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4-Formylphenylboronic acid

4-Formylphenylboronic acid Structure
4-Formylphenylboronic acid structure
CAS No.
87199-17-5
Chemical Name:
4-Formylphenylboronic acid
Synonyms
FPBA;4-FORMYLBENZENEBORONIC ACID;AKOS BRN-0111;TIMTEC-BB SBB004077;RARECHEM AH PB 0193;4-Formylphenylboroni;4-Formylboronic acid;4-BORONOBENZALDEHYDE;Metoprolol Impurity 34;4-Formylpenylboronic Acid
CBNumber:
CB1491072
Molecular Formula:
C7H7BO3
Molecular Weight:
149.94
MDL Number:
MFCD00151823
MOL File:
87199-17-5.mol
MSDS File:
SDS
Last updated:2024-04-16 14:59:45
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4-Formylphenylboronic acid Properties

Melting point 237-242 °C (lit.)
Boiling point 347.6±44.0 °C(Predicted)
Density 1.24±0.1 g/cm3(Predicted)
vapor pressure 0Pa at 25℃
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility <10g/l
form Liquid
pka 7.34±0.10(Predicted)
color Clear colorless to yellow-orange
PH 5.5 (1g/l, H2O, 20℃)
Water Solubility Slightly Soluble in water.
Sensitive Air Sensitive
BRN 3030770
InChIKey VXWBQOJISHAKKM-UHFFFAOYSA-N
LogP 1.36 at 20℃
CAS DataBase Reference 87199-17-5(CAS DataBase Reference)
FDA UNII Z4V1TO2DWR
EPA Substance Registry System Boronic acid, (4-formylphenyl)- (87199-17-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317
Precautionary statements  P261-P272-P280-P302+P352-P333+P313-P362+P364
Hazard Codes  C,Xi
Risk Statements  34-36/37/38
Safety Statements  22-26-36/37/39-45-37/39-36
RIDADR  UN 1759 8/PG 3
WGK Germany  3
F  10
Hazard Note  Irritant
TSCA  T
HazardClass  IRRITANT, AIR SENSITIVE
HS Code  29163990
NFPA 704
0
2 0

4-Formylphenylboronic acid price More Price(55)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 431966 4-Formylphenylboronic acid ≥95.0% 87199-17-5 1g $35.4 2024-03-01 Buy
Sigma-Aldrich 431966 4-Formylphenylboronic acid ≥95.0% 87199-17-5 5g $117 2024-03-01 Buy
TCI Chemical F0446 4-Formylphenylboronic Acid (contains varying amounts of Anhydride) 87199-17-5 1g $28 2024-03-01 Buy
TCI Chemical F0446 4-Formylphenylboronic Acid (contains varying amounts of Anhydride) 87199-17-5 5g $77 2024-03-01 Buy
Alfa Aesar B25199 4-Formylbenzeneboronic acid, 97% 87199-17-5 1g $33.65 2024-03-01 Buy
Product number Packaging Price Buy
431966 1g $35.4 Buy
431966 5g $117 Buy
F0446 1g $28 Buy
F0446 5g $77 Buy
B25199 1g $33.65 Buy

4-Formylphenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powder

Uses

4-Formylphenylboronic acid is a substrate for Suzuki cross-coupling reactions and it can be used as a reagent for:

  • Palladium-catalyzed Suzuki-Miyaura cross-coupling in water.
  • Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides.
  • Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.
  • Triethylamine-catalyzed three-component Hantzsch condensations.
  • Copper-catalyzed nitrations.
  • Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.
  • Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides.
  • Palladium-catalyzed aerobic oxidative cross-coupling reactions.
  • The synthesis of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells.
  • The synthesis of a novel protein synthesis inhibitor active against Gram-positive bacteria.
  • The Suzuki aryl-aryl coupling of the upper rim of hexahomotrioxacalix[3]arene.
  • A rhodium-catalyzed cyclization, converting 1,5-enynes to cyclopentenes and spiro-cyclopentenes.

Uses

4-Formylbenzeneboronic acid acts as a reagent used for Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids, triethylamine-catalyzed three-component Hantzsch condensations, copper-catalyzed nitrations, oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta, palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides, palladium-catalyzed aerobic oxidative cross-coupling reactions. It acts as a reagent used in preparation of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells, a novel protein synthesis inhibitor active against Gram-positive bacteria.

Uses

suzuki reaction

Flammability and Explosibility

Not classified

Synthesis

Potassium phenyltrifluoroborate (184 mg, 1.00 mmol) was added to a solution of iron trichloride (185 mg, 1.10 mmol) in 3 mL of 1:1 THF/water. The mixture was stirred at room temperature for 30 min. The reaction mixture was then passed through a short column containing neutral absorption alumina. The alumina was then washed with a mixture of ethyl acetate/hexanes (2:1) to obtain 4-Formylphenylboronic acid (105 mg, 86%). [The boronic acid products can also be isolated by simple extraction techniques.]

