Ammonium formate
CAS No.
540-69-2
Chemical Name:
Ammonium formate
Synonyms
AMMONIUM FORMAT;mravencanamonny;AMMONIUM FORMATE;Formiate ammonia;formated’ammonium;AMMONIUM FORMIATE;AmmoniumFormateAr;AmmoniumFormateGr;ammmonium formate;Ammoniumformate,99%
CBNumber:
CB3140017
Molecular Formula:
CH5NO2
Formula Weight:
63.06
MOL File:
540-69-2.mol
Ammonium formate Properties
Melting point:
119-121 °C(lit.)
Density
1.26 g/mL at 25 °C(lit.)
Flash point:
104℃
storage temp.
Store at RT.
solubility
H2 O: 10 M at 20 °C, clear, colorless
form
Solid
color
White
PH
6.0-8.0 (25℃, 10M in H2O)
Water Solubility
soluble
Sensitive
Hygroscopic
Merck
14,523
BRN
3625095
Stability:
Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference
540-69-2(CAS DataBase Reference)
EPA Substance Registry System
Formic acid, ammonium salt(540-69-2)
SAFETY
Risk and Safety Statements
Hazard and Precautionary Statements (GHS)
Symbol(GHS):
Signal word:
Hazard statements:
Code
Hazard statements
Hazard class
Category
Signal word
Pictogram
P-Codes
H303
May be harmfulif swallowed
Acute toxicity,oral
Category 5
P312
H315
Causes skin irritation
Skin corrosion/irritation
Category 2
Warning
P264, P280, P302+P352, P321,P332+P313, P362
H319
Causes serious eye irritation
Serious eye damage/eye irritation
Category 2A
Warning
P264, P280, P305+P351+P338,P337+P313P
H335
May cause respiratory irritation
Specific target organ toxicity, single exposure;Respiratory tract irritation
Category 3
Warning
Precautionary statements:
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340
IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405
Store locked up.
Manufacturer
Product number
Product description
CAS number
Packaging
Price
Updated
Buy
Sigma-Aldrich
09735
Ammonium formate
BioUltra, ≥99.0% (calc. based on dry substance, NT)
540-69-2
50g
$75.2
2017-11-08
Buy
Sigma-Aldrich
09735
Ammonium formate
BioUltra, ≥99.0% (calc. based on dry substance, NT)
540-69-2
250g
$259.5
2017-11-08
Buy
Alfa Aesar
14517
Ammonium formate, 98+%
540-69-2
50g
$22
2017-11-08
Buy
Alfa Aesar
14517
Ammonium formate, 98+%
540-69-2
250g
$44.9
2017-11-08
Buy
Sigma-Aldrich
516961
Ammonium formate
≥99.995% trace metals basis
540-69-2
100g
$47.2
2017-11-08
Buy
Ammonium formate Chemical Properties,Uses,Production
Description Ammonium formate is the ammonium salt of formic acid, and is a colorless, hydroscopic, crystalline solid. It can be synthesized through treating ammonium carbonate with 85% formic acid. It is widely used in many organic reactions such as Leuckart reaction which is the reductive amination of aldehydes and ketones. It can also be used as a buffer in HPLC and LC/MS test. Moreover, it is also used in palladium on carbon (Pd/C) reduction of functional group. It can also be used for the preparation of formic acid in situ as well as being used to store formic acid.
References http://www.orgsyn.org/demo.aspx?prep=CV2P0503
https://www.alfa.com/zh-cn/catalog/014517/
https://en.wikipedia.org/wiki/Ammonium_formate
Chemical Properties colourless crystals
Definition ChEBI: The ammonium salt of formic acid.
Uses In chemical analysis, especially to ppt base metals from salts of the "noble" metals.
General Description White solid with a weak odor of ammonia. Sinks and mixes slowly with water.
Air & Water Reactions Water soluble.
Reactivity Profile Salts, basic, such as Ammonium formate, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.
Health Hazard Inhalation causes irritation of nose and throat. Ingestion irritates mouth and stomach. Contact with eyes or skin causes irritation.
Fire Hazard Special Hazards of Combustion Products: Toxic and irritating ammonia and formic acid gases may form in fire.
Ammonium formate Preparation Products And Raw materials
Raw materials
Preparation Products
3-Azetidinecarboxylic acid
4-(Trifluoromethyl)nicotinic acid
(R)-(-)-2-AMINOHEPTANE
5-FLUORO-2-PICOLINIC ACID
(1,3,5-TRIMETHYL-1H-PYRAZOL-4-YL)METHYLAMINE
1-N-Boc-3-hydroxyazetidine
C-(1-METHYL-PIPERIDIN-2-YL)-METHYLAMINE
4-METHYL-1,3-OXAZOLE-5-CARBOXYLIC ACID
1,2,4-Triazole
Citrazinic acid
4-METHYLOXAZOLE-5-CARBONYL CHLORIDE
3,4,5-Trimethoxybenzylamine
5-(AMINOMETHYL)-2,3-DIHYDROBENZO[B]FURAN
4-CHLORO-7-METHYLTHIENO[3,2-D]PYRIMIDINE
Teicoplanin A2
3-Chlorobenzylamine
DL-alpha-Methylbenzylamine
4-Aminotetrahydropyran
5-CHLORO-1H-INDAZOLE-3-CARBOXYLIC ACID
4-CHLORO-2-METHYLBENZYLAMINE
7-METHYL-3,4-DIHYDROTHIENO[3,2-D]PYRIMIDIN-4-ONE
(4S)-HYDROXY-3-METHYL-2-(2-PROPENYL)-2-CYCLOPENTENE-1-ONE
3-(4-Morpholinyl)aniline
5-AMINO-2-INDOLE CARBOXYLIC ACID
5-Azaindole
(1H-INDAZOL-3-YL)-ACETIC ACID
4-Hydroxy-3-methoxybenzylamine hydrochloride
3-AMINO-5-FLUOROPYRIDINE
DL-ALPHA-METHYLBENZYLAMINE
Triadimefon
ETHYL 5-AMINO-1H-INDOLE-2-CARBOXYLATE
3,5-Bis(trifluoromethyl)benzylamine
3-Amino-4-methoxybenzoic acid
2,5-Dimethoxybenzylamine
Ammonium formate Suppliers
Global( 224)Suppliers
Belgium 1
Canada 1
China 162
Europe 3
Germany 1
India 4
Japan 5
Switzerland 1
United Kingdom 7
United States 39
Global 224
540-69-2(Ammonium formate)Related Search:
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formated’ammonium
mravencanamonny
AMMONIUM FORMAT
Ammonium formate, Eluent additive for LC-MS
AMMONIUM FORMATE, 99.995+% METALS BASIS
AMMONIUM FORMATE REAGENT GRADE 97%
AMMONIUM FORMATE SOLUTION 10M
AMMONIUM FORMATE PURE
AmmoniumFormateAr
AmmoniumFormateReagent
AmmoniumFormateGr
Ammoniumformate,99%
Ammoniumformate,97%
AMMONIUM FORMATE SOLUTION
HCOONH4
AMMONIUMFORMATE,CRYSTAL,REAGENT
Industrial/Fine Chemicals
NH4CHO2
Ammonium formate, 97%, water <3%
Formiate ammonia
CHOONH4
AMMONIUM FORMATE extrapure AR
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ammmonium formate
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