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Ethyl 2-butynoate

CAS No.
4341-76-8
Chemical Name:
Ethyl 2-butynoate
Synonyms
2-butynoate;Ethyl Butynoate;ETHYL TETROLATE;Ethyltetrolate,T;ETHYL 2-BUTYNOATE;ethyle2-butynoate;Ethyl2-butynoate,98+%;Ethyl 3-methylpropiolate;TETROLIC ACID ETHYL ESTER;Ethyl 1-propynecarboxylate
CBNumber:
CB4228518
Molecular Formula:
C6H8O2
Molecular Weight:
112.13
MDL Number:
MFCD00015182
MOL File:
4341-76-8.mol
MSDS File:
SDS
Last updated:2023-07-03 17:51:04

Ethyl 2-butynoate Properties

Boiling point 160-161 °C/730 mmHg (lit.)
Density 0.962 g/mL at 25 °C (lit.)
refractive index n20/D 1.436(lit.)
Flash point 145 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform, Ethyl Acetate
form Powder
Specific Gravity 0.962
color Grey to red to brown
Water Solubility Miscible with water, chloroform and ethyl acetate.
Sensitive Air Sensitive
BRN 1744948
InChIKey FCJJZKCJURDYNF-UHFFFAOYSA-N
CAS DataBase Reference 4341-76-8(CAS DataBase Reference)
FDA UNII 6UG3A7S3GB
NIST Chemistry Reference Ethyl 2-butynoate(4341-76-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  1993
WGK Germany  3
10-23
Hazard Note  Irritant
HazardClass  3.2
PackingGroup  III
HS Code  29161900
NFPA 704
2
2 0

Ethyl 2-butynoate price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 425117 Ethyl 2-butynoate 98% 4341-76-8 1g $39 2024-03-01 Buy
Sigma-Aldrich 425117 Ethyl 2-butynoate 98% 4341-76-8 10g $155 2024-03-01 Buy
TCI Chemical T1052 Ethyl 2-Butynoate >98.0%(GC) 4341-76-8 1mL $46 2024-03-01 Buy
TCI Chemical T1052 Ethyl 2-Butynoate >98.0%(GC) 4341-76-8 5mL $133 2024-03-01 Buy
Alfa Aesar B25370 Ethyl 2-butynoate, 98% 4341-76-8 1g $26.65 2024-03-01 Buy
Product number Packaging Price Buy
425117 1g $39 Buy
425117 10g $155 Buy
T1052 1mL $46 Buy
T1052 5mL $133 Buy
B25370 1g $26.65 Buy

Ethyl 2-butynoate Chemical Properties,Uses,Production

Uses

Ethyl 2-butynoate is used as a precursor for the synthesis of 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate, alkenylsilanols and tricyclic aziridine derivatives. It acts as a methanogenesis inhibitor. As an electron deficient alkyne derivative, it plays a vital role in the preparation of 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex.

Uses

Ethyl 2-butynoate was used in the study of its effect on in vitro degradation and microbial biomass production.
It may be used in the synthesis of the following:

  • 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate
  • tricyclic aziridine derivatives
  • alkenylsilanols

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 7, p. 226, 1990
The Journal of Organic Chemistry, 38, p. 3588, 1973 DOI: 10.1021/jo00960a032

General Description

Ethyl 2-butynoate, a 2-alkynoate is a methanogenesis inhibitor. It is an electron deficient internal alkyne that has been reported to undergo codimerization with alkenes to form 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex. The annulation of thioamides with ethyl 2-butynoate catalyzed by tri-n-butylphosphine to form thiazolines has been investigated.

64-17-5
590-93-2
4341-76-8
Synthesis of Ethyl 2-butynoate from Ethanol and 2-Butynoic acid
Global( 254)Suppliers
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View Lastest Price from Ethyl 2-butynoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl 2-butynoate pictures 2023-07-04 Ethyl 2-butynoate
4341-76-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Ethyl 2-butynoate pictures 2023-05-17 Ethyl 2-butynoate
4341-76-8
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Guanlang Biotechnology Co., Ltd.
Ethyl 2-butynoate pictures 2022-09-17 Ethyl 2-butynoate
4341-76-8
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
  • Ethyl 2-butynoate pictures
  • Ethyl 2-butynoate
    4341-76-8
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.

Ethyl 2-butynoate Spectrum

TETROLIC ACID ETHYL ESTER 2-BUTYNOIC ACID ETHYL ESTER ETHYL 2-BUTYNOATE ETHYL TETROLATE Ethyl 1-propynecarboxylate Ethyl 3-methylpropiolate 2-Butynoic acid ethyl ester~Ethyl tetrolate Ethyltetrolate,Tetrolicacidethy Ethyl2-butynoate,98+% Ethyl Butynoate but-2-ynoic acid ethyl ester ethyle2-butynoate 2-Butynoic Acid Ethyl Ester Tetrolic Acid Ethyl Ester Ethyl Tetrolate Ethyl tetrolate, Tetrolic acid ethyl ester N-phenylcarbamic acid 2,2,2-trichloroethyl ester ETHYL 2-BUTYNOATE, 98%ETHYL 2-BUTYNOATE, 98%ETHYL 2-BUTYNOATE, 98%ETHYL 2-BUTYNOATE, 98% Ethyltetrolate,T 2-butynoate 4341-76-8 CH3CCCOOC2H5 CH3C8801CCOOCH2CH3 CH3CCCO2CH2CH3 Acetylenes Acetylenic Carboxylic Acids & Their Derivatives Carbonyl Compounds Building Blocks C6 to C7 Esters Organic Building Blocks Acetylenes Acetylenic Carboxylic Acids & Their Derivatives