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Ethyl benzoylacetate

Ethyl benzoylacetate structure

CAS No.: 94-02-0

Chemical Name:: Ethyl benzoylacetate

Synonyms: ETHYL 3-OXO-3-PHENYLPROPANOATE;ETHYL 3-OXO-3-PHENYLPROPIONATE;FEMA 2423;BENZOYLACETIC ACID ETHYL ESTER;AKOS 92622;FEMA No. 2423;AKOS BBS-00004233;Ethylbenzoylacetat;thyl benzoylacetate;ETHYL BENZOYLACETATE

CBNumber:: CB2428608

Molecular Formula:: C11H12O3

Molecular Weight:: 192.21

MDL Number:: MFCD00009196

MOL File:: 94-02-0.mol

MSDS File:: SDS

Last updated:2024-03-14 18:29:10

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Ethyl benzoylacetate Properties

Melting point	<0 °C
Boiling point	265-270 °C (lit.)
Density	1.11 g/mL at 25 °C (lit.)
vapor density	6.6 (vs air)
vapor pressure	1 hPa (108 °C)
FEMA	2423 \| ETHYL BENZOYLACETATE
refractive index	n20/D 1.52(lit.)
Flash point	147 °F
storage temp.	Store below +30°C.
solubility	alcohol: miscible
form	Powder
pka	9.85±0.23(Predicted)
color	Brown
Odor	at 100.00 %. fruity cherry naphthyl hawthorn cumin phenolic almond spicy woody maraschino cherry
Odor Type	fruity
Water Solubility	INSOLUBLE
Sensitive	Light Sensitive
Merck	14,3767
JECFA Number	834
BRN	389944
Dielectric constant	12.8（20℃）
InChIKey	GKKZMYDNDDMXSE-UHFFFAOYSA-N
LogP	1.87
Substances Added to Food (formerly EAFUS)	ETHYL BENZOYLACETATE
FDA 21 CFR	172.515
CAS DataBase Reference	94-02-0(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	K8CHJ4MKM0
NIST Chemistry Reference	Ethyl benzoylacetate(94-02-0)
EPA Substance Registry System	Benzenepropanoic acid, .beta.-oxo-, ethyl ester (94-02-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H332-H335

Precautionary statements

P261-P280-P305+P351+P338

Safety Statements

24/25

WGK Germany

RTECS

AF4878000

Autoignition Temperature

375 °C DIN 51794

TSCA

Yes

HazardClass

IRRITANT

HS Code

29183000

Toxicity

LD50 orally in Rabbit: > 5000 mg/kg

NFPA 704

	1
		0

Ethyl benzoylacetate price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	8.01808	Ethyl benzoylacetate for synthesis	94-02-0	100mL	$49.7	2024-03-01	Buy
Sigma-Aldrich	8.01808	Ethyl benzoylacetate for synthesis	94-02-0	250ML	$103	2024-03-01	Buy
Sigma-Aldrich	12990	Ethyl benzoylacetate technical, ≥95% (HPLC)	94-02-0	100ml	$75.6	2024-03-01	Buy
Sigma-Aldrich	12980	Ethyl benzoylacetate redist., ≥97.0% (HPLC)	94-02-0	100ml	$274	2024-03-01	Buy
TCI Chemical	B0097	Ethyl Benzoylacetate >95.0%(GC)(T)	94-02-0	25g	$21	2024-03-01	Buy

Product number	Packaging	Price	Buy
8.01808	100mL	$49.7	Buy
8.01808	250ML	$103	Buy
12990	100ml	$75.6	Buy
12980	100ml	$274	Buy
B0097	25g	$21	Buy

Ethyl benzoylacetate Chemical Properties,Uses,Production

Chemical Properties

Brownish liquid

Chemical Properties

Ethyl benzoylacetate has a brandy-like odor and sweet, woody, cherry, phenolic-like flavor.

Uses

Ethyl benzoylacetate (Best) is used as intermediate for different organic synthesis. Product Data Sheet

Uses

Ethyl benzoylacetate (Benzoylacetic acid ethyl ester) was used to prepare ethyl 2-fluoro-2-benzolyacetate. It was also used to synthesize iodonium ylides.

