Sulfometuron-methyl | 74222-97-2

Sulfometuron-methyl Properties

Melting point	203-205°C
Boiling point	197°C (rough estimate)
Density	1.48
refractive index	1.6000 (estimate)
pka	5.7(at 25℃)
CAS DataBase Reference	74222-97-2(CAS DataBase Reference)
FDA UNII	JLY5D60J1A
EPA Substance Registry System	Sulfometuron methyl (74222-97-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS09
Signal word	Warning
Hazard statements	H400
Precautionary statements	P273-P391-P501
Hazard Codes	N
Risk Statements	50
Safety Statements	61
RIDADR	UN3077 9/PG 3
WGK Germany	2
RTECS	DG9096550
Toxicity	LD50 in male, female rats (mg/kg): >5000, >5000 orally (Harding)

Sulfometuron-methyl price More Price(8)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	34224	Sulfometuron methyl PESTANAL	74222-97-2	100mg	$207	2024-03-01	Buy
TRC	S080870	Sulfometuron methyl	74222-97-2	250mg	$265	2021-12-16	Buy
Usbiological	289383	Sulfometuron methyl ester	74222-97-2	50mg	$463	2021-12-16	Buy
TRC	S080870	Sulfometuron methyl	74222-97-2	100mg	$135	2021-12-16	Buy
AK Scientific	F020	Sulfometuronmethylester	74222-97-2	25mg	$98	2021-12-16	Buy

Product number	Packaging	Price	Buy
34224	100mg	$207	Buy
S080870	250mg	$265	Buy
289383	50mg	$463	Buy
S080870	100mg	$135	Buy
F020	25mg	$98	Buy

Sulfometuron-methyl Chemical Properties,Uses,Production

Chemical Properties

The prodrug is white solid. m.p. 203～205℃, vapor pressure 7.39×10-14Pa, relative density 1.48. At 25℃, the solubility is: acetone 2.4g/kg, acetonitrile 1.5g/kg, ethanol 137mg/kg, ether 32mg/kg, xylene 37mg/kg, water 8mg/L (pH=5), 70mg/L (pH =7). The partition coefficient was 0.31 (pH=7). The hydrolysis half-life of the aqueous suspension was 18d at pH=5, and it was stable at pH=7-9. The half-life in soil was about 28d.

Uses

Metsulfuron-methyl is a sulfonylurea herbicide that inhibits the synthesis of branched-chain amino acids, thereby inhibiting cell division at the growing tips of plants, preventing the growth of weeds, and leading to chlorosis and necrosis. It is suitable for the control of annual and perennial grass weeds and broadleaf weeds in forestry.

Definition

ChEBI: Sulfometuron methyl is a benzoate ester that is the methyl ester of 2-{[(4,6-dimethylpyrimidin-2-yl)carbamoyl]sulfamoyl}benzoic acid. It has a role as a herbicide and an EC 2.2.1.6 (acetolactate synthase) inhibitor. It is a member of pyrimidines, a benzoate ester and a N-sulfonylurea. It is functionally related to a sulfometuron.

Preparation

Sulfometuron-methyl is produced by reaction of 2-sulfonylisocyanate methylbenzoate with 2-amino-4,6-dimethylpyrimidine.

Agricultural Uses

Herbicide: Used to control annual and perennial grasses and broadleaf weeds on landscapes, rights-of-ways, fence rows, forests, industrial structure areas and non-crop land. Not listed for use in EU countries. Registered for use in the U.S.

Trade name

DPX-T5648®; KNOCKOUT®; LANDMARK® MP (sulfometuron-methyl + chlorsulfuron); OUST®; OUSTAR®; RIVERDALE®; STAMPRO®

Environmental Fate

Soil. In unsterilized soils, 58% of 14C-labeled sulfometuron-methyl degraded after 24 weeks. Metabolites identified were 2,3-dihydro-3-oxobenzisosulfonazole (saccharin), methyl-2-(aminosulfonyl)benzoate, 2-aminosulfonyl benzoic acid, 2-(((aminocarbonyl)amino)sulfonyl)benzoate and [14C]carbon dioxide. The rate of degradation in aerobic soils was primarily dependent upon pH and soil type (Anderson and Dulka, 1985). The reported half-life in soil was approximately 4 weeks (Hartley and Kidd, 1987).
Chemical/Physical. Sulfometuron-methyl is stable in water at pH values of 7 to 9 but is rapidly hydrolyzed at pH 5.0 forming methyl 2-(aminosulfonyl)benzoate and saccharin. When sulfometuron-methyl in an aqueous solution was exposed to UV light (λ = 300–400 nm), it degraded to the intermediate methyl benzoate which then mineralized to carbon dioxide (Harvey et al., 1985). The hydrolysis half-lives of metsulfuron-methyl at pH 5 and 25 and 45°C were 33 and 2.1 days, respectively. At pH 7 and 45°C, the hydrolysis half-life is 33 days (Beyer et al., 1988).

Metabolic pathway

Sulfometuron methyl is relatively stable at neutral and basic pH and undergoes cleavage of the sulfonylurea linkage to yield methyl-2-(aminosulfonyl)benzoate and 4,6-dimethyl-2-aminopyrimidine as major hydrolysis products, and saccharin as the terminal product. These products are also observed as major degradation products in soils. In plants, monohydroxymethylsulfometuron methyl is the primary metabolite which is also identified as a mammalian and soil metabolite and undergoes further degradation by mammals to give 2-amino-4-hydroxymethyl-6- methylpyrimidine.

