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tert-Butyl methyl ether

CAS No.1634-04-4
Chemical Name:tert-Butyl methyl ether
Synonyms:MTB;MTBE;HP-MTBE;Driveron;MBT-ETHER;tert-C4H9OCH3;Methyl-tert-bu;BOC-ARG(MTR)-OH;ARCOPURE(R) MTBE;BOC-L-ARG(MTR)-OH
CBNumber:CB2853178
Molecular Formula:C5H12O
Formula Weight:88.15
MOL File:1634-04-4.mol
tert-Butyl methyl ether Property
Melting point : -110 °C
Boiling point : 55-56 °C(lit.)
density : 0.7404
vapor density : 3.1 (vs air)
vapor pressure : 4.05 psi ( 20 °C)
refractive index : n20/D 1.369(lit.)
Fp : -27 °F
storage temp. : −20°C
Water Solubility : 51 g/L (20 ºC)
FreezingPoint : -108.6℃
Merck : 14,6032
BRN : 1730942
Stability:: Stable, but may form explosive peroxides in contact with air. Extremely flammable - note low flash point. Incompatible with strong oxidizing agents.
CAS DataBase Reference: 1634-04-4(CAS DataBase Reference)
NIST Chemistry Reference: Propane, 2-methoxy-2-methyl-(1634-04-4)
EPA Substance Registry System: Propane, 2-methoxy-2-methyl-(1634-04-4)
Safety
Hazard Codes : Xn,F,Xi,T
Risk Statements : 36/37/38-40-38-11-39/23/24/25-23/24/25
Safety Statements : 9-16-24-45-36/37-7
RIDADR : UN 2398 3/PG 2
WGK Germany : 3
RTECS : KN5250000
F : 3-10
HazardClass : 3
PackingGroup : II
Hazardous Substances Data: 1634-04-4(Hazardous Substances Data)

