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Carminic Acid

CAS No.
1260-17-9
Chemical Name:
Carminic Acid
Synonyms
CI 75470;coccinic acid;E120;CARMINE RED;CARMINE ALUMINUM LAKE;Carminic;NSC 326224;CARMINE 2G;CARMINE 40;Karminsure
CBNumber:
CB1428489
Molecular Formula:
C22H20O13
Molecular Weight:
492.39
MDL Number:
MFCD00167028
MOL File:
1260-17-9.mol
Last updated:2023-08-10 17:57:44

Carminic Acid Properties

Melting point 136 °C
Boiling point 506.2°C (rough estimate)
alpha 15654 +51.6° (water)
Density 1.4504 (rough estimate)
refractive index 1.6000 (estimate)
Flash point 12℃
storage temp. room temp
solubility 30g/l
Colour Index 75470
pka 1.62±0.20(Predicted)
form Crystalline Powder
color Red to dark red
PH 1.6 (10g/l, H2O, 20℃)
Odor Odorless
PH Range 4.8 - 6.2
optical activity [α]20/D +3.1°, c = 1 in H2O
Water Solubility 1.298g/L(room temperature)
Merck 14,1843
BRN 71651
LogP 1.532 (est)
Substances Added to Food (formerly EAFUS) COCHINEAL EXTRACT (COCCUS CACTI L.)
CAS DataBase Reference 1260-17-9
FDA UNII CID8Z8N95N
EPA Substance Registry System C.I. Natural Red 4 (1260-17-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
Safety Statements  22-24/25
WGK Germany  2
HS Code  32129000
NFPA 704
0
3 0

Carminic Acid price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 229253 Carminic acid 1260-17-9 1g $306 2024-03-01 Buy
Sigma-Aldrich PHL82865 Carminic acid phyproof? Reference Substance 1260-17-9 10MG $485 2024-03-01 Buy
Sigma-Aldrich 11298 Carminic acid analytical standard 1260-17-9 25mg $243 2024-03-01 Buy
Sigma-Aldrich 03320585 Carminic acid primary reference standard 1260-17-9 25MG $304 2024-03-01 Buy
TCI Chemical C0782 Carminic Acid (Natural dye) 1260-17-9 5g $168 2024-03-01 Buy
Product number Packaging Price Buy
229253 1g $306 Buy
PHL82865 10MG $485 Buy
11298 25mg $243 Buy
03320585 25MG $304 Buy
C0782 5g $168 Buy

Carminic Acid Chemical Properties,Uses,Production

Chemical Properties

red to dark red crystalline powder

Chemical Properties

Cochineal extract is a concentrated solution obtained after removing alcohol from an aqueous–alcoholic extract of cochineal (Dactylopius coccus Costa, also called Coccus cati L.). This extract is used as a color additive, the primary colorant being carminic acid.

History

CI Natural Red 4(CI 75470), is a red dye occurring as a glycoside in the body of the cochineal insect Dactylopius coccus of the order Homoptera, family Coccidae. This insect is native to Central and South America. The Aztecs had extracted the dye from the insect centuries before the coming of the Spaniards. For breeding purposes, the insects were collected in the autumn and carefully protected during the winter months. Cochineal was harvested after three months, and then the bugs were killed by immersion in hot water, by placing in hot ovens, or by exposure to the hot sun. The latter method produced the highest quality dye. At present, Peru and the Canary Islands are the main source of the dye. Until the advent of synthetic dyes, the principal use for carminic acid was for dyeing tin-mordanted wool or silk. Its aluminum lake, carmine, finds use in the coloring of foods.

Uses

Carminic acid (C.I. 75470) For staining nuclei in histological sections. Used to prepare staining solutions.
CAS 1260-17-9, pH 1.6 (10?g/l, H?O, 20?°C).

Uses

antineoplastic, glucosyltransferase inhibitor

Uses

A red glucosidal hydroxyanthrapurin, it is produced naturally within some insects as a defense mechanism.

Definition

ChEBI: A tetrahydroxyanthraquinone that is that is 1,3,4,6-tetrahydroxy-9,10-anthraquinone substituted by a methyl group at position 8, a carboxy group at position 7 and a 1,5-anhydro-D-glucitol moiety at position 2 via a C-gly osidic linkage. It is a natural dye isolated from several insects such as Dactylopius coccus.

General Description

Dark purplish-brown mass or bright red or dark red powder. Darkens at 248°F. Deep red color in water. Yellow to violet in acidic aqueous solutions.

Air & Water Reactions

Soluble in water [Hawley].

Reactivity Profile

CARMINE neutralizes bases in exothermic reactions. Incompatible with strong oxidizing agents.

Fire Hazard

Flash point data for CARMINE are not available. CARMINE is probably combustible.