Sulfometuron-methyl synthesis

Synthesis of Sulfometuron-methyl from 2-Amino-4,6-dimethylpyrimidine and Methyl 2-(chlorosulfonyl)benzoate

Sulfometuron-methyl Preparation Products And Raw materials

Raw materials

4,6-DIMETHYLPYRIMIDINE Guanidine carbonate Dicyandiamide Acetylacetone Ammonium nitrate

o-Toluic acid Cyanhydric acid Methyl formate Guanidine nitrate METSULFURON METHYL

Benzoic acid, 2-[[(methoxycarbonyl)amino]sulfonyl]-, methyl ester 2-Amino-4,6-dimethylpyrimidine methyl 2-(isocyanatosulphonyl)benzoate Saccharin Methyl 2-(chlorosulfonyl)benzoate

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Preparation Products

Sulfometuron-methyl Suppliers

Global( 177)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
BOC Sciences	+1-631-485-4226	inquiry@bocsci.com	United States	19553	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	19892	58
Longyan Tianhua Biological Technology Co., Ltd	0086 18039857276 18039857276		CHINA	2783	58
ANHUI WITOP BIOTECH CO., LTD	+8615255079626	eric@witopchemical.com	China	23556	58
Baoji Guokang Bio-Technology Co., Ltd.	0917-3909592 13892490616	gksales1@gk-bio.com	China	9339	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58

Supplier	Advantage
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
BOC Sciences	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
TargetMol Chemicals Inc.	58
Longyan Tianhua Biological Technology Co., Ltd	58
ANHUI WITOP BIOTECH CO., LTD	58
Baoji Guokang Bio-Technology Co., Ltd.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58

View Lastest Price from Sulfometuron-methyl manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2021-07-13	DPX-T5648 74222-97-2	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10	DPX-T5648 74222-97-2	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2021-07-02	DPX-T5648 74222-97-2	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

DPX-T5648
74222-97-2
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

DPX-T5648
74222-97-2
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

DPX-T5648
74222-97-2
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

74222-97-2(Sulfometuron-methyl)Related Search:

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Sulfometuron-methyl METHYL THIOSALICYLATE 2-CARBOXY PHENYLSULFAMIDE Oxasulfuron 2-Amino-4,6-dimethylpyrimidine

N-(aminocarbonyl)benzenesulphonamide SULFOMETURON-METHYL 95 % X% WP,DF SULFOMETURON METHYL SOLUTION 100UG/ML IN TOLUENE 1ML Sulfometuron-mehtyl Sulfometuron-Methyl75%Df,95%Tc

SULFOMETURON METHYL SOLUTION 100UG/ML IN ACETONITRILE 1ML

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Oust 75DF OUST WEED KILLER(R) oust methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulphonyl]benzoate DPX-5648(DU Pont) Oust(Du Pont) SULFOMETURON METHYL, 100MG, NEAT Sulfometuron methyl PESTANAL Oust[R] Methyl-2-((((4,6-dimethyl-2-pyrimidinyl)amino)crabonyl-amino)sulfonyl)benzoat Sulfometuron-methyl suspension Benzoic acid, 2-(4,6-dimethyl-2-pyrimidinyl)aminocarbonylaminosulfonyl-, methyl ester oust weed killer sulfometuron-methyl (bsi, e-iso, f-iso, ansi, wssa) SULPHOMETURON-METHYL METHYL2-(((((4,6-DIMETHYL-2-PYRIMIDINYL)AMINO)CARBONYL)AM. 2-(((((4,6-DIMETHYL-2-PYRIMIDINYL)AMINO)CARBONYL)AMINO)SUL. Sulfometuron-methyl soluble powder sulfometuron-me SULFOMETURON METHYL ESTER 2-(4,6-dimethylpyrimidin-2-ylcarbamoylsulfamoyl)benzoic acid methyl ester DPX-T5648 methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfamoyl]benzoate METHYL 2(((((4,6-DIMETHYL-2-PYRIMIDINYL)-AMINO)CARBONYL)AMINO)SULFONYL)BENZOATE aa5648 dpx5648 methyl2-(((((4,6-dimethyl-2-pyrimidinyl)amino)carbonyl)amino)sulfonyl)benzoa o-((3-(4,6-dimethyl-2-pyrimidinyl)ureido)sulfonyl)-benzoicacimethylester methyl-2(4,6-dimethylpyrimidinyl-2-carbamoyl sulfamoyl) benzoate Methyl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate 2-[(4,6-Dimethylpyrimidine-2-yl)carbamoylsulfamoyl]benzoic acid methyl ester 2-[3-(4,6-Dimethylpyrimidin-2-yl)ureidosulfonyl]benzoic acid methyl ester 2-[[[[(4,6-DIMETHYL-2-PYRIMIDINYL)AMINO]CARBONYL]AMINO]SULPHONYL]BENZOATEMETHYL Sulfometuron-m 2-[[[(4,6-dimethyl-2-pyrimidinyl)amino]-oxomethyl]sulfamoyl]benzoic acid methyl ester sulfometuron-methyl [ANSI] SULFOMETURON METHYL 74222-97-2 C15H16N4O5S C15H16H4O5S SN - SZPesticides&Metabolites Alpha sort Environmental Standards Herbicides MetabolitesPesticides&Metabolites Pesticides&Metabolites Q-ZAlphabetic S Urea structure HERBICIDE