[aR,(-)]-1,1'-Binaphthalene

CAS No.
24161-30-6
Chemical Name:
[aR,(-)]-1,1'-Binaphthalene
Synonyms
1,1'-Binaphthalene, (1R)-;[aR,(-)]-1,1'-Binaphthalene
CBNumber:
CB22379333
Molecular Formula:
C20H14
Molecular Weight:
254.33
MDL Number:
MOL File:
24161-30-6.mol

[aR,(-)]-1,1'-Binaphthalene Chemical Properties,Uses,Production

Purification Methods

Purify 1,1’-binaphthyl through a silica gel column with Me2CO/*C6H6 [or Al2O3 with 10% *C6H6/pet ether (b 30-60o)] and recrystallise it from EtOH, pentane, or slow evaporation of *C6H6, Me2CO or Et2O solutions. Half life ~10hours at 25o in various solvents. [Wilson & Pincock J Am Chem Soc 97 1474 1975, Akimoto & Yamada Tetrahedron 27 5999 1971, Beilstein 5 I 358, 5 II 642, 5 III 2465, 5 IV 2634.]

[aR,(-)]-1,1'-Binaphthalene Preparation Products And Raw materials

Raw materials

Preparation Products

[aR,(-)]-1,1'-Binaphthalene 1,1'-Binaphthalene, (1R)- 24161-30-6