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Dicyclohexylchlorophosphine

CAS No.
16523-54-9
Chemical Name:
Dicyclohexylchlorophosphine
Synonyms
chlorodicyclohexylphosphane;CHLORODICYCLOHEXYLPHOSPHINE;Cy2PCl;orodicycL;98% (C6H11)2PCl;DICYCLOHEXYLCHLOROPHOSPHINE;Dicyclohexylphosphine chloride;Chlorodicyclohexylphosphine 97%;Chlorodicyclohexylphosphine,97%;Chlorodicyclohexylphosphine >
CBNumber:
CB3345601
Molecular Formula:
C12H22ClP
Molecular Weight:
232.73
MDL Number:
MFCD00014294
MOL File:
16523-54-9.mol
MSDS File:
SDS
Last updated:2023-12-21 17:48:05

Dicyclohexylchlorophosphine Properties

Melting point 126-128 °C
Boiling point 165 °C/12 mmHg (lit.)
Density 1.054 g/mL at 25 °C (lit.)
refractive index n20/D 1.533(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Liquid
Specific Gravity 1.054
color Colorless to pale yellow
Water Solubility reacts violently
Sensitive Air & Moisture Sensitive
InChIKey AKJFBIZAEPTXIL-UHFFFAOYSA-N
CAS DataBase Reference 16523-54-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
Hazard Codes  C
Risk Statements  14-34
Safety Statements  26-27-36/37/39-45-8
RIDADR  UN 3265 8/PG 2
WGK Germany  3
TSCA  No
HazardClass  8
PackingGroup  II
HS Code  29319090
NFPA 704
1
3 2
W

Dicyclohexylchlorophosphine price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 481408 Chlorodicyclohexylphosphine 97% 16523-54-9 1g $83.5 2024-03-01 Buy
Sigma-Aldrich 481408 Chlorodicyclohexylphosphine 97% 16523-54-9 5g $283 2024-03-01 Buy
TCI Chemical C1658 Chlorodicyclohexylphosphine >97.0%(T) 16523-54-9 1g $52 2024-03-01 Buy
TCI Chemical C1658 Chlorodicyclohexylphosphine >97.0%(T) 16523-54-9 5g $226 2024-03-01 Buy
Alfa Aesar 033571 Dicyclohexylchlorophosphine, 98+% 16523-54-9 1g $128.65 2024-03-01 Buy
Product number Packaging Price Buy
481408 1g $83.5 Buy
481408 5g $283 Buy
C1658 1g $52 Buy
C1658 5g $226 Buy
033571 1g $128.65 Buy

Dicyclohexylchlorophosphine Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:

  • 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
  • 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.

It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.

Uses

Dicyclohexylchlorophosphine is used as pharmaceutical intermediate. It is also used in the synthesis of various phosphines.

Application

Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.

Precautions

Store in cool, dry conditions in well sealed containers. Protect from humidity and water. Store under dry inert gas. It is sensitive to air and moisture. Incompatible with strong oxidizing agents.

829-84-5
16523-54-9
Synthesis of Dicyclohexylchlorophosphine from DICYCLOHEXYLPHOSPHINE
Global( 276)Suppliers
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XINXIANG RUNYU MATERIAL CO., LTD.
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Hubei Jusheng Technology Co.,Ltd.
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View Lastest Price from Dicyclohexylchlorophosphine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dicyclohexylchlorophosphine pictures 2024-02-23 Dicyclohexylchlorophosphine
16523-54-9
US $59.00-485.00 / g 25g 0.98 25kg Shanghai UCHEM Inc.
Dicyclohexylchlorophosphine pictures 2023-12-16 Dicyclohexylchlorophosphine
16523-54-9
US $0.00-0.00 / kg 1kg 97% 500kg XINXIANG RUNYU MATERIAL CO., LTD.
Dicyclohexylchlorophosphine pictures 2023-11-01 Dicyclohexylchlorophosphine
16523-54-9
US $0.00-0.00 / kg 0.1kg 99.0%min 200kg Hangzhou ICH Biofarm Co., Ltd
Chlorodicyclohexylphosphine ,96% Chlorodicyclohexylphosphine, 97% 5GR 98% (C6H11)2PCl Phosphinous chloride, P,P-dicyclohexyl- Chlorodicyclohexylphosphine 97% Chlorodicyclohexylphosphine Synonyms Dicyclohexylchlorophosphine Dicyclohexylphosphine chloride DICYCLOHEXYLPHOSPHINOUS CHLORIDE DICYCLOHEXYLCHLOROPHOSPHINE Dicyclohexylchlorophosphine,min.98% Dicyclohexylchlorophosphine, 98+% Dicyclohexylchlorophosphine, min. 98% Chlorodicyclohexylphosphine,97% Dicyclohexylchlorophosphine(Cy2PCl) orodicycL Chlorodicyclohexylphosphine > Dicyclohexylchlorophosphinehloride chlorodicyclohexylphosphane CHLORODICYCLOHEXYLPHOSPHINE Cy2PCl 16523-54-9 C12H22ClP C6H112PCl Phosphorus Compounds Phosphorus Precursors Catalysis and Inorganic Chemistry organophosphine halide Achiral Phosphine Alkyl Phosphine P-Cl Catalysis and Inorganic Chemistry Phosphorus Compounds Phosphorus Precursors Chlorophosphines Phosphines