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Diacetone-D-glucose

CAS No.
582-52-5
Chemical Name:
Diacetone-D-glucose
Synonyms
GLUCOFURANOSE;(3aR,5S,6S,6aR)-5-((R)-2,2-DiMethyl-1,3-dioxolan-4-yl)-2,2-diMethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol;DIACETONEGLUCOSE;1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE;1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose;1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE;ucose;NSC 1223
CBNumber:
CB3673320
Molecular Formula:
C12H20O6
Molecular Weight:
260.29
MDL Number:
MFCD00005544
MOL File:
582-52-5.mol
MSDS File:
SDS
Last updated:2023-10-10 18:06:03

Diacetone-D-glucose Properties

Melting point 110-111 °C(lit.)
alpha -11 º (c=5, EtOH)
Boiling point 323.54°C (rough estimate)
Density 1.1432 (rough estimate)
refractive index -18.5 ° (C=5, H2O)
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Chloroform (Slightly), Methanol (Slightly), Water (Slightly, Sonicated)
pka 13.15±0.60(Predicted)
form Powder
color White to yellow
optical activity [α]20/D 18°, c = 1% in H2O
Water Solubility slightly soluble
Merck 14,2965
BRN 84386
InChIKey KEJGAYKWRDILTF-YENDLIOYSA-N
FDA UNII R3P8TN410C
EPA Substance Registry System Diacetone glucose (582-52-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25-36/37-26
WGK Germany  2
RTECS  LZ4958000
3-10
TSCA  Yes
HS Code  29329970
Toxicity LD50 oral in mouse: 4gm/kg
NFPA 704
1
0 1

Diacetone-D-glucose price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 31460 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose purum,≥98.0%(TLC) 582-52-5 25g $62.6 2024-03-01 Buy
Sigma-Aldrich 31460 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose purum,≥98.0%(TLC) 582-52-5 100g $138 2024-03-01 Buy
Sigma-Aldrich S83055 5-(2,2-DIMETHYL-(1,3)DIOXOLAN-4-YL)-2,2-DIMETHYL-4H-FURO(2,3-D)(1,3)DIOXOL-6-OL AldrichCPR 582-52-5 250MG $28.6 2023-06-20 Buy
TCI Chemical D1949 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose >97.0%(GC) 582-52-5 10g $16 2024-03-01 Buy
TCI Chemical D1949 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose >97.0%(GC) 582-52-5 25g $40 2024-03-01 Buy
Product number Packaging Price Buy
31460 25g $62.6 Buy
31460 100g $138 Buy
S83055 250MG $28.6 Buy
D1949 10g $16 Buy
D1949 25g $40 Buy

Diacetone-D-glucose Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose is a compound useful in organic synthesis.

Uses

It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose.

Purification Methods

Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.]

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View Lastest Price from Diacetone-D-glucose manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diacetone-d-Glucose pictures 2023-10-10 Diacetone-d-Glucose
582-52-5
US $0.00 / kg 1kg 0.99 20tons Hebei Yanxi Chemical Co., Ltd.
Diacetone-D-glucose pictures 2023-08-22 Diacetone-D-glucose
582-52-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Diacetone-D-glucose pictures 2023-06-15 Diacetone-D-glucose
582-52-5
US $95.00 / Kg/Bag 1KG 99% 100kg Baoji Guokang Bio-Technology Co., Ltd.
5-(2,2-DIMETHYL-[1,3]DIOXOLAN-4-YL)-2,2-DIMETHYL-TETRAHYDRO-FURO[2,3-D][1,3]DIOXOLE A-D-GLUCOFURANOSE Diacetone-D-glucose, 98+% DIACETONE-D-GLUCOSE DIACETONE-ALPHA-D-GLUCOSE DIACETONE-ALPHA-D-GLC D-GLUCOSE DIACETONIDE DIISOPROPYLIDENEGLUCOFURANOSE DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE, 1,2,5,6- .alpha.-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)- 1,2:5,6-di-o-isopropylidene-à-d-glucofuranose 1,2:5,6-Di-O-isopropylidene-a-L-glucofuranose 1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE,98% a-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)- Diacetone-D-Glucose/1,2:5,6-Di-O-Isopropylidene-Alpha-D-Glucofuranose 1,2:5,6-Di-isopropylidene-glucofuranose 1,2:5,6-DI-O-ISOPROPYLIDENE-ALFA-D-GLUCOFURANOSE 1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE (DIACETONE-D-GLUCOSE) D-Glucose diacetonide, Diacetone-D-glucose 1,2,5,6-diisopropylidene-D-glucose, D-Glucose diacetonide, Diacetone-D-glucose (3aR,5S,6S,6aR)-5-[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[4,5-d][1,3]dioxol-6-ol Di-O-isopropylidene-a-D-glucofuranose Glucose bisacetonide 1,2,5,6-Di-O-isopropylidene-|-L-glucofuranose (3aR,3aα,6aα)-5α-[(4R)-2,2-Dimethyl-1,3-dioxolane-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d]-1,3-dioxole-6α-ol 1-O,2-O:5-O,6-O-Bis(1-methylethylidene)-α-D-glucofuranose 1-O,2-O:5-O,6-O-Bis(isopropylidene)-α-D-glucofuranose 1-O,2-O:5-O,6-O-Diisopropylidene-α-D-glucofuranose 1,2,5,6-DIISOPROPYLIDENE-D-GLUCOSE 1,2:5,6-DIISOPROPYLIDENE-D-GLUCOSE 1,2;5,6-DI-O-ISOPROPYLIDENE-D-GLUCOFURANOSE 1,2,5,6-DI-O-ISO-PROPYLIDENEGLUCOFURANOSE 1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE 1,2:5,6-DI-O-ISOPROPYLDENE-ALPHA-D-GLUCOFURANOSE (-)-1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE 1,2:5,6-bis-o-(1-methylethylidene)-alpha-d-glucofuranos 1:2,5:6-di-o-isopropyliden-alpha-d-glucofuranose 5:6-di-o-isopropylidene-1:alpha-d-glucofuranos Diacetin Glucose 1,2,5,6-Di-O-isopropylidene-alpha-D-glucofuranose (Diacetone-D-g Diacetone-D-Glucos 1,2:5,6-Bis-O-(1-Methylethylidene)-α-D-glucofuranose 1,2:5,6-Di-O-isopropylidene-D-glucose NSC 1223 5,6-Di-O-isopropylidene-alpha-D-glucofuranose (-)-1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUC 1,2:5,6-Bis-O-(1-Methylethylidene)-a-D-Glucofuranose Glucose diacetonide 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose, 1,2:5,6-Diisopropylidene-D-glucose, D-glucose diacetonide 1.2.5.6-Diisopropylene-a-D-glucofuranose 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose~1,2:5,6-Diisopropylidene-D-glucose 1,2:5,6-Di-O-isopropylidene- 5-(2,2-Dimethyl-(1,3)dioxolan-4-yl)-2,2-dimethyl-4H-furo(2,3-d)(1,3)dioxol-6-ol (-)-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose for synthesis (3aR,5S,6S,6aR)-5-[(R)-2,2-Dimethyl-1,3-dioxolan-4-yl]-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole 5.6-Di-O-isopropylidene-α-D-glucopyranoside 1,2:5,6-Di-O-isopropylidene-α-L-gulofuranose