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Methyl 4-bromobenzoate

Methyl 4-bromobenzoate structure

CAS No.: 619-42-1

Chemical Name:: Methyl 4-bromobenzoate

Synonyms: METHYL P-BROMOBENZOATE;BRBSME;NSC 9392;RARECHEM AL BF 0075;Methyl 4-bromobenzoa;Methyl-4-brombenzoat;Methy14-bromobenzoate;METHYL 4-BROMOBENZOATE;Methyl 4-bromobenzoate,99%;Methyl 4-bromobenzoate 99%

CBNumber:: CB2139717

Molecular Formula:: C8H7BrO2

Molecular Weight:: 215.04

MDL Number:: MFCD00013531

MOL File:: 619-42-1.mol

MSDS File:: SDS

Last updated:2024-04-09 13:47:46

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Methyl 4-bromobenzoate Properties

Melting point	77-81 °C (lit.)
Boiling point	252.95°C (rough estimate)
Density	1,689 g/cm³
refractive index	1.5500 (estimate)
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Crystals or Crystalline Powder
color	White
Water Solubility	Insoluble in water.
Merck	14,1408
BRN	2045132
InChIKey	HANNIMAAZKBBRE-UHFFFAOYSA-N
CAS DataBase Reference	619-42-1(CAS DataBase Reference)
FDA UNII	UB1YSJ5XAR
NIST Chemistry Reference	4-Bromobenzoic acid methyl ester(619-42-1)
EPA Substance Registry System	Benzoic acid, 4-bromo-, methyl ester (619-42-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-24/25

WGK Germany

TSCA

Yes

HS Code

29163990

NFPA 704

	1
2		0

Methyl 4-bromobenzoate price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	407593	Methyl 4-bromobenzoate 99%	619-42-1	10g	$117	2024-03-01	Buy
TCI Chemical	B0556	Methyl 4-Bromobenzoate >98.0%(GC)	619-42-1	10g	$50	2024-03-01	Buy
TCI Chemical	B0556	Methyl 4-Bromobenzoate >98.0%(GC)	619-42-1	25g	$83	2024-03-01	Buy
Alfa Aesar	A15517	Methyl 4-bromobenzoate, 98+%	619-42-1	5g	$47.65	2024-03-01	Buy
Alfa Aesar	A15517	Methyl 4-bromobenzoate, 98+%	619-42-1	25g	$171	2024-03-01	Buy

Product number	Packaging	Price	Buy
407593	10g	$117	Buy
B0556	10g	$50	Buy
B0556	25g	$83	Buy
A15517	5g	$47.65	Buy
A15517	25g	$171	Buy

Methyl 4-bromobenzoate Chemical Properties,Uses,Production

Chemical Properties

WHITE CRYSTALS OR CRYSTALLINE POWDER

Uses

Methyl 4-bromobenzoate is used as a starting material in the synthesis of three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine and methyl 4-tri-n-butylstannylbenzoate. It is also used to stimulate microbial dechlorination of polychlorinated biphenyls. Further, it is used in the preparation of stable radioiodinating reagent to label monoclonal antibodies for radiotherapy of cancer.

Uses

Methyl 4-bromobenzoate is a halogenated benzoate used as a reagent in organic synthesis. It can be used to stimulate microbial dechlorination of PCBs. By condensing methyl 4-bromobenzoate with 3-buten-1-ol, 4-(4-methylphenyl)butanal can be obtained.

Application

Methyl 4-bromobenzoate may be used in the following syntheses:

Methyl 4-(2-pyridyl)benzoate by cross coupling reaction with lithium 2-pyridyltriolborate.
Methyl 4-imidazo[1,2-a]pyridin-3-ylbenzoate by ligand-free Pd(OAc)2 catalyzed reaction with Imidazo[1,2-a]pyridine.
Methyl (E)-4-[3-(2-methoxycarbonylvinyl)-thiophen-2-yl]acrylate by reacting with methyl (E)-3-(thiophen-3-y)lacrylate.

General Description

Methyl 4-bromobenzoate is a para-substituted aryl bromide. Mol-ecules of methyl 4-bromobenzoate are almost planar. The compound is isostructural with methyl 4-iodo-benzoate. The Zeeman effect on the N.Q.R. (nuclear quadrupole resonance) of methyl 4-bromobenzoate on single crystals, has been investigated by the ′geometric method′.

Purification Methods

Crystallise the ester from MeOH. EtOH (m 81o, also 80.5o, 79.5o) or *C6H6/pet ether (m 78-79o). [Beilstein 9 H 352, 9 III 1405, 9 IV 1017.]

