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Tetrahydropyran

CAS No.
142-68-7
Chemical Name:
Tetrahydropyran
Synonyms
THP;Tetrahydro-2H-pyran;OXACYCLOHEXANE;tetrahydropyrane;UMOD;THGP;MKCD2;Tamm-Horsfall;Etrahydropyran;TETRAHYDROPYRAN
CBNumber:
CB1709492
Molecular Formula:
C5H10O
Molecular Weight:
86.13
MDL Number:
MFCD00006585
MOL File:
142-68-7.mol
MSDS File:
SDS
Last updated:2023-12-19 09:14:59

Tetrahydropyran Properties

Melting point -45 °C (lit.)
Boiling point 88 °C (lit.)
Density 0.881 g/mL at 25 °C (lit.)
vapor density 3 (vs air)
refractive index n20/D 1.42(lit.)
Flash point 4 °F
storage temp. Store below +30°C.
solubility >80.2g/l
form Liquid
color Clear colorless
Odor at 0.10?%?in?dipropylene glycol. pungent sweet ethereal
Water Solubility 80 g/L (25 ºC)
Merck 14,9217
BRN 102436
Dielectric constant 7.3(30℃)
InChIKey DHXVGJBLRPWPCS-UHFFFAOYSA-N
LogP 0.950
CAS DataBase Reference 142-68-7(CAS DataBase Reference)
FDA UNII V06I3ILG6B
NIST Chemistry Reference 2H-Pyran, tetrahydro-(142-68-7)
EPA Substance Registry System Tetrahydropyran (142-68-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  F,Xi,Xn
Risk Statements  11-36/37/38-9-19-52/53-22
Safety Statements  9-16-26-33-36-61
RIDADR  UN 1993 3/PG 2
WGK Germany  3
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29321100
NFPA 704
3
1

Tetrahydropyran price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 293105 Tetrahydropyran anhydrous, 99% 142-68-7 1l $309.6 2024-03-01 Buy
TCI Chemical T0110 Tetrahydropyran >98.0%(GC) 142-68-7 25mL $16 2024-03-01 Buy
TCI Chemical T0110 Tetrahydropyran >98.0%(GC) 142-68-7 100mL $45 2024-03-01 Buy
Alfa Aesar A13392 Tetrahydropyran 98+% 142-68-7 100ml $54.5 2024-03-01 Buy
Alfa Aesar A13392 Tetrahydropyran 98+% 142-68-7 500ml $206 2024-03-01 Buy
Product number Packaging Price Buy
293105 1l $309.6 Buy
T0110 25mL $16 Buy
T0110 100mL $45 Buy
A13392 100ml $54.5 Buy
A13392 500ml $206 Buy

Tetrahydropyran Chemical Properties,Uses,Production

Description

Tetrahydropyran (THP) is the organic compound consisting of a saturated six-membered ring containing five carbon atoms and one oxygen atom. It is named by reference to pyran, which contains two double bonds, and may be produced from it by adding four hydrogens. Tetrahydropyran can be used as a solvent in various classical organic reactions such as radical reactions, palladium-catalyzed coupling, and Grignard reactions.

Chemical Properties

colorless to light yellow liquid

Uses

It is is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and dyestuff. They are also used as important solvents, as chemical intermediate and as monomer for ring-opening polymerization.

Definition

ChEBI: A saturated organic heteromonocyclic parent that is cyclohexane in which one of the carbon atoms has been replaced by an oxygen atom.

Purification Methods

Dry oxane with CaH2, then pass it through a column of silica gel to remove olefinic impurities and fractionally distil it. Free it from peroxides and moisture by refluxing with sodium, then distil it from LiAlH4. Alternatively, peroxides can be removed by treatment with aqueous ferrous sulfate and sodium bisulfate, followed by solid KOH, and fractional distillation from sodium. [Beilstein 17 H 12, 17 I 6, 17 II 18, 17 III/IV 51, 17/1 V 64.]

542-28-9
142-68-7
Synthesis of Tetrahydropyran from delta-Valerolactone
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View Lastest Price from Tetrahydropyran manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetrahydropyran pictures 2023-07-27 Tetrahydropyran
142-68-7
US $1.10 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
Tetrahydropyran pictures 2023-07-27 Tetrahydropyran
142-68-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Tetrahydropyran pictures 2021-11-13 Tetrahydropyran
142-68-7
US $10.00 / KG 1KG 99% 5tons Hebei Guanlang Biotechnology Co., Ltd.
  • Tetrahydropyran pictures
  • Tetrahydropyran
    142-68-7
  • US $1.10 / g
  • 99.0% Min
  • Shaanxi Didu New Materials Co. Ltd
  • Tetrahydropyran pictures
  • Tetrahydropyran
    142-68-7
  • US $10.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
TETRAHYDROPYRAN PENTAMETHYLENE OXIDE 2H-pyran,tetrahydro- Etrahydropyran Uromodulin human Pentamethylene oxide 3,4-Dihydro-2H-pyran THP tetrahydro-2h-pyra TETRAHYDROPYRAN, REAGENTPLUS, 99% TETRAHYDROPYRAN, ANHYDROUS, 99% Pentamethyleneoxide,THP 1,5-EPOXYPENTANE Tetrahydropyran, 98+% 3,4,5,6-Tetrahydro-2H-pyran Tetrahydropyran,99% Tetarhydropyran 4-tetrahydropyran Pyrantetrahydride THP Pentamethylene Oxide Four hydrogen pyranoid Four hydrogen pyran MKCD2 Tamm-Horsfall THGP Tetrahydropiran Tetrahydropyran > TETRAHYDROPYRAN FOR SYNTHESIS Tetrahydropyran ISO 9001:2015 REACH THP OXACYCLOHEXANE UMOD Tetrahydro-2H-pyran tetrahydropyrane Timolol Impurity 11 142-68-7 CH25O C6H13O3PO BioChemical Anhydrous Grade Solvents Solvents Anhydrous Solvents Solvent Bottles Solvent by Application Solvent Packaging Options Solvents Sure/Seal Bottles