Purification Methods

Carminic acid forms red prisms from EtOH. It gives a red colour in Ac2O and yellow to violet in acidic solution. UV: max (H2O) 500nm ( 6,800); (0.02N HCl) 490-500nm ( 5,800) and (0.0001N NaOH) 540nm ( 3,450). IR: max (Nujol) 1708s, 1693s, 1677m, 1648m, 1632m, 1606s, 1566s, 1509 cm-1. Periodate oxidation is complete after 4hours at 0o with the consumption of 6.2 mols. The tetra-O-methyl carminate has m 186-188o (yellow needles from *C6H6/pet ether). [IR: Ali & Haynes J Chem Soc 1033 1959, Bhatia & Venkataraman Indian J Chem 3 (2) 92 1965, Synthesis: Davis & Smith Biochemical Preparations 4 38 1955, Beilstein 18 III/1V 6697.]

Carminic Acid Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 199)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
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0551-65418671 sales@tnjchem.com China 34572 58
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View Lastest Price from Carminic Acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Carminic Acid pictures 2023-08-11 Carminic Acid
1260-17-9
US $50.00 / KG 25KG 98 200ton Hebei Mojin Biotechnology Co., Ltd
Carminic Acid pictures 2023-04-01 Carminic Acid
1260-17-9
US $10.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
Carminic Acid pictures 2019-07-06 Carminic Acid
1260-17-9
US $1.00 / kg 1g 99% 100KG Career Henan Chemical Co
  • Carminic Acid pictures
  • Carminic Acid
    1260-17-9
  • US $50.00 / KG
  • 98
  • Hebei Mojin Biotechnology Co., Ltd
  • Carminic Acid pictures
  • Carminic Acid
    1260-17-9
  • US $10.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
Carminic Acid  3,5,6,8-Tetrahydroxy-1-methyl-9,10-dioxo-7-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)-9,10-dihydroanthracene-2-carboxylic acid Carminic acid (C.I. 75470) GR for analysis and for microscopy ALUMINUM LAKE OF CARMINIC ACID 2-anthracenecarboxylicacid,7-beta-d-glucopyranosyl-9,10-dihydro-3,5,6,8-tetra 7-.beta.-D-glucopyranosyl-9,10-dihydro-3,5,6,8-tetrahydroxy-1-methyl-9,10-dioxo-2-Anthracenecarboxylicacid 7-alpha-d-glucopyranosyl-9,10-dihydro-3,5,6,8-tetrahydroxy-1-methyl-9,10-dioxo C.I.Naturalred4 carminicacid50% carminicacid95% cinaturalred4 cochinealtincture CarMinic acid, 70-90% 1GR NSC 326224 CARMINIC ACID (C.I. 75470) GR FOR ANALYS 2-Anthracenecarboxylicacid, 7-b-D-glucopyranosyl-9,10-dihydro-3,5,6,8-tetrahydroxy-1-Methyl-9,10-dioxo- CARMINIC ACID, FOR MICROSCOPY CarminicAcidGrForMicroscopy CarmineCochineal CARMINIC ACID (NATURAL DYE) Carminic acid (C.I. 75470) Carminic Acid 50% 10-dioxo-ahydroxy-1-methyl- 10-dioxo-hydroxy-1-methyl- 2-anthracenecarboxylicacid,7-beta-d-glucopyranosyl-9,10-dihydro-3,5,6,8-tetr CALCIUM ALUMINIUM LACQUER WITH CARMINIC ACID CARMINATE BORAX CARMINE 2G CARMINE 40 CARMINE BEST'S CARMINE NACARAT CARMINE PICRO CARMINE REAGENT CARMINE, WATER SOLUBLE CARMINIC ACID CI NO 75470 FD AND C CARMINE Karminsure Carminic 2-Anthracenecarboxylic acid, 7-.beta.-D-glucopyranosyl-9,10-dihydro-3,5,6,8-tetrahydroxy-1-methyl-9,10-dioxo- CARMINIC ACID(RG) Carminic acid, 70-90% 7-β-D-Glucopyranosyl-9,10-dihydro-3,5,6,8-tetrahydroxy-1-methyl-9,10-dioxo-2-anthracenecarboxylic acid Carminic acid,96% Carminic acid (E120) CarMinic Acid, >70% Cochineal Carmine Powder 2-Anthracenecarboxylic acid, 7-β-D-glucopyranosyl-9,10-dihydro-3,5,6,8-tetrahydroxy-1-methyl-9,10-dioxo- Carminic acid, Natural Red 4 Carminic Acid, > Carminic Acid USP/EP/BP Carminic acid, GR CARMINE ALUMINUM LAKE CARMINE RED CI 75470 E120 coccinic acid 1260-17-9