tert-Butyl methyl ether Chemical Properties,Usage,Production

Chemical Properties
Clear colorless liquid
Usage
Suitable for HPLC, spectrophotometry, environmental testing
Usage
Suitable for pesticide residue analysis
General Description
A colorless liquid with a distinctive anesthetic-like odor. Vapors are heavier than air and narcotic. Boiling point 131°F. Flash point 18°F. Less dense than water and miscible in water. Used as a octane booster in gasoline.
Air & Water Reactions
Highly flammable. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616. 1960].
Reactivity Profile
Ethers, such as tert-Butyl methyl ether, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Health Hazard
INHALATION: May cause dizziness or suffocation. Contact may irritate or burn eyes or skin. May be harmful if swallowed.
tert-Butyl methyl ether Preparation Products And Raw materials
Raw materials
ISOBUTYLENE DOYLE DIRHODIUM CATALYST-RH2(4S-MEOX)4 Methanol
Preparation Products
Methyl 2-aminothiophene-3-carboxylate (1R,2R)-(-)-1,2-Diaminocyclohexane 1-(Boc-amino)cyclopropanecarboxylic acid ((1R,4S)-2-Azabicyclo[2.2.1]hept-5-en-3-one ETHYL 2-(BROMOMETHYL)ACRYLATE 5-METHOXY-1H-PYRROLO[3,2-B]PYRIDINE-2-CARBOXYLIC ACID 2,2,2-Trichloroethyl chloroformate BIS(4-NITROBENZYL) PHOSPHOROCHLORIDATE Tris(dibenzylideneacetone)dipalladium-chloroform adduct 3-N-Boc-amino-azetidine 4-Vinylbenzyl chloride N,N-Diethylacetoacetamide Sodium triacetoxyborohydride Brinzolamide 5-AMINOINDOLE HYDROCHLORIDE 4-Aminotetrahydropyran hydrochloride N-METHYL-P-ANISIDINE 3-AMINO-ISONICOTINIC ACID ETHYL ESTER 2-CHLOROMALONALDEHYDE Azetidine 4-PYRIDIN-2-YLISOXAZOL-5-AMINE 2-(2-NITROPHENYL)ACRYLALDEHYDE (3-AMINO-PYRIDIN-4-YL)-METHANOL Tetraheptylammonium bromide Tetrakis(triphenylphosphine)palladium 5-METHOXY-1H-PYRROLO[2,3-C]PYRIDINE-2-CARBALDEHYDE 1-Aminocyclopropanecarboxylic acid 5-METHOXY-1H-PYRROLO[2,3-C]PYRIDINE-2-CARBOXYLIC ACID N-OCTADECYLTRICHLOROSILANE 6-Nitroindole N5-[imino(phosphonoamino)methyl]L-ornithine TERT-BUTYL METHYL MALONATE HEXAFLUOROACETYLACETONE 6-Aminoindole Azetidine hydrochloride 3-METHOXYBENZYL BROMIDE 4,6-Dimethylpyrimidine-5-carboxylic acid 2-Methoxyethyl acetate 3-AMINO-PYRIDINE-4-CARBALDEHYDE PHOSPHO-L-ARGININE SODIUM
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1634-04-4(tert-Butyl methyl ether)Related Search:
Isopropyl ether Isopropanol Bensulfuron methyl Thiophanate-methyl Methoxy Kresoxim-methyl TERT-BUTYLLITHIUM TERT-AMYL METHYL ETHER Methyl TERT-BUTYL ETHYL ETHER Propane METHYL N-PROPYL ETHER Methyl bromide tert-Butyl peroxyacetate Pinacolone 1,3-Bis[tris(hydroxymethyl)methylamino]propane Trimethylol propane METHOXYTRIMETHYLSILANE
1634-04-4 1-METHOXY-2-METHYLPROPANE BioChemical Analytical Chromatography Product Catalog Analytical Standards Analytical Reagents Anhydrous Grade Solvents 2-METHYL-2-METHOXY PROPANE BOC-ARG(MTR)-OH BOC-ARG(MTR)-OH MTBE BOC-ARGININE(MTR)-OH BOC-N-OMEGA-(4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL)-L-ARGININE BOC-L-ARG(MTR)-OH ARCOPURE(R) MTBE HP-MTBE MBT-ETHER METHYL-T-BUTYL ETHER METHYL TERT-BUTYL ETHER N-ALPHA-T-BOC-NG-(4-METHOXY-2,3,6 TRIMETHYLBENZENESULFONYL)-L-ARGININE N-ALPHA-TERT-BUTYLOXYCARBONYL-N'-(4-METHOXY-2,3,6-TRIMETHYLPHENYL-SULFONYL)-L-ARGININE N-ALPHA-T-BUTOXYCARBONYL-N-OMEGA-4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL-L-ARGININE N-ALPHA-BOC-N(G)-4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL-L-ARGININE N-ALPHA-BOC-N-OMEGA-(4-METHOXY-2,3,6-TRIMETHYL-BENZENE-SULFONYL)-L-ARGININE MTB MTBE TERT-BUTYL METHYL ETHER T-BUTYL METHYL ETHER T-BUTYL METHYL ETHER 300 TBOC-L-ARGININE (MTR) Chromatography CHROMASOLV® Plus CHROMASOLV® Solvents (HPLC, LC-MS) Chromatography/CE Reagents Environmental Standards Solvents Solvents - GC/SH Stable Isotopes Volatiles/ Semivolatiles LC-MS Plus and Gradient Purge & Trap Reagent Grade Solvents Pesticide Residue Analysis (PRA) Solvents (2-Methyl-2-propyl)methylether 1,1-dimethyl-1-methoxyethane 1,1-dimethylethylmethylether 2-methoxy-2-methyl 2-methoxy-2-methyl-propan 2-Methoxy-2-methylpropane 2-methoxy-2-methyl-Propane 3,3-dimethyl-2-oxabutane Driveron Ether, tert-butyl methyl ether,tert-butylmethyl Methyl 1,1-dimethylethyl ether methyl tert-butyl ether (MTBE) methyl1,1-dimethylethylether methyl2,2-dimethylethylether methylbutylether(non-specificname)
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