4-Formylphenylboronic acid synthesis

186497-79-0
87199-17-5
Synthesis of 4-Formylphenylboronic acid from Boronic acid, [4-(2-propenyl)phenyl]-

4-Formylphenylboronic acid Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid Toluene Tetrahydrofuran Ethylene glycol 4-Bromobenzaldehyde
n-Butyllithium

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Preparation Products

3-THIOPHEN-2-YL-BENZALDEHYDE 1,3,5-Tris(p-formylphenyl)benzene (2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene 3,4'-DIHYDROXYFLAVONE 4-(2-Cyanophenyl)benzaldehyde
4-AMINOMETHYLPHENYLBORONIC ACID, PINACOL ESTER, HCL 4-((N-BOC-AMINO)METHYL)PHENYLBORONIC ACID 4-(2-PHENYLETH-1-YNYL)BENZALDEHYDE Des-N-(methoxycarbonyl)-L-tert-leucine Bis-Boc Atazanavir URMC-099
(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

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4-Formylphenylboronic acid Suppliers

Global( 525)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Maison Chemical Co.,Ltd.
+8615511852758 sales@maisonchem.com.cn China 484 58
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12456 58
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 6710 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Hebei Saisier Technology Co., LTD 		+86-18400010335 +86-13102810335 admin@hbsaisier.cn China 747 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Beijing Cooperate Pharmaceutical Co.,Ltd 		010-60279497 sales01@cooperate-pharm.com CHINA 1811 55
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
China Synchem Technology Co.,Ltd. 		+86-0552-4929304 +86-18055277008 wangxuhui1985@126.com China 55 55
Supplier Advantage
Hebei Maison Chemical Co.,Ltd.
58
Hebei Mojin Biotechnology Co., Ltd 		58
Shanghai UCHEM Inc. 		58
Henan Fengda Chemical Co., Ltd 		58
Hebei Saisier Technology Co., LTD 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Beijing Cooperate Pharmaceutical Co.,Ltd 		55
Henan Tianfu Chemical Co.,Ltd. 		55
China Synchem Technology Co.,Ltd. 		55

View Lastest Price from 4-Formylphenylboronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Formylphenylboronic acid pictures 2024-04-16 4-Formylphenylboronic acid
87199-17-5
 US $6.00 / KG 1KG 99% 2000KG/MONTH Hebei Saisier Technology Co., LTD
4-Formylphenylboronic acid pictures 2024-04-08 4-Formylphenylboronic acid
87199-17-5
 US $34.00-1.20 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-BORONOBENZALDEHYDE pictures 2024-02-23 4-BORONOBENZALDEHYDE
87199-17-5
 US $61.00-516.00 / g 100g 0.98 25kg Shanghai UCHEM Inc.

4-Formylphenylboronic acid Spectrum

4-Formylphenylboronic acid(87199-17-5)1HNMR4-Formylphenylboronic acid(87199-17-5)IR

87199-17-5(4-Formylphenylboronic acid)Related Search:

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Benzaldehyde 4-(Methylthio)phenylboronic acid 2-CHLORO-5-FORMYLPHENYLBORONIC ACID 2-Boronobenzaldehyde~2-Formylphenylboronic acid,2-FORMYLPHENYLBORONIC ACID 5-CHLORO-2-FORMYLPHENYLBORONIC ACID
4-ETHOXY-3-FORMYLPHENYLBORONIC ACID 4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID 4-FORMYLPHENYLBORONIC ACID, NEOPENTYL GLYCOL CYCLIC ESTER 4-(N,N-DIMETHYLAMINOCARBONYL)PHENYLBORONIC ACID 4-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID
4-FORMYLPHENYLBORONIC ACID PROPANEDIOL-1,3 CYCLIC ESTER 4-(N,O-DIMETHYLHYDROXYLAMINOCARBONYL)PHENYLBORONIC ACID 4-Carbamoylphenylboronic acid

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RARECHEM AH PB 0193 TIMTEC-BB SBB004077 P-FORMYLPHENYLBORONIC ACID AKOS BRN-0111 4-FORMYLPHENYLBORONIC ACID 4-BORONOBENZALDEHYDE 4-(Dihydroxyboryl)benzaldehyde, 4-Boronobenzaldehyde 4-Formylboronic acid 4-Formylphenylboronic acid ,97% 4-Formylphenylboronic acid,4-(Dihydroxyboryl)benzaldehyde, 4-Boronobenzaldehyde 4-Formylphenylboroni 4-ForMylphenylboronic acid, 97% 1GR Benzeneboronic acid, p-forMyl- (6CI,7CI) 4-ForMylphenylboronic acid >=95.0% 4-Formylphenylboronic acid 4-(Dihydroxyboryl)benzaldehyde p-Formylbenzeneboronic acid (4-methanoylphenyl)boronic acid Boronic acid, (4-formylphenyl)- 4-(dihydroxyboryl)benzaldehyde BENZALDEHYDE-4-BORONIC ACID 4-Boronobenzaldehyde~4-Formylphenylboronic acid 4-Formylpenylboronic Acid Boronic acid, (4-formylphenyl)- (9CI) 4-Formylbenzeneboronicacid,97% 4-Formylphenylboronic acid(FPBA) 2,4-DINITROTOLUENE,1X1ML, ACN 1000UG/ML PARAFORMYLPHENYLBORONIC ACID 4-FORMYLPHENYLBORONIC ACID, 98+% 4-Formylphenlboronic acid 4-Formylphenylboronic Acid (contains varying amounts of Anhydride) Boronic acid, B-(4-formylphenyl)- 4-Formylphenylboronic Acid extrapure, 95% 4-FORMYLBENZENEBORONIC ACID FPBA 4-Formylphenylboronic acid (4-FPBA) Metoprolol Impurity 34 87199-17-5 87199-17-2 Boronic Acids B (Classes of Boron Compounds) BORONIC ACID Boronic Acids and Derivatives Aryl Organometallic Reagents Substituted Boronic Acids Boron, Nitrile, Thio,& TM-Cpds Carbonyl Compounds ALDEHYDE Aldehydes blocks BoronicAcids Boronic Acid series Aryl Organoborons B (Classes of Boron Compounds) CHIRAL CHEMICALS Boronic Acids & Esters Boronic Acid