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Benzyl salicylate

CAS No.
118-58-1
Chemical Name:
Benzyl salicylate
Synonyms
BENZYL 2-HYDROXYBENZOATE;118-58;FEMA 2151;Benzylsalicylat;enzyl salicylate;Benzyl saIicylate;BENZYL SALICYLATE;benzyle salicylate;benzylhydroxybenzoate;SALICILATO DE BENCILO
CBNumber:
CB3484524
Molecular Formula:
C14H12O3
Molecular Weight:
228.24
MDL Number:
MFCD00020034
MOL File:
118-58-1.mol
MSDS File:
SDS
Last updated:2024-04-25 17:59:01

Benzyl salicylate Properties

Melting point 18-20 °C
Boiling point 168-170 °C5 mm Hg(lit.)
Density 1.176 g/mL at 25 °C(lit.)
vapor pressure 0.01Pa at 25℃
refractive index n20/D 1.581(lit.)
FEMA 2151 | BENZYL SALICYLATE
Flash point >230 °F
storage temp. -20°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka 8.11±0.30(Predicted)
color Thick colorless liquid
Odor pleasant odor
Odor Type balsamic
Viscosity 17mm2/s
Water Solubility Slightly soluble
Merck 14,1144
JECFA Number 904
BRN 2115365
Dielectric constant 4.1(20℃)
InChIKey ZCTQGTTXIYCGGC-UHFFFAOYSA-N
LogP 4
Substances Added to Food (formerly EAFUS) BENZYL SALICYLATE
FDA 21 CFR 172.515
CAS DataBase Reference 118-58-1(CAS DataBase Reference)
EWG's Food Scores 4-7
FDA UNII WAO5MNK9TU
NIST Chemistry Reference Benzoic acid, 2-hydroxy-, phenylmethyl ester(118-58-1)
EPA Substance Registry System Benzyl salicylate (118-58-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317-H319-H412
Precautionary statements  P261-P264-P273-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,N
Risk Statements  36/37/38-51/53-43
Safety Statements  26-36-24/25-61-37-24
WGK Germany  2
RTECS  VO1750000
TSCA  Yes
HS Code  29182900
Toxicity LD50 orl-rat: 2227 mg/kg FCTXAV 11,1029,73
NFPA 704
1
0 0

Benzyl salicylate price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 77069 Benzyl salicylate reference material 118-58-1 100MG $163 2022-05-15 Buy
TCI Chemical S0009 Benzyl Salicylate >99.0%(GC) 118-58-1 25g $22 2024-03-01 Buy
TCI Chemical S0009 Benzyl Salicylate >99.0%(GC) 118-58-1 500g $46 2024-03-01 Buy
Alfa Aesar A16184 Benzyl salicylate, 99% 118-58-1 100g $18.65 2024-03-01 Buy
Alfa Aesar A16184 Benzyl salicylate, 99% 118-58-1 500g $48.65 2024-03-01 Buy
Product number Packaging Price Buy
77069 100MG $163 Buy
S0009 25g $22 Buy
S0009 500g $46 Buy
A16184 100g $18.65 Buy
A16184 500g $48.65 Buy

Benzyl salicylate Chemical Properties,Uses,Production

Description

Benzyl salicylate is a salicylic acid benzyl ester, a chemical compound most frequently used in cosmetics. It appears as an almost colorless liquid with a mild odor described as "very faint, sweetfloral, slightly balsamic" by those who can smell it, but many people either can't smell it at all or describe its smell as "musky". Trace impurities can have a significant influence on the odour.[1] It occurs naturally in a variety of plants and plant extracts and is widely used in blends of fragrance materials.
There is some evidence that people can become sensitized to this material and as a result there is a restriction standard concerning the use of this material in fragrances by the International Fragrance Association.
It is used as a solvent for crystalline synthetic musks and as a component and fixative in floral perfumes such as carnation, jasmine, lilac, and wallflower.

Chemical Properties

Benzyl Salicylate occurs in several essential oils, is a colorless, viscous liquid with a weak, sweet, slightly balsamic odor and a sweet, currant-like taste. It is soluble in ethanol, most non-volatile and volatile oils, slightly soluble in propylene glycol, insoluble in glycerin and practically insoluble in water.

Occurrence

It has been reported in small amounts in carnation oil (Dianthus caryophyllus L.) and in larger amounts in the oil of Primula auricula. Also found in American cranberry, clove bud, peppermint oil and buckwheat.

Uses

benzyl salicylate is a fragrance found naturally occurring in carnations and in certain members of the primrose family. Although it can be derived for cosmetic use from natural essential oils, such as jasmine oil, neroli, and ylang-ylang, it can also be synthetically manufactured.

