ChemicalBook >> CAS DataBase List >>(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- CAS No.
- 64536-78-3
- Chemical Name:
- (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
- Synonyms
- CRABTREE'S CATALYST;CRABTREE CATALYST;[Ir(cod)(PCy3)(py)]PF6;tricyclohexylphosphinecyclooctadienepyridineiridium PF6;Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex;[Ir(PCy3)(COD)(Py)]+PF6-;CRABTREE PRECURSOR COMPLEX;phosphine)iridium(I) hexafL;ooctadiene(pyridine)(tricycL;(1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6
- CBNumber:
- CB3108657
- Molecular Formula:
- C31H47F6IrNP2
- Molecular Weight:
- 801.88
- MDL Number:
- MFCD00075097
- MOL File:
- 64536-78-3.mol
- MSDS File:
- SDS
Last updated:2023-05-11 17:26:00
| Melting point | 175 °C (dec.)(lit.) |
|---|---|
| Density | 1.67 g/cm3 |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly) |
| form | Crystalline Powder |
| color | Orange |
| Water Solubility | Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water. |
| Sensitive | Moisture Sensitive |
| Merck | 13,2594 |
| FDA UNII | 816RS2NBPN |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29310099 | |||||||||
| NFPA 704 |
|
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE price More Price(35)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 337498 | (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate 85% | 64536-78-3 | 50mg | $27.48 | 2024-03-01 | Buy |
| Sigma-Aldrich | 29590 | (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate ≥99.0% (C) | 64536-78-3 | 250mg | $193 | 2024-03-01 | Buy |
| TCI Chemical | C2824 | (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate | 64536-78-3 | 100mg | $90 | 2024-03-01 | Buy |
| Alfa Aesar | 042057 | 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99% | 64536-78-3 | 50mg | $50.6 | 2023-06-20 | Buy |
| Alfa Aesar | 042057 | 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99% | 64536-78-3 | 250mg | $189 | 2023-06-20 | Buy |
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Uses,Production
Reaction
- Iridium catalyst used for the highly enantioselective hydrogenation of α,β-unsaturated esters.
- Iridium catalyst used for the stereoselective catalytic hydrogenation and conjugate reduction of 4methylitaconate derivatives bearing a chiral auxiliary.
- Iridium catalyst used in the synthesis of thiophene-based TAK-779 analogues via C-H arylation.
- Iridium catalyst used in the practical synthetic approach to chiral (α-chloroalkyl)boronic esters via an iridiumcatalyzed, chemoselective hydrogenation of chloro-substituted alkenyl boronates.
- Iridium catalyst used in the regioselective C-H activation and hydrogen-isotope exchange of non-aromatic unsaturated functionality.
Chemical Properties
orange crystals
Uses
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.
Synthesis of (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE from Bis(pyridine)(1,5-cyclooctadiene)iridium(I) hexafluorophosphate, 99% and Tricyclohexyl phosphine
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 151)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | mcbio_sales@163.com | China | 2255 | 58 |
| Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 | |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| Henan Alfa Chemical Co., Ltd | +8618339805032 | alfa4@alfachem.cn | China | 12755 | 58 |
| Labnetwork lnc. | +86-27-50766799 +8618062016861 | contact@labnetwork.com | China | 19994 | 58 |
| Alfa Chemistry | +1-5166625404 | Info@alfa-chemistry.com | United States | 21317 | 58 |
View Lastest Price from (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-01-13 | (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
64536-78-3
|
US $1.00 / g | 1g | 99% | 200kg | Career Henan Chemical Co |
-
- (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
64536-78-3
- US $1.00 / g
- 99%
- Career Henan Chemical Co
64536-78-3((1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE)Related Search:
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(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTA- DIENE)(PYRIDINE)IRIDIUM(I) PF6
(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,99%
(1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate
(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate,99%CRABTREE'SCATALYST
1,5-Cyclooctadiene-(pyridyl)-(tricyclohexylphosphine)-iridium hexafluoropho
(cycloocta-1,5-diene)pyridyl(tricyclohexyl-phosphine)iridium(I)hexafluorophosphate Crabtree's catalyst
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluoro phosphate Hexafluorophosphate (tricyclohexyl phosphine) (1,5-cyclooctadiene) (pyridine) iridium (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,98% (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I) hexafluorophosphate,98% CRABTREE'S CATALYST (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I)hexafluorophosphate,CRABTREE'S CATALYST 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridiuM(I) (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate >=99.0% (C) (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate 85% IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX CRABTREE PRECURSOR COMPLEX (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE (TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM (I) HEXAFLUOROPHOSPHATE (1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6 (Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate Crabtrees Catalyst~(Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) PF6, 85% [Ir(PCy3)(COD)(Py)]+PF6- ooctadiene(pyridine)(tricycL phosphine)iridium(I) hexafL 1,5-Cyclooctadiene(Pyridine)(Tricyclohexylphosphine)Iridium(I) Hexafluorophospha (1, 5-Cyclooctadiene) (pyridine) (tricylocohexylphosphine) iridium(I) hexafluorophosphate (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiu... 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, tricyclohexylphosphinecyclooctadienepyridineiridium PF6 Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex [Ir(cod)(PCy3)(py)]PF6 CRABTREE CATALYST CRABTREE'S CATALYST Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) (1:1) (1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-Iridium(1+) hexafluorophosphate(1-) (1:1) 64536-78-3 C31H50IrNPF6P C6H113PC8H12C5H5NIrPF6 C31H50IrNPPF6 C31H50F6IrNP2 Catalysis and Inorganic Chemistry Iridium Ir
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluoro phosphate Hexafluorophosphate (tricyclohexyl phosphine) (1,5-cyclooctadiene) (pyridine) iridium (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,98% (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I) hexafluorophosphate,98% CRABTREE'S CATALYST (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I)hexafluorophosphate,CRABTREE'S CATALYST 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridiuM(I) (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate >=99.0% (C) (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate 85% IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX CRABTREE PRECURSOR COMPLEX (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE (TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM (I) HEXAFLUOROPHOSPHATE (1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6 (Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate Crabtrees Catalyst~(Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) PF6, 85% [Ir(PCy3)(COD)(Py)]+PF6- ooctadiene(pyridine)(tricycL phosphine)iridium(I) hexafL 1,5-Cyclooctadiene(Pyridine)(Tricyclohexylphosphine)Iridium(I) Hexafluorophospha (1, 5-Cyclooctadiene) (pyridine) (tricylocohexylphosphine) iridium(I) hexafluorophosphate (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiu... 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, tricyclohexylphosphinecyclooctadienepyridineiridium PF6 Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex [Ir(cod)(PCy3)(py)]PF6 CRABTREE CATALYST CRABTREE'S CATALYST Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) (1:1) (1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-Iridium(1+) hexafluorophosphate(1-) (1:1) 64536-78-3 C31H50IrNPF6P C6H113PC8H12C5H5NIrPF6 C31H50IrNPPF6 C31H50F6IrNP2 Catalysis and Inorganic Chemistry Iridium Ir