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DIBUTYLBORON TRIFLUOROMETHANESULFONATE

DIBUTYLBORON TRIFLUOROMETHANESULFONATE structure

CAS No.: 60669-69-4

Chemical Name:: DIBUTYLBORON TRIFLUOROMETHANESULFONATE

Synonyms: DIBUTYLBORON TRIFLATE;dibutylboryl triflate;DIBUTYLBORYL TRIFLUOROMETHANESULFONATE;dibutyl(((trifluoroMethyl)sulfonyl)oxy)borane;dibutylboron triflate solution;DIBUTYLBORON TRIFLUOROMETHANESULFONATE;dibutylboranyl trifluoromethanesulfonate;Dibutylboron trifluoromethanesulfonate,98%;Dibutylboryl trifluoromethanesulfonate solution;Borane,dibutyl[[(trifluoromethyl)sulfonyl]oxy]-

CBNumber:: CB3402304

Molecular Formula:: C9H18BF3O3S

Molecular Weight:: 274.11

MDL Number:: MFCD00009669

MOL File:: 60669-69-4.mol

Last updated:2023-04-23 13:52:06

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DIBUTYLBORON TRIFLUOROMETHANESULFONATE Properties

Boiling point	37℃ (0.12 Torr)
Density	1.271 g/mL at 25 °C
Flash point	80 °F
storage temp.	2-8°C
form	Solution
color	Clear light yellow to orange
BRN	1968660
InChIKey	FAVAVMFXAKZTMV-UHFFFAOYSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H226-H314-H335-H336-H351-H373
Precautionary statements	P261-P280-P305+P351+P338-P310
Hazard Codes	C,F+,F
Risk Statements	12-22-34-66-67-40-10-37-65-48/20-11-63-19
Safety Statements	9-16-26-33-36/37/39-45-62
RIDADR	UN 2924 3/PG 1
WGK Germany	3
F	1-10
HazardClass	3.2
PackingGroup	III
HS Code	29310099

DIBUTYLBORON TRIFLUOROMETHANESULFONATE price More Price(12)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	D428010	Dibutylboryl trifluoromethanesulfonate solution	60669-69-4	1g	$120	2021-12-16	Buy
TRC	D428010	Dibutylboryl trifluoromethanesulfonate solution	60669-69-4	10g	$155	2021-12-16	Buy
American Custom Chemicals Corporation	BOR0004400	DIBUTYLBORON TRIFLUOROMETHANESULFONATE 98.00%	60669-69-4	25ML	$165.2	2021-12-16	Buy
Biosynth Carbosynth	FD75244	Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution	60669-69-4	5G	$200	2021-12-16	Buy
Biosynth Carbosynth	FD75244	Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution	60669-69-4	10g	$250	2021-12-16	Buy

Product number	Packaging	Price	Buy
D428010	1g	$120	Buy
D428010	10g	$155	Buy
BOR0004400	25ML	$165.2	Buy
FD75244	5G	$200	Buy
FD75244	10g	$250	Buy

DIBUTYLBORON TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production

Chemical Properties

clear light yellow to orange solution

Uses

Dibutylboryl trifluoromethanesulfonate may be used in the following studies:

Stereo- and regio-selective synthesis of erythro aldols.
As a promoter for the solution and polymer-supported trichloroacetimidate-based glycosylations.
Synthesis of β-alkoxy carbonyl compounds via one-step Mukaiyama aldol-type reaction.
Aldol-type cyclization for the stereoselective synthesis of cyclic ethers.
As a reagent for the formation of boron enolates.
As a complexation aid for the isolation of 1-acyldipyrromethanes.
As a promoter in [1,2]-Wittig reaction between aldehydes and O-benzyl or O-allyl glycolate esters, creating two contiguous stereocenters (1,2-diol) in good yield without the need for strong base.

General Description

Dibutylboryl trifluoromethanesulfonate (Dibutylboron triflate, Bu₂BOTf) is an organometallic reagent. It efficiently promotes the1,4-addition of benzylic and allylic organocopper reagents.

