ChemicalBook >> CAS DataBase List >>4-Chlorobenzyl alcohol
4-Chlorobenzyl alcohol
- CAS No.
- 873-76-7
- Chemical Name:
- 4-Chlorobenzyl alcohol
- Synonyms
- (4-CHLOROPHENYL)METHANOL;4-chlorobenzyl;ai3-20628;p-Chlorotoluol;RARECHEM AL BD 0077;4-Chlorobenzyl alcoh;p-chloro-benzylalcoho;Chlorophenyl Methanol;P-CHLOROBENZYL ALCOHOL;LABOTEST-BB LT02085068
- CBNumber:
- CB2714497
- Molecular Formula:
- C7H7ClO
- Molecular Weight:
- 142.58
- MDL Number:
- MFCD00004652
- MOL File:
- 873-76-7.mol
- MSDS File:
- SDS
Last updated:2023-09-11 17:45:53
| Melting point | 68-71 °C(lit.) |
|---|---|
| Boiling point | 234 °C(lit.) |
| Density | 1.1104 (rough estimate) |
| refractive index | 1.5390 (estimate) |
| Flash point | 70 °C |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | 2.5g/l |
| form | Crystalline Needles or Powder |
| pka | 14.16±0.10(Predicted) |
| color | Almost white to beige |
| Water Solubility | Soluble in water (2.5 mg/ml at 20°C), and methanol. |
| BRN | 636502 |
| Stability | Stable. Incompatible with acid chlorides, acid anhydrides, acids, oxidizing agents. Combustible. |
| CAS DataBase Reference | 873-76-7(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | GF8BS53B6V |
| NIST Chemistry Reference | 4-Chlorobenzyl alcohol(873-76-7) |
| EPA Substance Registry System | 4-Chlorobenzenemethanol (873-76-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| Safety Statements | 22-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | DN9242000 | |||||||||
| HS Code | 29062900 | |||||||||
| NFPA 704 |
|
4-Chlorobenzyl alcohol price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | C27115 | 4-Chlorobenzyl alcohol 99% | 873-76-7 | 25g | $120 | 2024-03-01 | Buy |
| TCI Chemical | C0565 | 4-Chlorobenzyl Alcohol >99.0%(GC) | 873-76-7 | 25g | $85 | 2024-03-01 | Buy |
| Alfa Aesar | A11504 | 4-Chlorobenzyl alcohol, 99% | 873-76-7 | 25g | $53.65 | 2024-03-01 | Buy |
| Alfa Aesar | A11504 | 4-Chlorobenzyl alcohol, 99% | 873-76-7 | 100g | $146.65 | 2024-03-01 | Buy |
| Sigma-Aldrich | C27115 | 4-Chlorobenzyl alcohol 99% | 873-76-7 | 100g | $175.2 | 2024-03-01 | Buy |
4-Chlorobenzyl alcohol Chemical Properties,Uses,Production
Description
It is usually used as the intermediate in organic synthesis and pharmaceutical industry. Specifically, this chemical can react with o-xylene in the presence of HAuCl4 or AuCl3 at 80 ℃ to generate the corresponding benzylated product.1 Moreover, the acetylation of 4-chlorobenzyl alcohol in presence of catalytic amounts of Ce(OTf)4 has been performed in acetic acid to produce the desired esters in the excellent yields.2 In addition, this chemical may function as the raw material to produce its corresponding carboxylic acids and ketones in good yields through the oxidation reaction by using hydrogen peroxide and cobalt(Ⅱ) complex.3 Besides, the formylation and acetylation of 4-chlorobenzyl alcohol may be carried out in the presence of Silphos [PCl3?n(SiO2)n] in ethyl formate and ethyl acetate.4
Referrence
- Mertins, K.; Lovel, I.; Kischel, J.; Zapf, A.; Beller, M., Gold-catallyzed benzylation of arenes and heteroarenes. Adv. Synth. Catal. 2006, 348, 691-695.
- Iranpoor, N.; Shekarriz, M., Catalytic Esterification of Alcohols, Carboxylic Acids and Transesterification Reactions with Cerium(IV) Triflate. Bull. Chem. Soc. Jpn. 1999, 72, 455-458.
- Das, S.; Punniyamurthy, T., Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide. Tetrahedron Lett. 2003, 44, 6033-6035.
