4-Acryloylmorpholine
- CAS No.
- 5117-12-4
- Chemical Name:
- 4-Acryloylmorpholine
- Synonyms
- ACRYLOYL MORPHOLINE;1-Morpholinoprop-2-en-1-one;N-ACRYLOYLMORPHOLINE;N-Acrylylmorpholine;4-AcryL;Acrylmorpholide;Acryloylmorpholin;4-Acrylmorpholine;ACRYOYL MORPHOLINE;N-Acrolylmorpholine
- CBNumber:
- CB3229639
- Molecular Formula:
- C7H11NO2
- Molecular Weight:
- 141.17
- MDL Number:
- MFCD00047413
- MOL File:
- 5117-12-4.mol
- MSDS File:
- SDS
| Melting point | −35 °C(lit.) |
|---|---|
| Boiling point | 158°C 50mm |
| Density | 1.122 g/mL at 25 °C(lit.) |
| vapor pressure | 1.03-1.64Pa at 25-29.9℃ |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Soluble in water |
| form | Liquid |
| pka | -1.08±0.20(Predicted) |
| color | Colorless to yellow |
| Water Solubility | 1000g/L at 20℃ |
| Sensitive | Light Sensitive |
| BRN | 119302 |
| InChIKey | XLPJNCYCZORXHG-UHFFFAOYSA-N |
| LogP | -0.46 at 20.5-21℃ |
| CAS DataBase Reference | 5117-12-4(CAS DataBase Reference) |
| EWG's Food Scores | 1-3 |
| FDA UNII | K0Y58P61JA |
| NIST Chemistry Reference | N-acryloylmorpholine(5117-12-4) |
| EPA Substance Registry System | Morpholine, 4-(1-oxo-2-propenyl)- (5117-12-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H317-H318-H373 | |||||||||
| Precautionary statements | P280-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-41-43-48/22 | |||||||||
| Safety Statements | 23-26-36/37/39 | |||||||||
| WGK Germany | 2 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29349990 | |||||||||
| NFPA 704 |
|
4-Acryloylmorpholine price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 448273 | 4-Acryloylmorpholine 97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor | 5117-12-4 | 50ml | $82.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 448273 | 4-Acryloylmorpholine 97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor | 5117-12-4 | 250ml | $288 | 2024-03-01 | Buy |
| TCI Chemical | A0841 | 4-Acryloylmorpholine (stabilized with MEHQ) >98.0%(GC) | 5117-12-4 | 25mL | $28 | 2024-03-01 | Buy |
| TCI Chemical | A0841 | 4-Acryloylmorpholine (stabilized with MEHQ) >98.0%(GC) | 5117-12-4 | 100mL | $77 | 2024-03-01 | Buy |
| Alfa Aesar | L12947 | 4-Acryloylmorpholine, 98+%, stab. with 4-methoxyphenol | 5117-12-4 | 5g | $36.65 | 2024-03-01 | Buy |
4-Acryloylmorpholine Chemical Properties,Uses,Production
Chemical Properties
4-Acryloylmorpholine has a melting point of ?35 °C and is clear liquid at room temperature. At 25 °C, it has a density of 1.122 g/mL. It needs to be stored at 2-8°C.
Uses
4-Acryloylmorpholine is used in adhesives, UV curable resins, industrial coatings, UV printing ink, oil recovery polymer, medicinal and commodity chemicals.
Flammability and Explosibility
Non flammable
Synthesis
A
solution of 0.04 mol of the corresponding amine in 20 ml of anhydrous
methylene chloride was slowly added at 0-5??C to 0.02 mol of acryloyl
chloride in 20 ml of anhydrous methylene chloride. The mixture was
stirred for 3 h at room temperature in an inert atmosphere, and the
precipitate was filtered off and washed with methylene chloride (2 ?á 10
ml). The organic layer was washed in succession with 5 ml of water and 5
ml of a saturated solution of NaHCO3 and dried over Na2SO4, the solvent
was removed under reduced pressure, and the residue was purified by
column chromatography on silica gel using hexane-ethyl acetate (5 : 1 to
1 : 1) as eluent. 4-Acryloylmorpholine, Yield 1.78 g (63%).
IR spectrum, |í, cm-1: 2857, 1647, 1612, 1439, 1263, 1238, 1115, 1038,
953. 1H NMR spectrum, |?, ppm: 3.51-3.73 m (8H, NCH2CH2O),
5.72 d.d (1H, 3-Hcis, 3J = 10.6, 2J = 1.9 Hz), 6.29 d.d (1H, 3-Htrans,
3J = 16.7, 2J = 1.9 Hz), 6.57 d.d (1H, 2-H, J = 16.7, 10.6 Hz). 13C NMR
spectrum, |?C, ppm: 41.74 and 45.66 (CH2N), 66.22 (CH2O), 126.64 (C2),
127.69 (C3), 164.92 (C1). Mass spectrum, m/z (Irel, %): 141 (36) [M]+,
140 (12), 126 (58), 112 (22), 111 (15), 110 (15), 109 (12), 98 (10), 96
(26), 86 (72), 83 (13), 70 (14), 68 (14), 57 (17), 56 (86), 55 (100),
42 (23).
Fig. The synthetic method 2 of 4-Acryloylmorpholine
4-Acryloylmorpholine Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 | marketing@royal-chem.com | China | 142 | 55 |
| Gansu Jinyuantai New Material Co., Ltd. | +86-025-86618065 +86-13914714331 | sales@jinyuantaichem.com | China | 73 | 58 |
| Yancheng Green Chemicals Co.,Ltd | +undefined-86-25-86655873 | info@royal-chem.com | China | 114 | 58 |
| Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 | daisy@crovellbio.com | China | 5964 | 58 |
| Shaanxi Haibo Biotechnology Co., Ltd | +undefined18602966907 | qinhe02@xaltbio.com | China | 1000 | 58 |
| Ouhuang Engineering Materials (Hubei) Co., Ltd | +8617702722807 | admin@hbouhuang.com | China | 1696 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 | sales@tjzxchem.com | China | 559 | 58 |
Related articles
- Synthesis, Hazard and Application of N-Acryloylmorpholine
- N-Acryloylmorpholine is used in UV-curable inks, coatings and adhesives.
- Oct 10，2022
View Lastest Price from 4-Acryloylmorpholine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-25 | 4-Acryloylmorpholine
5117-12-4
|
US $1.00 / g | 1g | 99 | 20tons | Shanghai Longyu Biotechnology Co., Ltd. | |
 |
2024-04-23 | 4-Acryloylmorpholine
5117-12-4
|
US $10.00 / kg | 1kg | 99.6% | 100000 | Ouhuang Engineering Materials (Hubei) Co., Ltd | |
 |
2024-04-12 | 4-Acryloylmorpholine
5117-12-4
|
US $0.00 / kg | 1kg | 99% | 2000ton | Shaanxi Haibo Biotechnology Co., Ltd |
-
- 4-Acryloylmorpholine
5117-12-4
- US $1.00 / g
- 99
- Shanghai Longyu Biotechnology Co., Ltd.
-
- 4-Acryloylmorpholine
5117-12-4
- US $10.00 / kg
- 99.6%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
-
- 4-Acryloylmorpholine
5117-12-4
- US $0.00 / kg
- 99%
- Shaanxi Haibo Biotechnology Co., Ltd
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