Uses

Ethyl benzoylacetate (Best) is used as an intermediate for different organic synthesis Product Data Sheet

Preparation

By condensation of ethyl benzoate with ethyl acetate (via Claisen condensation) using sodium ethoxide; another method also known.

Definition

ChEBI: Ethyl 3-oxo-3-phenylpropanoate is an aromatic ketone.

Taste threshold values

Taste characteristics at 10 ppm: sweet, cherry, fruity, berry-like with woody, jamy notes.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 28, p. 1864, 1985 DOI: 10.1021/jm00150a018
Journal of Heterocyclic Chemistry, 32, p. 723, 1995 DOI: 10.1002/jhet.5570320303
The Journal of Organic Chemistry, 38, p. 2731, 1973 DOI: 10.1021/jo00955a040

General Description

Ethyl benzoylacetate is an ester. It undergoes microbial reduction by bakers′ yeast (Saccharomyces cerevisiae), Beauveria sulfurescens or Geotrichum candidum to afford ethyl (S)-3-hydroxy-3-phenylpropionate. It undergoes Claisen condensation reaction with malononitrile to afford 2-cyano-5-phenyl-3,5-dioxopentanonitrile which on cyclization followed by coupling with diazonium salts yields azo derivatives.

Ethyl benzoylacetate Preparation Products And Raw materials

Raw materials

Ethyl acetoacetate Ethyl 3-oxobutanoate sodium salt Sodium oxide Sodium Acetophenone

Benzene Ammonium chloride Ethyl acetate Acetic acid Methanol

Sodium hydroxide Diethyl carbonate Benzoyl chloride PETROLEUM ETHER Ethyl benzoate

2-BENZOYLACETOACETIC ACID ETHYL ESTER

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Preparation Products

NORDALBERGIN ETHYL 2-HYDROXY-4-PHENYLPYRIMIDINE-5-CARBOXYLATE ETHYL 2-CHLORO-4-PHENYLPYRIMIDINE-5-CARBOXYLATE RUFLOXACIN PHENOXYACETIC ACID

Ciprofloxacin hydrochloride 3-(4-OXO-6-PHENYL-1,4-DIHYDRO-PYRIMIDIN-2-YLSULFANYL)-PROPIONIC ACID Ethyl 2-amino-4-phenyl-5-thiazolecarboxylate ETHYL 4-PHENYL-1,2,3-THIADIAZOLE-5-CARBOXYLATE 2,4-DIPHENYL-1,3-THIAZOLE-5-CARBALDEHYDE

ETHYL 2-HYDRAZINYL-4-PHENYLPYRIMIDINE-5-CARBOXYLATE 2-CHLORO-4-PHENYLPYRIMIDINE-5-CARBONYL CHLORIDE 5-CHLORO-1,3-DIPHENYL-1H-PYRAZOLE-4-CARBALDEHYDE 2-HYDROXY-4-PHENYLPYRIMIDINE-5-CARBOXYLIC ACID 2'-Benzoylacetanilide

Benzeneacetic acid, α-(hydroxymethylene)-, ethyl ester, (αZ)- 2-Phenylquinolin-4-ol

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Ethyl benzoylacetate Suppliers

Global( 438)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12453	58
Shandong Juchuang Chemical Co., LTD	+86-18885615001 +86-18885615001	admin@juchuangchem.com	China	387	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15371	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Shandong Juchuang Chemical Co., LTD	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Hubei Jusheng Technology Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58

View Lastest Price from Ethyl benzoylacetate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-03-15	Ethyl benzoylacetate 94-02-0	US $44.00-22.00 / kg	500kg	99.9	200ton	Shandong Juchuang Chemical Co., LTD
2023-09-26	Ethyl benzoylacetate 94-02-0	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-09-06	Ethyl benzoylacetate 94-02-0	US $0.00 / KG	1KG	99%	500000kg	Hebei Guanlang Biotechnology Co., Ltd.

