(4bα,7E,8aβ,10aα)-Tetradecahydro-9β-hydroxy-1α,4aβ,8α-trimethyl-7-[2-[2-(methylamino)ethoxy]-2-oxoethylidene]-10-oxo-1β-phenanthrenecarboxylic acid methyl ester

CAS No.
36150-74-0
Chemical Name:
(4bα,7E,8aβ,10aα)-Tetradecahydro-9β-hydroxy-1α,4aβ,8α-trimethyl-7-[2-[2-(methylamino)ethoxy]-2-oxoethylidene]-10-oxo-1β-phenanthrenecarboxylic acid methyl ester
Synonyms
Norerythrosuamine;(4bα,7E,8aβ,10aα)-Tetradecahydro-9β-hydroxy-1α,4aβ,8α-trimethyl-7-[2-[2-(methylamino)ethoxy]-2-oxoethylidene]-10-oxo-1β-phenanthrenecarboxylic acid methyl ester
CBNumber:
CB22346898
Molecular Formula:
C24H37NO6
Molecular Weight:
435.55368
MDL Number:
MOL File:
36150-74-0.mol

(4bα,7E,8aβ,10aα)-Tetradecahydro-9β-hydroxy-1α,4aβ,8α-trimethyl-7-[2-[2-(methylamino)ethoxy]-2-oxoethylidene]-10-oxo-1β-phenanthrenecarboxylic acid methyl ester Chemical Properties,Uses,Production

Description

An amorphous minor alkaloid obtained from Erythrophleurn guineense, this base has [α] 20 D- 71.9° (c 0.44, EtOH). The structure has been determined from the infrared, NMR and mass spectra. Oxidation with chromic acid yields the dehydro-compound (q.v.) which also occurs naturally.

References

Friedrich-Fiechtl, Spiteller., Chern. Ber., 104, 3535 (1971)

(4bα,7E,8aβ,10aα)-Tetradecahydro-9β-hydroxy-1α,4aβ,8α-trimethyl-7-[2-[2-(methylamino)ethoxy]-2-oxoethylidene]-10-oxo-1β-phenanthrenecarboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

(4bα,7E,8aβ,10aα)-Tetradecahydro-9β-hydroxy-1α,4aβ,8α-trimethyl-7-[2-[2-(methylamino)ethoxy]-2-oxoethylidene]-10-oxo-1β-phenanthrenecarboxylic acid methyl ester Norerythrosuamine 36150-74-0