2-Azidobenzoic acid

CAS No.
31162-13-7
Chemical Name:
2-Azidobenzoic acid
Synonyms
o-Azidobenzoic acid;2-Azidobenzoic acid;2-Azidobenzoic acid solution;2-Azidobenzoic acid solution ~0.25 M in tert-butyl methyl ether, >=95.0% (HPLC);2-azidobenzoic acidQ: What is 2-azidobenzoic acid Q: What is the CAS Number of 2-azidobenzoic acid
CBNumber:
CB22348034
Molecular Formula:
Molecular Weight:
0
MDL Number:
MFCD00211421
MOL File:
31162-13-7.mol
Last updated:2023-07-17 08:27:58

2-Azidobenzoic acid Properties

Melting point 142-143 °C (decomp)
Flash point -33℃
storage temp. -20°C
solubility Chloroform (Slightly, Sonicated), DMSO (Slightly)
form Solid
color Pale Brown to Light Brown
BRN 1950619

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319
Precautionary statements  P210-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-38
Safety Statements  16
RIDADR  UN 2398 3 / PGII
WGK Germany  3

2-Azidobenzoic acid price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 727458 2-Azidobenzoic acid solution ~0.25 M in tert-butyl methyl ether, ≥95.0% (HPLC) 31162-13-7 10ml $188 2023-06-20 Buy
TRC A822058 2-AzidobenzoicAcid 31162-13-7 100mg $45 2021-12-16 Buy
TRC A822058 2-AzidobenzoicAcid 31162-13-7 500mg $55 2021-12-16 Buy
AK Scientific 0049AQ 2-Azidobenzoic acid solution 31162-13-7 10ml $234 2021-12-16 Buy
Product number Packaging Price Buy
727458 10ml $188 Buy
A822058 100mg $45 Buy
A822058 500mg $55 Buy
0049AQ 10ml $234 Buy

2-Azidobenzoic acid Chemical Properties,Uses,Production

Synthesis

The solution of the corresponding 2-aminobenzoic acid (15.3 mmol) in water (15 mL) and conc. HCl (17 mL) was placed in a 200 mL beaker and cooled to 5 °C. To this mixture a precooled solution of sodium nitrite (1.06 g, 15.3 mmol in 10 mL water) was added drop wise with vigorous stirring. After stirring for 15 min, a solution of sodium azide (1.08 g, 16.6 mmol) in 10 mL water was added and the resulting mixture was gradually warmed to room temperature and stirred at this temperature for about 2 h. The white crystalline azides precipitated from the reaction mixture and were filtered off. After washing with cold water and drying in the dark at room temperature the azides were recrystallized from heptane/benzene (v/v, 1:1). 1H NMR (400 MHz, CDCl3) δ 10.65  (s, 1H), 8.11 (dd, J = 7.9, 1.5 Hz, 1H), 7.66 – 7.56 (m, 1H), 7.31 – 7.21 (m, 2H). 13C  NMR (101 MHz, CDCl3) δ 168.8, 140.4, 134.6, 133.4, 125.1, 120.9, 119.7.

Uses

2-Azidobenzoic Acid can be used for polyethylene surface with aryl azides.

118-92-3
31162-13-7
Synthesis of 2-Azidobenzoic acid from Anthranilic acid

2-Azidobenzoic acid Preparation Products And Raw materials

2-Azidobenzoic acid Suppliers

Global( 7)Suppliers
Supplier Tel Email Country ProdList Advantage
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Wuhan Shanhai Zhihe Biotechnology Co., Ltd. 17771424646 shoubull@126.com China 964 58
Shanghai Yingxin laboratory equipment Co., Ltd 021-021-59178156 15300768757 359382369@qq.com China 10680 58
Shanghai Guchen Biotechnology Co., LTD 021-34675735 19147740836 1986399151@qq.com China 9849 58
2-Azidobenzoic acid o-Azidobenzoic acid 2-Azidobenzoic acid solution 2-Azidobenzoic acid solution ~0.25 M in tert-butyl methyl ether, >=95.0% (HPLC) 2-azidobenzoic acidQ: What is 2-azidobenzoic acid Q: What is the CAS Number of 2-azidobenzoic acid 31162-13-7