Ethyl benzoylacetate
94-02-0
US $44.00-22.00 / kg
99.9
Shandong Juchuang Chemical Co., LTD

Ethyl benzoylacetate
94-02-0
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

Ethyl benzoylacetate
94-02-0
US $0.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

Ethyl benzoylacetate Spectrum

Ethyl benzoylacetate(94-02-0)MS Ethyl benzoylacetate(94-02-0)¹HNMR Ethyl benzoylacetate(94-02-0)¹³CNMR Ethyl benzoylacetate(94-02-0)IR1 Ethyl benzoylacetate(94-02-0)Raman

94-02-0(Ethyl benzoylacetate)Related Search:

Ethyl acetate PHENOXYACETIC ACID Ethylparaben Ethylbenzene Ethyl formate

Ethanol CHLOROETHANE Ethyl benzoate Phenylhydrazine Dibenzoylmethane

Benzoyl peroxide Ethyl benzoylformate Ethyl malonyl chloride Ethyl isobutyrylacetate Ethyl butyrylacetate

Ethyl acrylate PHENYL VALERATE Ethyl cellulose

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AKOS 92622 AKOS BBS-00004233 3-OXO-3-PHENYLPROPIONIC ACID ETHYL ESTER LABOTEST-BB LTBB001316 ETHYL BENZOYLACETATE ETHYL BETA-KETO-BETA-PHENYLPROPIONATE Ethyl 3-phenyl-3-oxopropanoate ETHYL 3-PHENYL-3-OXOPROPIONATE BETA-OXO BENZENEPROPANOIC ACID ETHYL ESTER Acetic acid, benzoyl-, ethyl ester Benzenepropanoic acid, beta-oxo-, ethyl ester Benzenepropanoicacid,.beta.-oxo-,ethylester Benzenepropanoicacid,b-oxo-,ethylester benzoyl-aceticaciethylester Ethylbenzoylacetat Benzoylacetic acid ethyl ester, Ethyl 3-oxo-3-phenylpropionate 1-Ethoxy-3-phenylpropane-1,3-dione Ethyl benzoylacetate min. 91.0% Ethyl benzoylacetate min. 98.0% Ethyl benzovlacetate Ethylbenzoylacetate,technical Ethyl benzoylacetate, 90% 100GR Ethyl benzoylacetate, 90% 50GR b-Oxobenzenepropanoic acid ethyl ester Ethyl b-oxobenzenepropanoate Ethyl benzoylacetate ,97% 3-phenyl-3-oxopropanoate 3-keto-3-phenyl-propionic acid ethyl ester 3-OXO,3-PHENYL-PROPANOIC ACID,ETHYL ESTER 3-oxo-3-phenylpropanoic acid ethyl ester Ethyl benzoylacetate, Ethyl 3-oxo-3-phenylpropionate ETHYL BENZOYLACETATE FOR SYNTHESIS Ethyl benzoylacetate, 95%+ Benzoyl acetic ester Ethyl benzoylacetate technical grade, 90% Ethyl benzoylacetate technical, >=95% (HPLC) beta-oxo-benzenepropanoicaciethylester Ethyl beta-oxobenzenepropanoate ethyl2-benzoylacetate ethylbeta-oxobenzenepropanoate -Oxobenzenepropanoicacidethylester Benzoylacetic acid, ethyl FEMA No. 2423 Ethylbeonzoyl acetate ETHYL BENZOYLACETATE 90+% ETHYL BENZOYLACETATE, REDIST. ETHYL BENZOYLACETATE, TECH., 90% Ethylbenzoylacetateforperfumery 3-(Acetylethylamino)-&beta -[[[(1S)-2-hydroxy-1-methylethyl]amino]methylene]-&beta 2,3,4-Trifluoro-&alpha 2,3,4,5-Tetrafluoro-&alpha -oxo-benzenepropanoic Acid Ethyl Ester-d5 -[(2-formyl-2-methylhydrazinyl)methylene]-&beta Ethyl benzoylacetate, 96%, for synthesis Ethyl Benzoylacetate > Benzenepropanoic acid, β-oxo-, ethyl ester Ethyl benzoylacetate USP/EP/BP