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Di-tert-butylchlorophosphane

CAS No.
13716-10-4
Chemical Name:
Di-tert-butylchlorophosphane
Synonyms
DI-TERT-BUTYLCHLOROPHOSPHINE;Chlorodi-tert-butylphosphine;Di-t-butyL;AURORA KA-1319;(tert-C4H9)2PCl;98% [(CH3)3C]2PCl;Phosphonous dichloride;DI-TERT-BUTYLCHLOROPHO;DI-T-BUTYLCHLOROPHOSPHINE;DI-TERT-BUTYLCHLOROPHOSPHANE
CBNumber:
CB2200163
Molecular Formula:
C8H18ClP
Molecular Weight:
180.66
MDL Number:
MFCD00008815
MOL File:
13716-10-4.mol
MSDS File:
SDS
Last updated:2023-12-21 17:48:05

Di-tert-butylchlorophosphane Properties

Melting point 2-3°C
Boiling point 48 °C/3 mmHg (lit.)
Density 0.951 g/mL at 25 °C (lit.)
refractive index n20/D 1.482(lit.)
Flash point 142 °F
solubility Miscible with terahydrofuran.
form Liquid
Specific Gravity 0.951
color Clear colorless
Sensitive Air & Moisture Sensitive
InChIKey MCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference 13716-10-4(CAS DataBase Reference)
NIST Chemistry Reference Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45-25
RIDADR  UN 3265 8/PG 2
WGK Germany  3
TSCA  No
HazardClass  8
PackingGroup  II
HS Code  29310099
NFPA 704
2
3 2
W

Di-tert-butylchlorophosphane price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 301558 Di-tert-butylchlorophosphine 96% 13716-10-4 5g $113 2024-03-01 Buy
Sigma-Aldrich 301558 Di-tert-butylchlorophosphine 96% 13716-10-4 25g $441 2024-03-01 Buy
TCI Chemical D3632 Di-tert-butylchlorophosphine >95.0%(GC) 13716-10-4 5g $72 2024-03-01 Buy
TCI Chemical D3632 Di-tert-butylchlorophosphine >95.0%(GC) 13716-10-4 25g $244 2024-03-01 Buy
Alfa Aesar B20998 Di-tert-butylchlorophosphine, 96% 13716-10-4 5g $118 2024-03-01 Buy
Product number Packaging Price Buy
301558 5g $113 Buy
301558 25g $441 Buy
D3632 5g $72 Buy
D3632 25g $244 Buy
B20998 5g $118 Buy

Di-tert-butylchlorophosphane Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Uses

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.

Application

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Precautions

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

819-19-2
13716-10-4
Synthesis of Di-tert-butylchlorophosphane from Di-tert-butylphosphine
Global( 275)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 370 58
Puyang Huicheng Electronic Materials Co., Ltd.
+86-0393-+86-0393-8910800 +8615839383373 info@huichengchem.com China 515 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12452 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5988 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 6645 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 14764 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9354 55
AB PharmaTech,LLC
323-480-4688 United States 989 55

View Lastest Price from Di-tert-butylchlorophosphane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Di-tert-butylchlorophosphane pictures 2024-02-23 Di-tert-butylchlorophosphane
13716-10-4
US $85.00-515.00 / g 25g 0.96 25kg Shanghai UCHEM Inc.
Di-tert-butylchlorophosphane pictures 2023-11-11 Di-tert-butylchlorophosphane
13716-10-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Di-tert-butylchlorophosphane pictures 2023-09-26 Di-tert-butylchlorophosphane
13716-10-4
US $10.00-1.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
AURORA KA-1319 Bis(1,1-dimethylethyl)-phosphinous chloride DI-T-BUTYLCHLOROPHOSPHINE DI-T-BUTYLPHOSPHINOUS CHLORIDE DI-TERT-BUTYLPHOSPHORUS CHLORIDE DI-TERT-BUTYLCHLOROPHOSPHANE (tert-C4H9)2PCl Di-tert-Butylphosphinous chloride Phosphinous chloride, di-tert-butyl- DI-TERT-BUTYLCHLOROPHOSPHINE (DTBCP) Di-t-butylchlorophosphine,min.98% Phosphonous dichloride Di-tert-B-butylchlorophosphine, 96% Di-t-butylchlorophosphine, min. 98% Di-tert-butylchlorophosphine,96% Phosphonous Dichloride, Bis[1,1-dimethylethyl]- Di-t-butylchlorophosphine, 98+% Di-tert-butylchlorophosphine, 96% 25ML 98% [(CH3)3C]2PCl Di-tert-butylchlorophosphine, 96%, AcroSeal Di-tert-butylchlorophosphine, AcroSeal, 96% Di-tert-butylchlorophosphanec Di-tert-butylchlorophosphine 96% Di-t-butylchlorophosphine,98% [(CH3)3C]2PCl Di-tert-butylchlorophosphane Bis(1,1-dimethylethyl)-phosphinous chloride Di-tert-butylchlorophosphine, 96%, AcroSeal&trade Phosphinous chloride, P,P-bis(1,1-dimethylethyl)- Di-t-butyL Di-tert-butylchlorophosphine> DI-TERT-BUTYLCHLOROPHO DI-TERT-BUTYLCHLOROPHOSPHINE Chlorodi-tert-butylphosphine 13716-10-4 13716-01-4 CH33C2PCl C8H18ClP Catalysis and Inorganic Chemistry Phosphorus Compounds Phosphorus Precursors organophosphine halide Catalysis and Inorganic Chemistry Phosphorus Compounds Phosphorus Precursors Phosphines Ligand Chlorophosphines Achiral Phosphine Alkyl Phosphine P-Cl