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Ammonium formate

Description References

CAS No.540-69-2
Chemical Name:Ammonium formate
Synonyms:AMMONIUM FORMAT;mravencanamonny;AMMONIUM FORMATE;Formiate ammonia;formated’ammonium;AMMONIUM FORMIATE;AmmoniumFormateAr;AmmoniumFormateGr;ammmonium formate;Ammoniumformate,99%
CBNumber:CB3140017
Molecular Formula:CH5NO2
Formula Weight:63.06
MOL File:540-69-2.mol
Ammonium formate Property
Melting point : 119-121 °C(lit.)
density : 1.26 g/mL at 25 °C(lit.)
storage temp. : Store at RT.
solubility : H2O: 10 M at 20 °C, clear, colorless
Water Solubility : soluble
Sensitive : Hygroscopic
Merck : 14,523
BRN : 3625095
Stability:: Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference: 540-69-2(CAS DataBase Reference)
EPA Substance Registry System: Formic acid, ammonium salt(540-69-2)
Safety
Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26-36-37/39
WGK Germany : 2
RTECS : BQ6650000
F : 3-10
TSCA : Yes
Hazardous Substances Data: 540-69-2(Hazardous Substances Data)

Ammonium formate Chemical Properties,Usage,Production

Description
Ammonium formate is the ammonium salt of formic acid, and is a colorless, hydroscopic, crystalline solid. It can be synthesized through treating ammonium carbonate with 85% formic acid. It is widely used in many organic reactions such as Leuckart reaction which is the reductive amination of aldehydes and ketones. It can also be used as a buffer in HPLC and LC/MS test. Moreover, it is also used in palladium on carbon (Pd/C) reduction of functional group. It can also be used for the preparation of formic acid in situ as well as being used to store formic acid.
References
http://www.orgsyn.org/demo.aspx?prep=CV2P0503
https://www.alfa.com/zh-cn/catalog/014517/
https://en.wikipedia.org/wiki/Ammonium_formate
Chemical Properties
colourless crystals
General Description
White solid with a weak odor of ammonia. Sinks and mixes slowly with water.
Air & Water Reactions
Water soluble.
Reactivity Profile
Salts, basic, such as Ammonium formate, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.
Health Hazard
Inhalation causes irritation of nose and throat. Ingestion irritates mouth and stomach. Contact with eyes or skin causes irritation.
Fire Hazard
Special Hazards of Combustion Products: Toxic and irritating ammonia and formic acid gases may form in fire.
Ammonium formate Preparation Products And Raw materials
Raw materials
4-Chlorobenzaldehyde Formic acid Ammonia
Preparation Products
3-Azetidinecarboxylic acid 4-(Trifluoromethyl)nicotinic acid (R)-(-)-2-AMINOHEPTANE 5-FLUORO-2-PICOLINIC ACID (1,3,5-TRIMETHYL-1H-PYRAZOL-4-YL)METHYLAMINE 1-N-Boc-3-hydroxyazetidine C-(1-METHYL-PIPERIDIN-2-YL)-METHYLAMINE 4-METHYL-1,3-OXAZOLE-5-CARBOXYLIC ACID 1,2,4-Triazole Citrazinic acid 4-METHYLOXAZOLE-5-CARBONYL CHLORIDE 3,4,5-Trimethoxybenzylamine 5-(AMINOMETHYL)-2,3-DIHYDROBENZO[B]FURAN 4-CHLORO-7-METHYLTHIENO[3,2-D]PYRIMIDINE Teicoplanin A2 3-Chlorobenzylamine DL-alpha-Methylbenzylamine 4-Aminotetrahydropyran 5-CHLORO-1H-INDAZOLE-3-CARBOXYLIC ACID 4-CHLORO-2-METHYLBENZYLAMINE 7-METHYL-3,4-DIHYDROTHIENO[3,2-D]PYRIMIDIN-4-ONE (4S)-HYDROXY-3-METHYL-2-(2-PROPENYL)-2-CYCLOPENTENE-1-ONE 3-(4-Morpholinyl)aniline 5-AMINO-2-INDOLE CARBOXYLIC ACID 5-Azaindole (1H-INDAZOL-3-YL)-ACETIC ACID 4-Hydroxy-3-methoxybenzylamine hydrochloride 3-AMINO-5-FLUOROPYRIDINE DL-ALPHA-METHYLBENZYLAMINE Triadimefon ETHYL 5-AMINO-1H-INDOLE-2-CARBOXYLATE 3,5-Bis(trifluoromethyl)benzylamine 3-Amino-4-methoxybenzoic acid 2,5-Dimethoxybenzylamine
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