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(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE

CAS No.
132873-57-5
Chemical Name:
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
Synonyms
(S)-NITRESOLVE;(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL;(S)-alpha-methyl-4-nitrobenzenemethanamine;(S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL;(S)-α-Methyl-4-nitrobenzylamineHydrochloride;(S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE;1-(S)-4-Nitrophenyl ethylamine hydrochloride;(S)-4-Nitro-α-methylbenzylamine hydrochloride;(S)-1-(4-Nitrophenyl)ethanaMine hydrochloride;(S)-α-Methyl-4-nitrobenzylamine Hydrochloride
CBNumber:
CB1467176
Molecular Formula:
C8H11ClN2O2
Molecular Weight:
202.64
MDL Number:
MFCD00066312
MOL File:
132873-57-5.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:36

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Properties

Melting point 248-250 °C(lit.)
refractive index -7.2 ° (C=1, 0.05mol/L NaOH)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
color White to Light yellow
optical activity [α]25/D 6.5°, c = 1 in 0.05 M NaOH
Water Solubility faint turbidity
CAS DataBase Reference 132873-57-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
3-10
HS Code  29214990
NFPA 704
0
2 0

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 339822 (S)-α-Methyl-4-nitrobenzylamine hydrochloride 97% 132873-57-5 1g $49.6 2024-03-01 Buy
TCI Chemical N0543 (S)-alpha-Methyl-4-nitrobenzylamine Hydrochloride >99.0%(T) 132873-57-5 1g $57 2024-03-01 Buy
TRC N545280 (S)-1-(4-Nitrophenyl)ethanamineHydrochloride 132873-57-5 50mg $60 2021-12-16 Buy
Chem-Impex 37513 (S)-α-Methyl-4-nitrobenzylaminehydrochloride,99%(T) 99%(T) 132873-57-5 1G $60.48 2021-12-16 Buy
ChemScene CS-M0682 (S)-1-(4-nitrophenyl)ethanamineHydrochloride >99.0% 132873-57-5 25g $110 2021-12-16 Buy
Product number Packaging Price Buy
339822 1g $49.6 Buy
N0543 1g $57 Buy
N545280 50mg $60 Buy
37513 1G $60.48 Buy
CS-M0682 25g $110 Buy

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Chemical Properties,Uses,Production

Uses

(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:

  • A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.
  • A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.

Purification Methods

To ensure dryness, the hydrochloride (ca 175 g) is extracted with EtOH (3x100mL) and evaporated to dryness (any residual H2O increases the solubility in EtOH and lowers the yield). The hydrochloride residue is triturated with absolute EtOH and dried in vacuo. The product is further purified by refluxing with absolute EtOH (200 mL for 83g) for 1hour, and cool to 10o to give 76.6g of hydrochloride m 243-245o(dec). The free base is prepared by dissolving in N NaOH, extracting with CH2Cl2 (3 x 500mL), drying (Na2CO3), filtering, evaporating and distilling it. It has m 27o, b 119-120o/0.5mm (105-107o/0.5mm, 157-159o/9mm, d 1.1764, n 1.5688, [] ±17.7o (neat) [Perry et al. Synthesis 492 1977,ORD: Nerdel & Liebig Justus Liebigs Ann Chem 621 142 1959]. [Beilstein 12 IV 2451.]

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE Suppliers

Global( 122)Suppliers
Supplier Tel Email Country ProdList Advantage
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 7836 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
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Aladdin Scientific
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Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32360 55

View Lastest Price from (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE pictures 2020-01-15 (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
132873-57-5
US $1.00 / g 1g 99% 200kg Career Henan Chemical Co
(S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE pictures 2020-01-15 (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE
132873-57-5
US $1.00 / g 1g 99% 200kg Career Henan Chemical Co
(S)-(+)-1-(4-NITROPHENYL)-ETHYLAMINE HCL (S)-1-(4-NITROPHENYL)-METHYLAMIN HYDROCHLORIDE (S)-4-NITROPHENYL-1-ETHYLAMINE HYDROCHLORIDE (S)-NITRESOLVE (S)-(+)-ALPHA-METHYL-4-NITROBENZYLAMINE HCL (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE (S)-ALPHA-METHYL-4-NITROBENZYLAMMONIUM CHLORIDE (S)-(+)-ALPHA-METHYL-P-NITROBENZYLAMINE HYDROCHLORIDE (S)-(-)-A-METHYL 4-NITROBENZYLAMINE HYDROCHLORIDE (S)-α-Methyl-4-nitrobenzylamineHydrochloride (S)-4-Nitro-α-methylbenzylamine hydrochloride (S)-(+)-α-Methyl-p-nitrobenzylamine Hydrochloride (S)-alpha-methyl-4-nitrobenzenemethanamine (s)-alpha-Methyl-4-nitroitrobenzylaMine Hydrochloride (S)-1-(4-Nitrophenyl)ethanaMine hydrochloride (S)-Nitresolve (S)-1-(4-Nitrophenyl)ethylamine Hydrochloride (S)-alpha-Methyl-4-nitrobenzeneMethanaMine HCL (S)-alpha-Methyl-4-nitrobenzylamine hydrochloride 97% (S)-ALPHA-METHYL-4-NITROBENZYLAMINE HYDROCHLORIDE 99+% 1-(S)-4-Nitrophenyl ethylamine hydrochloride (S)-α-Methyl-4-nitrobenzylamineHydrochloride> Benzenemethanamine, α-methyl-4-nitro-, hydrochloride (1:1), (αS)- (S)-α-Methyl-4-nitrobenzylamine Hydrochloride 132873-57-5 O2NC6H4CHCH3NH2HCl Asymmetric Synthesis Chiral Resolution Reagents Optical Resolution for Resolution of Acids Chiral Resolving Reagents chiral for Resolution of Acids Optical Resolution Synthetic Organic Chemistry 1