NICKEL BROMATE
- CAS No.
- 13462-88-9
- Chemical Name:
- NICKEL BROMATE
- Synonyms
- NiBr2;Nickel dibromide;Nickel(II)-bromid;Nickel-bromid;NICKEL BROMATE;Nickel(Ⅱ) bromide;Dibromonickel(II);Nickeleus bromide;nickelbromide(nibr2);Nickel(II) dibromide
- CBNumber:
- CB2669337
- Molecular Formula:
- Br2Ni
- Molecular Weight:
- 218.5
- MDL Number:
- MFCD00049991
- MOL File:
- 13462-88-9.mol
- MSDS File:
- SDS
| Melting point | 963 °C (lit.) |
|---|---|
| Density | 5.098 g/mL at 25 °C (lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | H2O: slightly soluble(lit.) |
| form | powder |
| color | Brown |
| Specific Gravity | 5.098 |
| Water Solubility | Soluble in water, alcohol and ether. |
| Sensitive | Hygroscopic |
| Merck | 14,6502 |
| Exposure limits |
ACGIH: TWA 0.1 mg/m3 NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| InChIKey | IPLJNQFXJUCRNH-UHFFFAOYSA-L |
| CAS DataBase Reference | 13462-88-9(CAS DataBase Reference) |
| FDA UNII | 41SGH8A2S6 |
| EPA Substance Registry System | Nickel(II) bromide (13462-88-9) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H317-H334-H341-H350-H360-H372-H410 | |||||||||
| Precautionary statements | P201-P273-P280-P302+P352-P308+P313 | |||||||||
| Hazard Codes | T,N,Xi | |||||||||
| Risk Statements | 45-22-43-50/53-68-48/23-42/43-61-49 | |||||||||
| Safety Statements | 53-36/37-45-60-61 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28275900 | |||||||||
| NFPA 704 |
|
NICKEL BROMATE price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 217891 | Nickel(II) bromide 98% | 13462-88-9 | 10g | $37.9 | 2024-03-01 | Buy |
| Sigma-Aldrich | 217891 | Nickel(II) bromide 98% | 13462-88-9 | 50g | $76.8 | 2024-03-01 | Buy |
| Alfa Aesar | 053115 | Nickel(II) bromide, anhydrous, 99% | 13462-88-9 | 50g | $106 | 2024-03-01 | Buy |
| Alfa Aesar | 053115 | Nickel(II) bromide, anhydrous, 99% | 13462-88-9 | 250g | $446 | 2024-03-01 | Buy |
| Strem Chemicals | 28-1140 | Nickel(II) bromide, anhydrous (99+%-Ni) | 13462-88-9 | 50g | $118 | 2024-03-01 | Buy |
NICKEL BROMATE Chemical Properties,Uses,Production
Description
Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.
References
https://en.wikipedia.org/wiki/Nickel(II)_bromide
Chemical Properties
Brownish powder
Uses
Nickel(II) Bromide, is used as a source of bromide ion. It is also an important raw material used in various chemical synthesis and also as a catalyst in cross-coupling reactions.
General Description
Yellowish-green odorless solid. Sinks in and mixes with water.
Air & Water Reactions
Deliquescent. Soluble in water.
Reactivity Profile
NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]
Health Hazard
Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.
Fire Hazard
Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.
Purification Methods
Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.
NICKEL BROMATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
| SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
| Hebei Henghe Import and Export Trading Co. LTD | +8618032935937 18032916000 | demi@hbtycoon.com | CHINA | 449 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9654 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| Alfa Chemistry | +1-5166625404 | Info@alfa-chemistry.com | United States | 21317 | 58 |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 9407 | 58 |
View Lastest Price from NICKEL BROMATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-12-13 | Nickel(II) bromide
13462-88-9
|
US $10.00 / KG | 100KG | 99% | 100 | Hebei Henghe Import and Export Trading Co. LTD | |
 |
2019-07-11 | NICKEL BROMATE
13462-88-9
|
US $1.00 / KG | 1KG | 99% | 25kg | Career Henan Chemical Co |
-
- Nickel(II) bromide
13462-88-9
- US $10.00 / KG
- 99%
- Hebei Henghe Import and Export Trading Co. LTD
-
- NICKEL BROMATE
13462-88-9
- US $1.00 / KG
- 99%
- Career Henan Chemical Co