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Methyl 2-furoate

CAS No.
611-13-2
Chemical Name:
Methyl 2-furoate
Synonyms
METHYL FURAN-2-CARBOXYLATE;2-FURANCARBOXYLIC ACID METHYL ESTER;MEFAT;FEMA 2703;2-METHYLFUROATE;Methyle furoate;METHYL 2-FUROATE;METHYL PYROMUCATE;Methyl 2-furanoate;RARECHEM AL BF 0007
CBNumber:
CB3306772
Molecular Formula:
C6H6O3
Molecular Weight:
126.11
MDL Number:
MFCD00003236
MOL File:
611-13-2.mol
MSDS File:
SDS
Last updated:2023-11-03 16:33:47

Methyl 2-furoate Properties

Boiling point 181 °C (lit.)
Density 1.179 g/mL at 25 °C (lit.)
FEMA 2703 | METHYL 2-FUROATE
refractive index n20/D 1.487(lit.)
Flash point 164 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Clear pale yellow to brown
Odor fruity, mushroom-like odor
Odor Type fungal
Water Solubility slightly soluble
Sensitive Lachrymatory
JECFA Number 746
Merck 14,4307
BRN 111110
LogP 0.99
CAS DataBase Reference 611-13-2(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) METHYL 2-FUROATE
FDA UNII O9A8D29YDE
NIST Chemistry Reference Methyl 2-furoate(611-13-2)
EPA Substance Registry System 2-Furancarboxylic acid, methyl ester (611-13-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H301-H312-H315-H319-H335
Precautionary statements  P280-P301+P310+P330-P302+P352+P312-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  36/37/38-21/22-22
Safety Statements  26-36-36/37/39
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  LV1950000
Hazard Note  Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29321900
NFPA 704
2
3 0

Methyl 2-furoate price More Price(32)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W270318 Methyl 2-furoate ≥98%, FG 611-13-2 sample-k $54.6 2024-03-01 Buy
Sigma-Aldrich W270318 Methyl 2-furoate ≥98%, FG 611-13-2 100g $75.3 2024-03-01 Buy
Sigma-Aldrich W270318 Methyl 2-furoate ≥98%, FG 611-13-2 1kg $212 2024-03-01 Buy
Sigma-Aldrich W270318 Methyl 2-furoate ≥98%, FG 611-13-2 5kg $480 2024-03-01 Buy
Sigma-Aldrich 129852 Methyl 2-furoate 98% 611-13-2 25g $35.4 2024-03-01 Buy
Product number Packaging Price Buy
W270318 sample-k $54.6 Buy
W270318 100g $75.3 Buy
W270318 1kg $212 Buy
W270318 5kg $480 Buy
129852 25g $35.4 Buy

Methyl 2-furoate Chemical Properties,Uses,Production

Description

Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).

Chemical Properties

Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy

Chemical Properties

Colorless to light yellow liqui

Occurrence

Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.

Uses

Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.

Uses

Solvent, organic synthesis.

Definition

ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.

Preparation

From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)

Aroma threshold values

Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.

Taste threshold values

Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225

General Description

Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.

Safety Profile

Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.

98-00-0
67-56-1
611-13-2
Synthesis of Methyl 2-furoate from Furfuryl alcohol and Methanol
Global( 451)Suppliers
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View Lastest Price from Methyl 2-furoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 2-furoate pictures 2024-04-12 Methyl 2-furoate
611-13-2
US $0.00 / kg 1kg 99% 2000ton Shaanxi Haibo Biotechnology Co., Ltd
Methyl 2-furoate pictures 2023-11-04 Methyl 2-furoate
611-13-2
US $20.00-1.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
Methyl 2-furoate pictures 2023-09-06 Methyl 2-furoate
611-13-2
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
  • Methyl 2-furoate pictures
  • Methyl 2-furoate
    611-13-2
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
RARECHEM AL BF 0007 PYROMUCIC ACID METHYL ESTER 2-METHYLFUROATE 2-FUROIC ACID METHYL ESTER METHYL 2-FURANCARBOXYLATE METHYL 2-FUROATE MEFAT METHYL PYROMUCATE FEMA 2703 FURAN-2-CARBOXYLIC ACID METHYL ESTER FURANCARBOXYLIC ACID METHYL ESTER Furoic acid Methyl ester Methyl 2-furoate 98% Furan-alpha-carboxylic acid methyl ester furan-alpha-carboxylicacidmethylester Methyl alpha-furoate METHYL 2-FUROATE 98+% 2-FURANCARBOXYLIC ACID METHYL ESTER 99+% 2-Furanecarboxylicacidmethylester Methyl furan-2-carboxylate, Methyl pyromucate Methyl 2-furanoate Methyl 2-furoate ,99% Methyl 2-furoate Methyl pyromucate 2-Furancarboxylic acid methyl 2-Furoic Acid Methyl Ester 2-Furancarboxylic Acid Methyl Ester Methyl 2-Furoate METHYL 2-FURANCARBOXYLATE FOR SYNTHESIS Methyl furan-2-carboxylate, 2-(Methoxycarbonyl)furan Methyl2-Furancarboxylate> Methyl 2-furoate USP/EP/BP 2-(Methoxycarbonyl)furan 2-FURANCARBOXYLIC ACID METHYL ESTER METHYL FURAN-2-CARBOXYLATE Cimetidine Impurity 16(Cimetidine EP Impurity I) Methyle furoate 611-13-2 611-32-2 Building Blocks Furans Heterocyclic Building Blocks Aromatic Esters Furan&Benzofuran ester Flavor