- Iranpoor, N.; Firouzabadi, H.; Jamalian, A., Silphos PCl3-n(SiO2)(n) : a heterogeneous phosphine reagent for formylation and acetylation of alcohols and amines with ethyl formate and acetate. Tetrahedron Lett. 2005, 46, 7963-7966.
Chemical Properties
white crystalline powder
Uses
Reagent for carboxyl group protection.
Uses
4-Chlorobenzyl alcohol acts as a reagent for the protection of carboxyl groups as their 4-chlorobenzyl esters, more stable to acid than the corresponding benzyl esters. It is used as solvent in paint stripper and waterborne coatings. It acts as curing agent. It is also used in pharmaceuticals, cosmetics, preservatives, and flavoring & fragrance agents.
Synthesis Reference(s)
Journal of the American Chemical Society, 82, p. 681, 1960 DOI: 10.1021/ja01488a045
4-Chlorobenzyl alcohol Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
Global( 417)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Speranza Chemical Co., Ltd. | +86-86-075521030354 +8618688942810 | sophieliu@speranzachem.com | China | 723 | 55 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 885 | 50 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
View Lastest Price from 4-Chlorobenzyl alcohol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-25 | 4-Chlorobenzyl alcohol
873-76-7
|
US $100.00 / kg | 25kg | 98% | 300 tons | Speranza Chemical Co., Ltd. | |
 |
2023-09-11 | 4-Chlorobenzyl alcohol
873-76-7
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-04-14 | 4-Chlorobenzyl alcohol
873-76-7
|
US $30.00-10.00 / kg | 10kg | 99% | 100000kg | Hebei Guanlang Biotechnology Co,.LTD |
-
- 4-Chlorobenzyl alcohol
873-76-7
- US $100.00 / kg
- 98%
- Speranza Chemical Co., Ltd.
-
- 4-Chlorobenzyl alcohol
873-76-7
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- 4-Chlorobenzyl alcohol
873-76-7
- US $30.00-10.00 / kg
- 99%
- Hebei Guanlang Biotechnology Co,.LTD
873-76-7(4-Chlorobenzyl alcohol)Related Search:
2-Chlorobenzaldehyde
Benzyl alcohol
1,2,4-Trichlorobenzene
1,3-Dichlorobenzene
Chlorphenamine maleate
1,2-Dichlorobenzene
Ethyl acetate
4,4'-DICHLORO-ALPHA-METHYLBENZHYDROL
3,4-Dichlorobenzoic acid
4-CHLOROPHTHALIC ACID MONOSODIUM SALT
1of4
4-CHLOROBENZYL ALCOHOL
4-chlorobenzylic alcohol
4-Chlorobenzylalcohol,99%
LABOTEST-BB LT02085068
P-CHLOROBENZYL ALCOHOL
RARECHEM AL BD 0077
4-chloro-benzenemethano
4-chlorobenzenemethanol
ai3-20628
Benzenemethanol, 4-chloro-
Benzyl alcohol, p-chloro-
p-chloro-benzylalcoho
4-Chlorobenzyl alcohol 98%
4- CHLOROMETHYL ALCOHOL
PARA-CHLOROBENZYLALCOHOL
p-Chlorotoluol
1-Hydroxymethyl-4-chlorobenzene
4-Chlorobenzyl alcoh
Chlorophenyl Methanol
4-CHLOROBENZYL ALCOHOL FOR SYNTHESIS
4-Chlorobenzyl Alcohol >
4-Chloro benzyl alcohol, 98%+
4-Chlorobenzyl Alcohol/Para Chlorobenzyl Alcohol
(4-CHLOROPHENYL)METHANOL
4-chlorobenzyl
13C6]-4-Chlorobenzyl alcohol
Oxiconazole Impurity 12
Chlorpheniramine Impurity 43
873-76-7
837-76-7
8763-76-7
C7H7ClO
Oxygen Compounds
Organic Building Blocks
C7 to C8
Alcohols
Building Blocks
Building Blocks
C7 to C8
Chemical Synthesis
Organic Building Blocks
Oxygen Compounds
Benzhydrols, Benzyl & Special Alcohols
Alcohol
Alcohols
Chlorine Compounds
C7 to C8
Oxygen Compounds
Alcohols and Derivatives