ChemicalBook >> CAS DataBase List >>PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
- CAS No.
- 185812-86-6
- Chemical Name:
- PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
- Synonyms
- Pd-113;broMopalladiuM;[Pd(μ-Br)t-Bu3P]2;PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE;Dibromobis(tri-tert-butylphosphine)dipalladium;Bromo(tri-tert-butylphosphine)palladium(I)dimer;DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium(I);Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I);Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
- CBNumber:
- CB3279937
- Molecular Formula:
- C24H56Br2P2Pd2
- Molecular Weight:
- 779.31
- MDL Number:
- MFCD04114019
- MOL File:
- 185812-86-6.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
|---|---|
| form | crystal |
| color | dark-green |
| Water Solubility | Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water. |
| Sensitive | Air Sensitive |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | F,C | |||||||||
| Risk Statements | 36/37/38-34-17-14 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3393 4.2/PG 1 | |||||||||
| NFPA 704 |
|
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE price More Price(33)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Alfa Aesar | 044446 | Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) | 185812-86-6 | 0.1g | $73.1 | 2024-03-01 | Buy |
| Alfa Aesar | 044446 | Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) | 185812-86-6 | 0.5g | $292 | 2024-03-01 | Buy |
| Strem Chemicals | 46-0355 | Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) | 185812-86-6 | 100mg | $64 | 2024-03-01 | Buy |
| Strem Chemicals | 46-0355 | Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) | 185812-86-6 | 500mg | $254 | 2024-03-01 | Buy |
| Alfa Aesar | 044446 | Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) | 185812-86-6 | 2g | $1020 | 2024-03-01 | Buy |
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Chemical Properties,Uses,Production
Reactions
- Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids.
- Aryl bromide - silyl ketene acetal coupling.
- Catalyst for intermolecular α-arylation of zinc amide enolates.
- Catalyst for α-vinylation of carbonyl compounds.
- Catalyst for thiol coupling of heteroaromatic aryl bromides.
Chemical Properties
Greenish blue
Uses
Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 104)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15371 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | sales@dolonchem.com | CHINA | 2972 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12439 | 58 |
| Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
| Shanxi Xuanran Import and Export Trade Co., Ltd. | +8617735180244 | mike_yan@xuanranglobal.com | CHINA | 4022 | 58 |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | mcbio_sales@163.com | China | 2255 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9604 | 58 |
View Lastest Price from PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-03-06 | Dibromobis(tri-tert-butylphosphine)dipalladium(I)
185812-86-6
|
US $8.70 / g | 10g | 27.4% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD | |
 |
2019-07-06 | PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
185812-86-6
|
US $1.00 / kg | 1kg | 95%-99% | 100kg | Career Henan Chemical Co |
-
- Dibromobis(tri-tert-butylphosphine)dipalladium(I)
185812-86-6
- US $8.70 / g
- 27.4%
- Hebei Guanlang Biotechnology Co,.LTD
-
- PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
185812-86-6
- US $1.00 / kg
- 95%-99%
- Career Henan Chemical Co
185812-86-6(PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE)Related Search:
DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I)
Dibromobis(tri-tert-butylphosphine)dipalladium
Dibromobis(tri-tert-butylphosphine)dipalladium(I)
-bromobis(tri-tert-butylphosphine)dipalladium/ Pd (I) dimer Reasonably stable for packaging and transfer.
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE, DIMER
Bromo(tri-tert-butylphosphine)palladium(I)dimer
DI--BROMOBIS(TRI-TERT-BUTYLPHOSPHINO)DIPALLADIUM(I)
Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I)
Dibromobis(tri-tert-butylphosphino)dipalladium(I), Palladium(I) tri-tert-butylphosphine bromide, dimer
PalladiuM, di-M-broMobis[tris(1,1-diMethylethyl)phosphine]di-,(Pd-Pd)
Di-^M-broMobis(tri-tert-butylphosphine)dipalladiuM(I)
broMopalladiuM
[Pd(μ-Br)t-Bu3P]2
Pd-113
Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
Palladium, di-μ-bromobis[tris(1,1-dimethylethyl)phosphine]di-, (Pd-Pd)
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE ISO 9001：2015 REACH
Bis (tri-t-butylphosphine) palladium bromide (I), dimer
185812-86-6
PdC4H93PBr2
C24H54Br2P2Pd2
C12H27BrPPd
Pd
metal phosphine complex