ChemicalBook >> CAS DataBase List >>N,N-Diethyl-1,1,1-trimethylsilylamine

N,N-Diethyl-1,1,1-trimethylsilylamine

CAS No.
996-50-9
Chemical Name:
N,N-Diethyl-1,1,1-trimethylsilylamine
Synonyms
DK436;TMSDEA;CD4450;(CH3)3SiN(C2H5)2;Trimethylsilyl-diethylamin;TRIMETHYLSILYLDIETHYLAMINE;DIETHYLAMINOTRIMETHYLSILANE;Diethyl(trimethylsilyl)amine;Trimethyl(diethylamino)silane;Diethyl-trimethylsilanyl-amine
CBNumber:
CB3771284
Molecular Formula:
C7H19NSi
Molecular Weight:
145.32
MDL Number:
MFCD00009040
MOL File:
996-50-9.mol
MSDS File:
SDS
Last updated:2023-07-27 13:57:03

N,N-Diethyl-1,1,1-trimethylsilylamine Properties

Melting point -10°C
Boiling point 125-126 °C(lit.)
Density 0.767 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
refractive index n20/D 1.411(lit.)
Flash point 50 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), DMSO (Slightly), Ethyl Acetate (Slightly)
form clear liquid
pka 11.27±0.70(Predicted)
Specific Gravity 0.763
color Colorless to Light yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 635718
CAS DataBase Reference 996-50-9(CAS DataBase Reference)
FDA UNII 5LP9WK7P33
NIST Chemistry Reference N,N-Diethyl-1,1,1-trimethylsilylamine(996-50-9)
EPA Substance Registry System Silanamine, N,N-diethyl-1,1,1-trimethyl- (996-50-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05
Signal word  Danger
Hazard statements  H225-H314
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  F,C
Risk Statements  11-34
Safety Statements  26-36/37/39-45-24/25-16
RIDADR  UN 2733 3/PG 2
WGK Germany  3
10-21
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29310095
NFPA 704
3
3 0

N,N-Diethyl-1,1,1-trimethylsilylamine price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 127256 N,N-Diethyltrimethylsilylamine 97% 996-50-9 25g $61.9 2024-03-01 Buy
Sigma-Aldrich 127256 N,N-Diethyltrimethylsilylamine 97% 996-50-9 100g $68.4 2024-03-01 Buy
TCI Chemical T0492 N-(Trimethylsilyl)diethylamine >98.0%(GC) 996-50-9 25mL $101 2024-03-01 Buy
Alfa Aesar A18149 N-(Trimethylsilyl)diethylamine, 98% 996-50-9 25g $47.65 2024-03-01 Buy
Alfa Aesar A18149 N-(Trimethylsilyl)diethylamine, 98% 996-50-9 100g $137.65 2024-03-01 Buy
Product number Packaging Price Buy
127256 25g $61.9 Buy
127256 100g $68.4 Buy
T0492 25mL $101 Buy
A18149 25g $47.65 Buy
A18149 100g $137.65 Buy

N,N-Diethyl-1,1,1-trimethylsilylamine Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

It is used to derivative polar organic compounds. N,N-Diethyl(trimethylsilyl)amine is a chemical reagent with wide application in organic chemistry and used in stereo specific addition reactions as well as in SN2 nucleophilic substitutions.

Uses

Trimethylsilyldiethylamine is a reagent used as an electrophilic trimethylsilyl source for cleavage of cyclic ethers, esters, oxazolidines, and cyclic acetals; also as a nucleophilic source of the diethylamino group, participating in the following synthesis reactions: Trimethylsilyl Group Transfer, Diethylamino Group Transfer, Trimethylsilyldiethylamine as Halosilane Equivalent, Silylation of Alcohols, Mild Generation of Phosphonochloridates, Silylation of Amines, Diethylamino Group Transfer, Conjugate Addition, Aminoalkylation of Aldehydes, Enamine and Silyl Enol Ether Preparation, Mediation of 1,4-Conjugate Additions, etc.

Definition

ChEBI: An N-silyl compound that is diethylamine in which the amino hydrogen is replaced by a trimethylsilyl group. N-(trimethylsilyl)diethylamine is a derivatisation agent used in gas chromatography/mass spectrometry applicat ons.

