6-Nonadienal (2E,6Z)-Nonadienal (E)-2,(Z)-6-nonadienal (E,Z)-2,6-nonadienal (e,z)-6-nonadienal (E,Z)-nona-2,6-dienal 2-(trans)-6-(cis)-Nonadienal 2,6-(E,Z)-Nonadienal 2-trans-6-cis-Nonadien-1-al 2-trans-6-cis-Nonadienal 6-Nonadienal,(E,Z)-2 Nona-2(E),6(Z)-dienal Nona-2,6(E,Z)-dienal Nonadien-2(trans)-6-(cis)-al nona-trans-2,cis-6-dienal trans,cis-2,6-Nonadien-1-al trans,cis-2,6-Nonadienal Violet leaf aldehyde violetleafaldehyde FEMA 3377 (E,Z)-2,6-NONADIEN-1-AL CUCUMBER ALDEHYDE (2E,6Z)-nona-2,6-dien-1-al TRANS-2 CIS-6-NONADIENAL 96+% MIXTURE& 2,6-nonadienal,(E,Z)-2,6-nonadienal 2,6-Nonadienal, (2E,6Z)- trans-2, cis-6-Nonadienal Odor Standard NONA-2-TRANS,6-CIS-DIENAL NONADIENAL-2,6 trans-2,cis-6-Nonadienal, 90+%(major isomer), remainder mainly trans,trans-isomer TRANS-2, CIS-6-NONADIENAL, NATURAL 1% SOL. IN CAPROIC ACID TRANS-2, CIS-6-NONADIENAL, NATURAL 1% SOL. IN ETHYL ACETATE trans-2,cis-6-Nonadienal,95% Trans-2,Cis-6-Nonadienal (Major Isomer), Remainder Mainly Trans,Trans-Isomer trans-2,cis-6-Nonadienal,Violet leaf aldehyde (2E,6Z)-nona-2,6-dienal trans-2,cis-6-Nonadienal 95% trans,cis-2,6-Nonadienal Trans, cis-2, 6-nonadienal aldehyde trans,cis-2,6-Nonadienal> FEMA 3377 USP/EP/BP trans-2,cis-6-Nonadienal, 90+% (major isomer), remainder mai Farnesane Impurity 48 e,z-2,6-Nonadien-1-al FCC rans-2,cis-6-nonadienal 557-48-2 Organic Building Blocks ALDEHYDE Aldehydes Building Blocks C9 Carbonyl Compounds