Purification Methods

Distil it in a vacuum under argon and store it under argon. It should be used within 2 weeks of purchase or after redistillation. Use a short path distillation system. It has IR bands in CCl4 at max 1405, 1380, 1320, 1200 and 1550cm1 , and 1 3C NMR (CDCl3) with at 118.1, 25.1, 21.5 and 13.6ppm. [Gage & Evans Org Synth 68 83 1990, Evans et al. J Am Chem Soc 103, 3099 1981.] TOXIC

DIBUTYLBORON TRIFLUOROMETHANESULFONATE synthesis

Synthesis of DIBUTYLBORON TRIFLUOROMETHANESULFONATE from TRIBUTYLBORANE and Trifluoromethanesulfonic acid

DIBUTYLBORON TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

TRIBUTYLBORANE Trifluoromethanesulfonic acid Dichloromethane

Preparation Products

DIBUTYLBORON TRIFLUOROMETHANESULFONATE Suppliers

Global( 83)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15371	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12431	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58
Wuxi Rejoys chemical Technology Co., Ltd.	0510-86103381	sales@rejoyschem.com	CHINA	976	58
Alfa Chemistry	+1-5166625404	Info@alfa-chemistry.com	United States	21317	58
GLR Innovations	+91 9891111994	info@glrgroup.in	India	4542	58
LEAP CHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	24738	58

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
CONIER CHEM AND PHARMA LIMITED	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Wuxi Rejoys chemical Technology Co., Ltd.	58
Alfa Chemistry	58
GLR Innovations	58
LEAP CHEM CO., LTD.	58

View Lastest Price from DIBUTYLBORON TRIFLUOROMETHANESULFONATE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-09-03	DIBUTYLBORON TRIFLUOROMETHANESULFONATE 60669-69-4	US $1.80-3.60 / KG	1KG	99%	88kg	Career Henan Chemical Co

DIBUTYLBORON TRIFLUOROMETHANESULFONATE
60669-69-4
US $1.80-3.60 / KG
99%
Career Henan Chemical Co

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Dibutylboron trifluoromethanesulfonate, 1M solution in diethylether dibutylboron triflate solution TRIFLUOROMETHANESULFONIC ACID ANHYDRIDE WITH DIBUTYLBORINIC ACID) Dibutylboron trifluoromethanesulfonate,98% Dibutylboryl trifluoromethanesulfonate solution,Dibutylboron triflate solution Dibutylboron trifluoroMethanesulfonate, 1M solution in diethyl ether, AcroSeal Dibutylboryl trifluoroMethanesulfonate solution 1.0 M in Methylene chloride dibutylboranyl trifluoromethanesulfonate DIBUTYLBORON TRIFLUOROMETHANESULFONATE dibutylboryl trifluoromethanesulfonate sol.,~1 M in diet.E. Dibutylboryl trifluoromethanesulfonate solution DIBUTYLBORON TRIFLATE, 1.0M SOLUTION IN DIETHYL ETHER DIBUTYLBORON TRIFLATE, 1.0M SOLUTION IN DICHLOROMETHANE DIBUTYLBORYL TRIFLUOROMETHANESULF. SOL., ~1M IN DICHLOROMET. Dibutylboron trifluoromethanesulfonate, 1M sol. in dichloromethane Methanesulfonic acid, 1,1,1-trifluoro-, anhydride with B,B-dibutylborinic acid Borane,dibutyl[[(trifluoromethyl)sulfonyl]oxy]- Dibutylboryl trifluoromethanesulphonate solution, 1.0 M in methylene chloride Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution dibutylboryl triflate dibutyl(((trifluoroMethyl)sulfonyl)oxy)borane DIBUTYLBORON TRIFLATE DIBUTYLBORYL TRIFLUOROMETHANESULFONATE 60669-69-4 C9H18BF3O3S CF3SO3BCH23CH32 C-C Bond Formation Boronic Acids and Derivatives Synthetic Reagents Others Organometallic Reagents