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Methylboronic acid

CAS No.
13061-96-6
Chemical Name:
Methylboronic acid
Synonyms
METHANDROSTENOLONE;CH5BO2;dihydroxy-methyl-borane;Methyboronic Acid;Methylboranic acid;Methyl boric acid;METHYLBORONIC ACID;METHANEBORONIC ACID;METHYLBORON DIHYDROXIDE;Methylboronic acid ,98%
CBNumber:
CB3373202
Molecular Formula:
CH5BO2
Molecular Weight:
59.86
MDL Number:
MFCD00002105
MOL File:
13061-96-6.mol
MSDS File:
SDS
Last updated:2023-08-30 19:07:15

Methylboronic acid Properties

Melting point 91-94 °C (lit.)
Boiling point 141.7±23.0 °C(Predicted)
Density 0.965±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility DMSO, Water
pka 9.97±0.43(Predicted)
form Crystalline Powder
color White to off-white
Water Solubility Soluble in water.
Sensitive Hygroscopic
BRN 1731087
InChI InChI=1S/CH5BO2/c1-2(3)4/h3-4H,1H3
InChIKey KTMKRRPZPWUYKK-UHFFFAOYSA-N
SMILES CB(O)O
CAS DataBase Reference 13061-96-6(CAS DataBase Reference)
FDA UNII 8Z1ME41SCH

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
3-10
Hazard Note  Irritant/Keep Cold
HazardClass  IRRITANT
HS Code  29319090
NFPA 704
1
2 0

Methylboronic acid price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 165336 Methylboronic acid 97% 13061-96-6 1g $54.7 2024-03-01 Buy
Sigma-Aldrich 165336 Methylboronic acid 97% 13061-96-6 5g $117 2024-03-01 Buy
TCI Chemical M1553 Methylboronic Acid (contains varying amounts of Anhydride) 13061-96-6 1g $41 2024-03-01 Buy
TCI Chemical M1553 Methylboronic Acid (contains varying amounts of Anhydride) 13061-96-6 5g $102 2024-03-01 Buy
Alfa Aesar L15589 Methylboronic acid, 97% 13061-96-6 1g $51.5 2024-03-01 Buy
Product number Packaging Price Buy
165336 1g $54.7 Buy
165336 5g $117 Buy
M1553 1g $41 Buy
M1553 5g $102 Buy
L15589 1g $51.5 Buy

Methylboronic acid Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal powde

Uses

Methylboronic acid can be used as a reagent:

  • In the palladium-catalyzed Stille and Suzuki-Miyaura cross-couplings.
  • In the microwave-heated heterogeneous palladium (Pd)-catalytized reactions.
  • In ruthenium (Ru)-catalyzed silylation reactions
  • To prepare bis(aminotropone) titanium (Ti) catalysts for ethylene polymerizations.
  • In the enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts.
  • To prepare common building blocks for pharmaceuticals and agrochemicals.
  • To prepare chrysin analogs by Suzuki-Miyaura coupling reactions.
  • To prepare casein kinase I inhibitors.
  • In the divergent C-H functionalizations directed by sulfonamide pharmacophores in drug discovery.
  • In the synthesis of unsymmetrical monosulfides from disulfides via copper-catalyzed coupling with boronic acids.
  • In a palladium-catalyzed coupling with enol tosylates.
  • For derivatizing many carbohydrates and biologically active compounds for GLC analysis.

Uses

suzuki reaction

Uses

Methylboronic Acid is a methylated derivative of boronic acid, a building block towards various intermediates in suzuki coupling.

Global( 351)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2503 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
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Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3012 60
ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
NINGBO INNO PHARMCHEM CO., LTD.
13867897135 sales@nbinno.com CHINA 925 58
Shanghai Arbor Chemical Co., Ltd.
021-60451682 act@arborchemical.com CHINA 906 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 6992 58

View Lastest Price from Methylboronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methylboronic acid pictures 2023-08-31 Methylboronic acid
13061-96-6
US $100.00 / bag 1bag 99 5000 Hebei Fengqiang Trading Co., LTD
Methylboronic acid pictures 2023-05-27 Methylboronic acid
13061-96-6
US $30.00 / kg 1kg 99.99% 50000tons Henan Bao Enluo International TradeCo.,LTD
Methylboronic acid pictures 2023-03-06 Methylboronic acid
13061-96-6
US $1.90 / KG 1KG 99% 10 ton Hebei Guanlang Biotechnology Co,.LTD
  • Methylboronic acid pictures
  • Methylboronic acid
    13061-96-6
  • US $30.00 / kg
  • 99.99%
  • Henan Bao Enluo International TradeCo.,LTD
METHYLBORON DIHYDROXIDE METHYLBORONIC ACID METHANEBORONIC ACID Methylboron dihydroxide, GLC Grade Methylboronic acid ,98% Methylboronic Acid (contains varying amounts of Anhydride) METHYLBORONIC ACID FOR GC Methylboronic acid CH3B(OH)2 Methylboronic acid(Methaneboronic acid) Boronic acid, methyl- (9CI) Methylboronic acid, 98%, for synthesis TIANFU CHEM----Methylboronic acid CH5BO2 dihydroxy-methyl-borane Methylboranic acid METHANDROSTENOLONE Methyboronic Acid Methyl boric acid 13061-96-6 13061-96-5 CH5O2B CH3BOH2 Organometallic Reagents Acylation Alkyl Boronic Acids Boronic Acids and Derivatives Piperidines ,Piperazines ,Homopiperidines Alkyl API intermediates Boronic acid Organoborons Substituted Boronic Acids CHIRAL CHEMICALS