Uses

Benzyl Salicylate is an chemical compound commonly used in the cosmetic industry. Benzyl Salicylate is also found in essential oils from green tea and was shown to exhibit antioxidant and antimicrobia l activity.

Definition

ChEBI: Benzyl salicylate is a benzoate ester and a member of phenols. It is functionally related to a salicylic acid.

Preparation

By esterification of salicylic acid with benzyl alcohol.

General Description

Colorless liquid. Melting point near room temperature (18-20°C). As fixer in perfumery; in sunscreen preparations.

Air & Water Reactions

Slightly water soluble .

Reactivity Profile

Benzyl salicylate may hydrolyze in aqueous acid or basic solutions. Benzyl salicylate can react with oxidizing materials.

Fire Hazard

Flash point data for Benzyl salicylate are not available, but Benzyl salicylate is probably combustible.

Flammability and Explosibility

Non flammable

Contact allergens

Benzyl salicylate is used as fixer in perfumery and sunscreen preparations. As a (weak) perfume sensitizer, it has to be listed by name in cosmetic preparations in the EU.

Safety Profile

Moderately toxic by ingestion. Seealso BENZYL ALCOHOL, SALICYLIC ACID, andESTERS. Combustible when exposed to heat or flame.When heated to decomposition it emits acrid smoke andirritating fumes. Incompatible with oxidizing materials.

Safety

Benzyl salicylate poses dangers to sensitive skin.  Even in very small amounts, it may cause allergic reactions when applied to the skin. Benzyl salicylate can cause contact dermatitis (skin irritation) to people with sensitive skin types. It is also on the European Commission's list of 26 known allergens. Some of the other ingredients on the fragrance allergen list include linalool, coumarin, geraniol, and limonene.

54-21-7
100-44-7
118-58-1
Synthesis of Benzyl salicylate from Sodium salicylate and Benzyl chloride
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View Lastest Price from Benzyl salicylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzyl salicylate pictures 2024-04-25 Benzyl salicylate
118-58-1
US $200.00-95.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
benzyl pictures 2024-04-25 benzyl
118-58-1
US $100.00 / kg 1kg 99 5000 Hebei Zhuanglai Chemical Trading Co.,Ltd
Benzyl salicylate pictures 2023-09-06 Benzyl salicylate
118-58-1
US $1.00 / kg 1kg 99% 20tons Hebei Yanxi Chemical Co., Ltd.
  • Benzyl salicylate pictures
  • Benzyl salicylate
    118-58-1
  • US $200.00-95.00 / kg
  • 99%
  • Hebei Zhuanglai Chemical Trading Co.,Ltd
  • benzyl pictures
  • benzyl
    118-58-1
  • US $100.00 / kg
  • 99
  • Hebei Zhuanglai Chemical Trading Co.,Ltd
2-hydroxy-benzoicaciphenylmethylester Benzoicacid,2-hydroxy-,phenylmethylester benzyle salicylate benzylhydroxybenzoate Salicyclic acid benzyl ester SALICILATO DE BENCILO BENZYL SALICYLATE 98+% FCC SALICYLIC ACID BENZYL ESTER, SECONDARY STANDARD Benzyl salicylate, 98+% Benzylsalicylat Benzoic acid, 2-hydroxy-, phenylme 2-Hydroxybenzone acid benzoate Benzyl saIicylate 2-Hydroxybenzoic acid benzyl o-Hydroxybenzoic acid benzyl ester Salicylic acid benzyl Benzyl salisylate-d4 (Benzyl 2-hydroxybenzoate-3,4,5,6-d4) Salicylic Acid Benzyl Ester 2-Hydroxybenzoic Acid Benzyl Ester Benzyl 2-Hydroxybenzoate Benzyl 2-Hydroxybenzoate-d4 Benzyl salicylate purum, >=99.0% (GC) enzyl salicylate FEMA 2151 BENZYL SALICYLATE BENZYL O-HYDROXYBENZOATE BENZYL ORTHO HYDROXY BENZOATE SALICYLIC ACID BENZYL ESTER 2-HYDROXYBENZOIC ACID BENZYL ESTER 2-hydroxybenzoic acid phenylmethyl ester 118-58 Benzyl salicylate@1000 μg/mL in Acetonitrile Benzyl Salicylate > Benzyl salicylate USP/EP/BP Best Price Benzyl Salicylate CAS 118-58-1 with Fast Delivery Fast Delivery Benzyl Salicylate CAS 118-58-1 with Best Price BENZYL 2-HYDROXYBENZOATE 118-58-1 115-58-1 C6H5CH2OOCC6H4OH 2HOC6H4CO2CH2C6H5 ESTER Organic Building Blocks Esters Carbonyl Compounds C12 to C63 Building Blocks Used in variety of cosmetic and soap essences. Pharmaceutical Intermediates