Methyl 4-bromobenzoate synthesis

Synthesis of Methyl 4-bromobenzoate from Methanol and 4-Bromobenzoic acid

Methyl 4-bromobenzoate Preparation Products And Raw materials

Raw materials

Benzenecarbothioic acid, 4-bromo-, O-methyl ester 4-BROMOBENZALDEHYDE DIMETHYL ACETAL

Preparation Products

2,3,5,6-Tetrafluoropyridine 4-ETHYNYL-BENZOIC ACID 2-(4-bromophenyl)-1,3,4-oxadiazole METHYL 4'-BROMO[1,1'-BIPHENYL]-4-CARBOXYLATE 4-(TRIMETHYLSILYLETHYNYL)BENZYL ALCOHOL

4-ETHYNYLBENZYL ALCOHOL 97 3-ETHYNYL-BENZOIC ACID METHYL ESTER METHYL 4'-HYDROXY[1,1'-BIPHENYL]-4-CARBOXYLATE 1-(4-bromophenyl)-2-chloroethan-1-one METHYL 4-VINYLBENZOATE

4'-Isopropylacetophenone Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate Methyl benzoate TERT-BUTYL 4-(4-(METHOXYCARBONYL)PHENYLAMINO)PIPERIDINE-1-CARBOXYLATE

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Methyl 4-bromobenzoate Suppliers

Global( 426)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Dideu Industries Group Limited	+86-29-89586680 +86-15129568250	1026@dideu.com	China	29321	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7534	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15371	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
Zjartschem	+86-571-8723 8903 jocelynpan@zjarts.com	jocelynpan@zjarts.com	CHINA	993	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58

Supplier	Advantage
Dideu Industries Group Limited	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Zjartschem	58
career henan chemical co	58

View Lastest Price from Methyl 4-bromobenzoate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-09	Methyl 4-bromobenzoate 619-42-1	US $5.00-0.10 / KG	1KG	98%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-09-06	Methyl 4-bromobenzoate 619-42-1	US $0.00 / KG	1KG	99%	500000kg	Hebei Guanlang Biotechnology Co., Ltd.
2023-07-27	Methyl 4-bromobenzoate 619-42-1	US $1.50 / g	1g	99.0% Min	100 Tons	Shaanxi Didu New Materials Co. Ltd

Methyl 4-bromobenzoate
619-42-1
US $5.00-0.10 / KG
98%
Henan Fengda Chemical Co., Ltd

Methyl 4-bromobenzoate
619-42-1
US $0.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

Methyl 4-bromobenzoate
619-42-1
US $1.50 / g
99.0% Min
Shaanxi Didu New Materials Co. Ltd

Methyl 4-bromobenzoate Spectrum

Methyl 4-bromobenzoate(619-42-1)MS Methyl 4-bromobenzoate(619-42-1)¹HNMR Methyl 4-bromobenzoate(619-42-1)¹³CNMR Methyl 4-bromobenzoate(619-42-1)IR1 Methyl 4-bromobenzoate(619-42-1)IR2 Methyl 4-bromobenzoate(619-42-1)IR3 Methyl 4-bromobenzoate(619-42-1)Raman

619-42-1(Methyl 4-bromobenzoate)Related Search:

4-Bromobenzoic acid 4-Aminobenzoic acid Bensulfuron methyl Thiophanate-methyl Methyl bromoacetate

Methyl benzoate Methyl acetate METHYL THIOPHENE-2-CARBOXYLATE Methyl 2-bromo-2-methylpropionate Methylparaben

Kresoxim-methyl Methyl 4-cyanobenzoate Benzoic acid Methyl acrylate Methyl 4-(bromomethyl)benzoate

4-Bromomethylbenzoic acid 4-Nitrophenylacetic acid 4-Nitrophenyl chloroformate

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RARECHEM AL BF 0075 BRBSME METHYL 4-BROMOBENZOATE 4-BROMOBENZOIC ACID METHYL ESTER 4-bromo-benzoicacimethylester Benzoic acid, 4-bromo-, methyl ester Benzoic acid, p-bromo-, methyl ester Benzoicacid,4-bromo-,methylester p-Bromobenzoic acid, methyl ester 1-BROMO-4-(METHOXYCARBONYL)BENZENE Methyl 4-bromobenzoate, 98+% Methyl 4-bromobenzoate,99% Methyl 4-bromobenzoa 4-Methoxycarbonyl-1-broMobenzene 4-Methoxycarbonylphenyl BroMide NSC 9392 ThebroMo benzoic acidMethyl ester The broMine benzoic acid Methyl ester Methyl 4-bromobenzoate 99% Methyl 4-Bromobenzoate > Methyl 4-bromobenzoate, 99%, for synthesis Methyl-4-brombenzoat High purity CAS 619-42-1 Methyl 4-bromobenzoate in stock METHYL P-BROMOBENZOATE Methy14-bromobenzoate 619-42-1 BrC6H4CO2CH3 Alphabetic Esters Organic Building Blocks META - METH Carbonyl Compounds C8 to C9 Analytical Chromatography Product Catalog Analytical Standards Building Blocks Pyridines C8 to C9 Carbonyl Compounds Esters Aromatic Esters Acids & Esters Bromine Compounds bc0001