ChemicalBook >> CAS DataBase List >>Borane-methyl sulfide complex
Borane-methyl sulfide complex
- CAS No.
- 13292-87-0
- Chemical Name:
- Borane-methyl sulfide complex
- Synonyms
- BMS;Dimethylsulfide borane complex;(Dimethyl sulfide)trihydroboron;DMSB;borane-methyl sulfide;DIMETHYL SULFIDE BORANE;BORANE-DIMETHYLSULFIDE;BORANE-DIMETHYLSULFIDE COMPLEX;borane dimethyl sulfide complex solution;Borane dimethyL
- CBNumber:
- CB3700534
- Molecular Formula:
- C2H10BS
- Molecular Weight:
- 76.97
- MDL Number:
- MFCD00013189
- MOL File:
- 13292-87-0.mol
Last updated:2023-07-19 18:04:24
| Melting point | -40--37°C |
|---|---|
| Boiling point | ~34 °C |
| Density | 1.287 g/mL at 25 °C |
| refractive index | 1.4570 |
| Flash point | 65 °F |
| storage temp. | 2-8°C |
| solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. |
| form | Solution |
| color | Colorless to pale yellow |
| Specific Gravity | 0.801 |
| Water Solubility | reacts |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3663489 |
| InChIKey | RMHDLBZYPISZOI-UHFFFAOYSA-N |
| CAS DataBase Reference | 13292-87-0(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 6AVE9SRR08 |
| NIST Chemistry Reference | Borane-methyl sulfide complex(13292-87-0) |
| EPA Substance Registry System | Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H260-H301+H311-H318-H360FD-H412 | |||||||||
| Precautionary statements | P210-P231+P232-P273-P280-P301+P310-P305+P351+P338 | |||||||||
| Hazard Codes | F+,Xn,F,Xi | |||||||||
| Risk Statements | 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37 | |||||||||
| Safety Statements | 36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39 | |||||||||
| RIDADR | UN 3399 4.3/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | PV5080000 | |||||||||
| F | 10-13-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29309090 | |||||||||
| NFPA 704 |
|
Borane-methyl sulfide complex price More Price(35)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 192120 | Borane dimethyl sulfide complex solution 2.0?M in THF | 13292-87-0 | 4X25ML | $80.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 179825 | Borane dimethyl sulfide complex | 13292-87-0 | 25ml | $80.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 179825 | Borane dimethyl sulfide complex | 13292-87-0 | 4x25ml | $153 | 2024-03-01 | Buy |
| TCI Chemical | D1843 | Dimethyl Sulfide Borane >90.0%(T) | 13292-87-0 | 25mL | $40 | 2024-03-01 | Buy |
| TCI Chemical | D1843 | Dimethyl Sulfide Borane >90.0%(T) | 13292-87-0 | 100mL | $116 | 2024-03-01 | Buy |
Borane-methyl sulfide complex Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow solution
Uses
Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent:
- For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
- For the conversion of ozonides to alcohols.
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
- For the hydroboration reduction and other applications.
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
Uses
Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
General Description
Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.
Borane-methyl sulfide complex Preparation Products And Raw materials
Raw materials
Preparation Products
4H-AMINO-6-BROMO-2,3-DIHYDROTHIOCHROMEN-1,1-DIOXIDE
Ethylferrocene
5'-BROMO-2'-CHLOROACETOPHENONE
1,1'-DI-N-BUTYLFERROCENE
4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide
Butylferrocene
3-Nitrobenzylammonium hydrochloride
(S)-5-Hydroxymethyldihydrofuran-2-one
1,1,2-Trimethylpropylborane
1,1'-DIMETHYLFERROCENE
1of4
Global( 286)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 | daisy@crovellbio.com | China | 5964 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com | jocelynpan@zjarts.com | CHINA | 993 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
View Lastest Price from Borane-methyl sulfide complex manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-07-20 | Borane-Methyl Sulfide Complex
13292-87-0
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD | |
 |
2022-09-27 | Borane-methyl sulfide complex
13292-87-0
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2021-07-09 | Borane-methyl sulfide complex
13292-87-0
|
US $25.00 / KG | 1KG | 99% | 1000 Kilogram/Kilograms per Month | Hebei Xibaijie Biotechnology Co., Ltd. |
-
- Borane-Methyl Sulfide Complex
13292-87-0
- US $5.00-2.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co,.LTD
-
- Borane-methyl sulfide complex
13292-87-0
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- Borane-methyl sulfide complex
13292-87-0
- US $25.00 / KG
- 99%
- Hebei Xibaijie Biotechnology Co., Ltd.
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