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2,6-DIMETHOXY-1,4-BENZOQUINONE

CAS No.
530-55-2
Chemical Name:
2,6-DIMETHOXY-1,4-BENZOQUINONE
Synonyms
dmbq;2,6-Dimethoxyquinone;56336;LABOTEST-BB LT00159337;2,6-DIMETHOXY-P-QUINONE;Sitagliptin Impurity 162;2,6-DIMETHOXYBENZOQUINONE;Dimethoxybenzoquinone,2,6-;Phloroglucinol Impurity 43;2,6-dimethoxy-p-benzoquinon
CBNumber:
CB2146779
Molecular Formula:
C8H8O4
Molecular Weight:
168.15
MDL Number:
MFCD00016368
MOL File:
530-55-2.mol
MSDS File:
SDS
Last updated:2023-05-18 11:31:17

2,6-DIMETHOXY-1,4-BENZOQUINONE Properties

Melting point 253-257 °C (dec.) (lit.)
Boiling point 257.07°C (rough estimate)
Density 1.3037 (rough estimate)
refractive index 1.5090 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO: soluble(lit.)
form Crystalline Powder
color Yellow
Merck 14,3225
BRN 2048182
Stability Stable. Combustible. Incompatible with oxidizing agents.
CAS DataBase Reference 530-55-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1Z701W789S

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  DK4750000
HS Code  29146990
NFPA 704
1
2 0

2,6-DIMETHOXY-1,4-BENZOQUINONE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 428566 2,6-Dimethoxy-1,4-benzoquinone 97% 530-55-2 5g $69.7 2024-03-01 Buy
Sigma-Aldrich 428566 2,6-Dimethoxy-1,4-benzoquinone 97% 530-55-2 25g $198.6 2024-03-01 Buy
TCI Chemical D2706 2,6-Dimethoxy-1,4-benzoquinone >97.0%(HPLC) 530-55-2 5g $109 2024-03-01 Buy
TCI Chemical D2706 2,6-Dimethoxy-1,4-benzoquinone >97.0%(HPLC) 530-55-2 25g $142 2021-12-16 Buy
Alfa Aesar A14936 2,6-Dimethoxy-p-benzoquinone, 98% 530-55-2 1g $25.65 2024-03-01 Buy
Product number Packaging Price Buy
428566 5g $69.7 Buy
428566 25g $198.6 Buy
D2706 5g $109 Buy
D2706 25g $142 Buy
A14936 1g $25.65 Buy

2,6-DIMETHOXY-1,4-BENZOQUINONE Chemical Properties,Uses,Production

Description

2,6-DimethoXY-1A-benzoquinone is an allergen in more than 50 different plants and wood species, e.g., mahogany, macore~, sipo, wenge, oak, beech, elms, and poplar. With acamelin, it is one of the allergens of Acacia melanoxylon. Sensitization can occur in woodworkers such as carpenters, joiners and sawyers.

Chemical Properties

yellow powder

Uses

2,6-Dimethoxy-1,4-benzoquinone may be used in the synthesis of 2-aryl-3,5-dimethoxy-1,4-benzoquinone derivatives.

Synthesis Reference(s)

Chemistry Letters, 16, p. 771, 1987
The Journal of Organic Chemistry, 45, p. 1596, 1980 DOI: 10.1021/jo01297a010

General Description

2,6-Dimethoxy-1,4-benzoquinone (DBQ, 2,6-DMBQ, DMOBQ) is a 1,4-benzoquinone derivative. It is a wood allergen, has been reported to cause various skin and mucosal symptoms on exposure to wood dusts. It is formed as a product due to the activity of bacterial Azospirillum lipoferum laccase on phenolic compounds of the syringic type. DBQ is one of the components isolated from the rhizome of Gynura japonica with a potential to show anti-platelet aggregation activity in vitro. It is an anticancer agent, whose kinetics of cyclic redox transformation induced by ascorbate (AscH-) has been studied using the Clark electrode and ESR techniques. Its electrochemical reduction in acetonitrile has been studied.

Contact allergens

2,6-Dimethoxy-1,4-benzoquinone is an allergen in more than 50 different plants and wood species, e.g., mahog- any, macore, sipo, wenge, oak, beech, elms, and poplar. With acamelin, it is one of the allergens of Acacia mel- anoxylon. Sensitization can occur in woodworkers such as carpenters, joiners, and sawyers.

Purification Methods

Crystallise the quinone from H2O or acetic acid. It sublimes at 175-180o/1mm. It has UV with max at 287 and 377nm (CHCl3). [Beilstein 8 H 385, 8 I 683, 8 II 433, 8 III 3354, 8 IV 2710,]

134-96-3
530-55-2
Synthesis of 2,6-DIMETHOXY-1,4-BENZOQUINONE from Syringaldehyde

2,6-DIMETHOXY-1,4-BENZOQUINONE Preparation Products And Raw materials

Raw materials

Preparation Products

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+1-781-999-5354 support@targetmol.com United States 19973 58

View Lastest Price from 2,6-DIMETHOXY-1,4-BENZOQUINONE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,6-DIMETHOXY-1,4-BENZOQUINONE pictures 2020-01-05 2,6-DIMETHOXY-1,4-BENZOQUINONE
530-55-2
US $1.00 / KG 1KG 95-99% 1ton Career Henan Chemical Co
2,6-DIMETHOXY-1,4-BENZOQUINONE 2,6-DIMETHOXY-P-QUINONE 2,6-DIMETHOXY-P-BENZOQUINONE 2,6-DIMETHOXYBENZOQUINONE 2,6-DIMETHOXY-PARA-BENZOQUINONE 2,5-Cyclohexadiene-1,4-dione, 2,6-dimethoxy- 2,6-Dimethoxybenzo-1,4-quinone 2,6-dimethoxy-p-benzoquinon 4-dione,2,6-dimethoxy-5-cyclohexadiene-1 56336 Dimethoxybenzoquinone,2,6- p-Benzoquinone, 2,6-dimethoxy- LABOTEST-BB LT00159337 2,6-DiMethoxycyclohexa-2,5-diene-1,4-dione 2,6-DiMethoxy-p-benzoquinone, 98%, 98% 2,6-Dimethoxy-1,4-benzoquinone 97% 2,6-dimethoxy-2,5-cyclohexadiene-1,4-dione 2,6-Dimethoxy-1,4-benzoquinone,97% 2,6-Dimethoxy-1,4-benzoquine Phloroglucinol Impurity 43 2,6-Dimethoxy-1,4-benzoquinone> 2,6-Dimethoxy-1,4-Benzoquinone[2,6-Dimethoxycyclohexa-2,5-Diene-1,4-Dione 2,6-Dimethoxyquinone dmbq Sitagliptin Impurity 162 2,6-Dimethoxy-1,4-benzoquinone, ≥ 95.0% 530-55-2 Benzoquinones Building Blocks Carbonyl Compounds C7 to C8 Ketones Organic Building Blocks Anthraquinones, Hydroquinones and Quinones Benzoquinones