General Description

N,N-Diethyltrimethylsilylamine is a silylating agent used to derivatize polar organic compounds.

Purification Methods

Fractionate it through a 2ft vacuum-jacketed column containing Helipak packing with a reflux ratio of 10:1. [Sauer & Hasek J Am Chem Soc 68 241 1946, Langer et al. J Org Chem 23 50 1958, Rühlmann J Prakt Chem 9 315 1959, Beilstein 4 IV 4010.]

Global( 237)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Hubei Co-Formula Material Tech Co., Ltd.
+86-27-84459282 sales@cfmats.com CHINA 882 58

View Lastest Price from N,N-Diethyl-1,1,1-trimethylsilylamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N,N-Diethyl-1,1,1-trimethylsilylamine pictures 2023-07-28 N,N-Diethyl-1,1,1-trimethylsilylamine
996-50-9
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
N,N-Diethyl-1,1,1-trimethylsilylamine pictures 2023-04-20 N,N-Diethyl-1,1,1-trimethylsilylamine
996-50-9
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Guanlang Biotechnology Co., Ltd.
N,N-Diethyl-1,1,1-trimethylsilylamine  pictures 2022-08-18 N,N-Diethyl-1,1,1-trimethylsilylamine
996-50-9
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
Silanamine, N,N-diethyl-1,1,1-trimethyl- Silanamine,N,N-diethyl-1,1,1-trimethyl- Trimethylsilyl-diethylamin (Diethylamino)trimethylsilane, N-(Trimethylsilyl)diethylamine, TMSDEA N,N-DiethylaminotrimethylsilaneTMSDEAN,N-Diethyltrimethylsilylamine Trimethylsilyldiethylamine (TMSDEA) Diethyl(trimethylsilyl)amine N,N-DIETHYLTRIMETHYLSILYLAMINE, DERIVATI ZATION GRADE N,N-DIETHYL-1,1,1-TRIMETHYLSILYLAMINE 98+% TMSDEA N,N-DIETHYL-TRIMETHYLSILYLAMINE TRIMETHYLSILYLDIETHYLAMINE TRIMETHYL-N,N-DIETHYLAMINOSILANE TMSDEA (CH3)3SiN(C2H5)2 CD4450 Diethyl-trimethylsilanyl-amine DIETHYLAMINOTRIMETHYLSILANE N,N-DIETHYLAMINOTRIMETHYLSILANE N,N-DIETHYLTRIMETHYLSILYLAMINE N,N-DIETHYL-1,1,1-TRIMETHYLSILYLAMINE N-(TRIMETHYLSILYL)DIETHYLAMINE N,N-Diethyl(trimethyl)silanamine n,n-diethyl-1,1,1-trimethyl-silanamin N,N-diethyl-1,1,1-trimethyl-Silanamine Trimethyl(diethylamino)silane N,N-Diethyl-1,1,1-triMethylsilylaMine, 98+% 25GR Diethylaminotrimethylsilane TMS-DEA DIETHYLAMINOTRIMETHYLSILANE FOR SYNTHESI N,N-Diethyltrimethylsilylamine ,97% N, N-(triMethylsilyl) diethylaMine N-(Trimethylsilyl)diethylamine N,N-Diethyltrimethylsilylamine 97% Diethylaminotrimethylsilane for synthesis N-(Trimethylsilyl)diethylamine > N,N-Diethyl-1,1,1-trimethylsilylamine ISO 9001:2015 REACH N-(Trimethylsilyl)diethylamine (TMSDEA) extrapure, 97% N-ethyl-N-trimethylsilylethanamine DK436 996-50-9 C2H52NSiCH33 C7H19NSi C7H19NSiC CH33SiNCH2CH32 C7 Amines Building Blocks Nitrogen Compounds Organic Building Blocks Protected Amines Si-N Compounds Silicon Compounds (for Synthesis) Trimethylsilylation (GC Derivatizing Reagents) Silylation (GC Derivatizing Reagents) GC Derivatizing Reagents Aminosilanes Si (Classes of Silicon Compounds) Halogenated Heterocycles Building Blocks